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51.
52.
Heikki M. Salo Nga Nguyen Emmi Alakärppä Linards Klavins Anne Linn Hykkerud Katja Karppinen Laura Jaakola Maris Klavins Hely Häggman 《Comprehensive Reviews in Food Science and Food Safety》2021,20(5):5197-5225
Berries represent one of the most important and high-valued group of modern-day health-beneficial “superfoods” whose dietary consumption has been recognized to be beneficial for human health for a long time. In addition to being delicious, berries are rich in nutrients, vitamins, and several bioactive compounds, including carotenoids, flavonoids, phenolic acids, and hydrolysable tannins. However, due to their high value, berries and berry-based products are often subject to fraudulent adulteration, commonly for economical gain, but also unintentionally due to misidentification of species. Deliberate adulteration often comprises the substitution of high-value berries with lower value counterparts and mislabeling of product contents. As adulteration is deceptive toward customers and presents a risk for public health, food authentication through different methods is applied as a countermeasure. Although many authentication methods have been developed in terms of fast, sensitive, reliable, and low-cost analysis and have been applied in the authentication of a myriad of food products and species, their application on berries and berry-based products is still limited. The present review provides an overview of the development and application of analytical chemistry methods, such as isotope ratio analysis, liquid and gas chromatography, spectroscopy, as well as DNA-based methods and electronic sensors, for the authentication of berries and berry-based food products. We provide an overview of the earlier use and recent advances of these methods, as well as discuss the advances and drawbacks related to their application. 相似文献
53.
Ni-Mn-Ga alloys were compacted using pulsed electric current sintering (PECS) at 850-875 °C (50 MPa, 8 min) of flake-like powders made from the rapidly quenched melt-spun ribbons. Two kinds of ribbons were used: one made with a relatively slow wheel speed (6 m/s; average grain size ∼14 μm), and another with a faster wheel speed (23 m/s; average grain size ∼5 μm). Both sets of flake-like powders consisted of a mixture of non-modulated martensite (NM) and seven-layered modulated martensite (7M) structure. The amount of NM was greater in the slower speed material, while the other one exhibited mostly the 7M structure. These crystal structures were inherited by the sintered samples. In the compacts having the NM structure the multi-step martensitic reaction overlapped with the magnetic transition, and the Curie temperatures during heating and cooling differed from each other. In the compacts having mainly 7M structure the Curie point was about 100 °C and the martensitic transition took place in the paramagnetic state, while the intermartensitic one occurred in the region of 60-85 °C. This material demonstrated good magnetic properties and saturation magnetization, at best ∼50 emu/g. Mechanical properties of the compacts were good, and comparable to those of the polycrystalline Ni-Mn-Ga samples in compression. 相似文献
54.
Outi K. Santala Emilia A. Nordlund Kaisa S. Poutanen 《Food and Bioprocess Technology》2013,6(11):3102-3112
The aim of the work was to elucidate the impacts of treatment with xylanase at high (90 %) and low (40 %) water contents on the structural and physicochemical properties of wheat bran. The bran treatments at 40 % water content, both with and without added xylanase, resulted in a smaller average bran particle size, more changes in bran microstructure, and higher solubilization of polysaccharides than the corresponding treatments at 90 %. Also, the water holding capacity of bran (3.6?±?0.1 g water/g bran dm), determined by Baumann method, decreased more already after 4-h xylanase treatments at 40 % (2.4?±?0.1) than at 90 % (2.9?±?0.2). The solubility of salt-extractable bran proteins decreased during the treatments, especially at 40 %, also without added xylanase. Protein aggregation was detected in the SDS?+?DTT-extractable bran fraction, which also contained small proteins of 10–20 kDa not detectable in the untreated bran. The use of xylanase had only minor effect on bran proteins as compared to the treatments without added xylanase. The results indicate the large role of mechanical shear on the bran properties at 40 % water content. The low arabinose/xylose ratio (0.32) in the bran water extract after 24-h xylanase treatment at 40 %, however, suggests that the solubilization of arabinoxylan was caused by enzymatic action, and not by mechanical degradation. Arabinose/xylose ratio of the bran water extract decreased similarly during all the treatments, suggesting similar solubilization pattern of arabinoxylan at both water contents. The study showed that bran properties can be significantly modified by adjusting the water content and mechanical energy used in processing. 相似文献
55.
Peter F. Giddings Christopher R. Bowen Aki I.T. Salo Hyunsun A. Kim Alan Ive 《Composite Structures》2010
This paper develops a finite element (FE) approach using commercial ANSYS V11.0 software to accurately predict the cured shape of bistable composites by including the influence of manufacturing imperfections, such as resin rich areas and ply-thickness variations. Laminate composition was characterised by optical microscopy and their cured shapes measured using a Peak Motus motion analysis system. The FE model accurately predicts observed differences between laminate curvature in the two stable states. Localised reversal of curvature resulting from through-thickness shear stress is also predicted. Structural response to thermal loading was experimentally characterised showing a temperature dependent deflection rate and a residual curvature caused by non-reversible residual stresses. FE-predictions show good agreement with experiment over the range 20–110 °C. The presented data highlights the importance of manufacturing processes and materials selection in the design of thermally stressed multi-stable composite structures. 相似文献
56.
The effects of impurities and growth conditions on the optical quality of potassium dihydrogen phosphate (KDP) crystals were
examined. The transmittance of crystals grown under various conditions was measured in the range 200–400 nm for a larger number
of impurities than previously. The highest transmittance is afforded by crystals grown from solutions with the stoichiometric
composition at 55‡C and a growth rate of 1 mm per day. 相似文献
57.
58.
Luginy Machine Building Institute. Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 4, pp. 46–48, April, 1992. 相似文献
59.
The chromium (Cr) films on silicon Si(100) substrate are prepared using DC magnetron sputtering technique at an argon gas pressure of 3 Torr for different applied powers (40—140 W). The chemical composition, the thicknesses and the structural characterization of the deposited Cr films are studied and analyzed using energy dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), and X-ray diffraction (XRD), respectively. Furthermore, the generated plasma parameters, including floating potential, plasma potential, electron density, ion density and electron temperature, have been measured, and the automated Langmuir probe is used for the Cr films deposition. The ion and metal fluxes are also determined. The results show that the Cr film thickness enhances with the higher applied power. The Cr deposited films properties are characterized and correlated with the measured plasma parameters. 相似文献
60.
In order to investigate the relation between the structure of mono-branched saturated fatty acids and their physical properties,
a three-factor central composite design was constructed. For this purpose sixteen different fatty acids were prepared. The
synthetic strategy was to use if possible, a few common starting materials for the preparation of most of the acids. Thus
alkylation and hydrolysis of oxazolines were used for the preparation of 2-butylhexanoic acid, 2-methyloctadecanoic acid,
2-hexadecyloctadecanoic acid and 2-pentyloctadecanoic acid. A number of acids were prepared from thiophene derivatives followed
by desulfurization with Raney-Nickel alloy under alkaline conditions. Thus, starting from 3-ethylthiophene, 4-ethyl-2-thiophenecarboxylic
acid and 4-ethyl-2-methyl-5-thiophenecarboxylic acid were prepared, which upon desulfurization gave the desired 4-methylhexanoic
acid. From 3-bromo-2-methylthiophene, 3-ethyl-2-methyl-5-thiophenecarboxylic acid was preparedvia 3-acetyl-2-methylthiophene and 3-ethyl-2-methylthiophene. Desulfurization gave 4-ethylhexanoic acid. Another approach started
with 2-acylthiophenes, which were reacted with Grignard reagent to yield the appropriate olefins. By metalation and reaction
with carbon dioxide, these were transformed to the corresponding 2-thiophenecarboxylic acids. Upon desulfurization, the desired
fatty acids were obtained. In this way 6-propyldecanoic acid, 6-hexyldodecanoic acid, 6-methyldodecanoic acid and 6-pentylpentadecanoic
acid were prepared. The remaining four acids were prepared from some of the branched acids described above through Kolbe reactions
of dioic acids. Thus 16-methyloctadecanoic acid and 10-methyl-dodecanoic acid were obtained from 4-methylhexanoic acid, 16-ethyloctadecanoic
acid from 4-ethylhexanoic acid and 9-pentyloctadecanoic acid from 6-pentylpentadecanoic acid. 相似文献