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81.
Hamid Reza Rajabi Mojtaba Shamsipur Seied Mahdi Pourmortazavi 《Materials science & engineering. C, Materials for biological applications》2013,33(6):3374-3381
This work reports the first application of the ion imprinting technology for determination of potassium ion by precipitation polymerization method. Ion imprinted polymeric (IIP) nanoparticles were prepared by using dicyclohexyl 18C6 (DC18C6) as a K+ ion selective crown ether, in the acetonitrile–dimethylsulfoxide (3:1; v/v) mixture as porogen. The imprint potassium ion was removed from the polymeric matrix using 0.5 M HNO3. The scanning electron microscopy (SEM) micrographs showed colloidal nanoparticles of 60–90 nm in diameter and slightly irregular in shape. The obtained ion-imprinted particles for K+ showed selective recognition with rapid adsorption and desorption processes. It was found that imprinting results in increased affinity of the material toward K+ ion over other competitor metal ions with the same charge and/or close ionic radius. The synthesized IIP nanobeads were shown to be promising for solid-phase extraction coupled with flame photometry for determination of trace K+ ion in different water samples. 相似文献
82.
Mechanochemical processing is a novel technique for the synthesis of nano-sized materials. This research is based on the production of Al2O3–TiB2 nanocomposite powder using mechanochemical processing. For this purpose, a mixture of aluminum, titanium and boron oxide powders was subjected to high energy ball milling. The structural evaluation of powder particles after different milling times was conducted by X-ray diffractometry (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results showed that during ball milling the Al/B2O3/Ti reacted with a combustion mode producing Al2O3–TiB2 nanocomposite. In the final stage of milling, the crystallite sizes of Al2O3 and TiB2 were estimated to be less than 50 nm. 相似文献
83.
Mehdi Kiani M. Sharif Bakhtiar Mojtaba Atarodi 《Analog Integrated Circuits and Signal Processing》2010,62(3):319-325
This paper presents a low voltage low noise open loop automatic amplitude control method for voltage-controlled oscillators
(VCO’s). In this method a feedback mechanism keeps the VCO at its optimum amplitude over temperature and process variations
and then the loop is broken to avoid noise injection form the control circuitry to the VCO. The loop does not add extra noise
to the VCO. Based on the proposed method, a low voltage low noise LC-VCO was designed for a low phase noise application in
TSMC 0.18 micron RFCMOS technology. Simulations show considerable improvement in the phase noise with the application of the
proposed method. 相似文献
84.
The composition of essential oils from aerial parts of Heracleum persicum, a widely used medicinal plant, and three other Heracleum species growing wild in Iran were analysed by GC and GC–MS. Myristicin (53.6%), (E)-anethole (25.0%), hexyl butanoate (29.7%) and elemicin (41.1%) were the major compounds of Heracleum pastinacifolium, H. persicum, Heracleum rechingeri and Heracleum transcaucasicum, respectively. Cytotoxic activity assessed on three human cancer cell lines (HeLa, LS180 and Raji), showed that essential oils from H. transcaucasicum (IC50 values; 0.362–0.594 mg/ml) followed by H. pastinacifolium (0.497–1.398 mg/ml) had moderate antitumoral activities. In the DPPH radical scavenging assay, H. pastinacifolium and H. persicum oils showed the highest activities with IC50 values of 7.3 and 7.4 mg/ml, respectively. Antioxidant activity correlated well with the total phenolic content of the oils. None of the essential oils showed significant antimicrobial activities. 相似文献
85.
In this paper, particle size effect on pinewood combustion in a stationary packed bed was investigated. Mass loss rate, temperature profile at different bed locations and gas compositions in the out-of-bed flue gases were measured at a fixed primary air flow rate. Pinewood cubes was fired with size ranging from 5 to 35 mm. A unique numerical model applicable to thermally thick particles was proposed and relevant equations were solved to simulate the non-homogeneous characteristics of the burning process. It is found that at the operating conditions of the current study, smaller particles are quicker to ignite than larger particles and have distinctive combustion stages; burning rate is also higher with smaller fuel size; and smaller fuels have a thinner reaction zone and result in both higher CO and CH4 concentrations in the out-of-bed flue gases; on the other hand, larger particles produced a higher flame temperature and result in higher H2 concentration in the flue gases. Larger particles also cause the combustion process becoming more transient where the burning rate varies for most part of the combustion process. 相似文献
86.
Amphiphilic block copolymers are macromolecular compounds of great importance from both fundamental scientific and many technological
point of views for a large variety of applications. Amphiphilic diblock copolymer containing segments of monomethoxypoly(ethylene
glycol) and polystyrene (MPEG-b-PS) was synthesised by a convenient method for preparation of macroinitiator MPEG-TEMPO for
‘living’ free radical polymerization (NMRP technique). Initially, derivative of MPEG with chlorine function has been prepared
in an one-step reaction with thionyl chloride. 1-hydroxy-2,2,6,6-tetramethyl-piperidine (TEMPO-OH) obtained by reduction of
2,2,6,6-tetramethyl-piperidinyl-1-oxy (TEMPO) with sodium ascorbate was coupled with chlorinated MPEG to yield the macroinitiator
MPEG terminated with a TEMPO unit (MPEG-TEMPO), which was further used to prepare the diblock copolymer MPEG-b-PS of styrene.
The product was purified and identified by 1H NMR, GPC and, FT-IR. 相似文献
87.
Mohammad Ali Faramarzi Nadia Zolfaghary Mojtaba Tabatabaei Yazdi Sina Adrangi Hossein Rastegar Mohsen Amini Mohsen Badiee 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2009,84(7):1021-1025
BACKGROUND: A large number of bacterial, fungal and microalgal species are able to bio‐transform steroid compounds. Among them, fungi from the Mucor genus have been shown to mediate hydroxylation, oxidation, and desaturation by the double bond formation and epoxidation of various steroid substances. Mucor racemocus has not been studied for its ability to modify androst‐1,4‐dien‐3,17‐dione, a pharmaceutically important steroid precursor. RESULTS: The filamentous fungus M. racemosus was applied for bioconversion of androst‐1,4‐dien‐3,17‐dione (ADD, I ) in a 5‐day fermentation. Microbial metabolites were purified chromatographically and identified on the basis of their spectral data as 17β‐hydroxyandrost‐1,4‐dien‐3‐one ( II ), 14α‐hydroxyandrost‐1,4‐dien‐3,17‐dione ( III ), 15α‐hydroxyandrost‐1,4‐dien‐3,17‐dione ( IV ), 15α,17β‐dihydroxyandrost‐1,4‐dien‐3‐one ( V ), 14α,17β‐dihydroxyandrost‐1,4‐dien‐3‐one ( VI ), and 6β,17β‐dihydroxyandrost‐1,4‐dien‐3‐one ( VII ). CONCLUSION: Observed modifications included hydroxylation at C‐6β, C‐14α, C‐15α positions and 17‐carbonyl reduction. The best fermentation conditions for production of hydroxysteroid‐1,4‐dien‐3‐one derivatives were found to be 25 °C at 150 rpm for 5 days with a substrate concentration of 0.5 g L?1. Copyright © 2009 Society of Chemical Industry 相似文献
88.
Serati Mehdi Bahaaddini Mojtaba Roshan Hamid Zhang Tian Tian Bryant Nicholas 《Bulletin of Engineering Geology and the Environment》2021,80(7):5867-5879
Bulletin of Engineering Geology and the Environment - This work aims to identify fracture pattern and crack growth mode in brittle rocks and solids under induced tensile stresses, and further... 相似文献
89.
Saharnaz Ahmadi Maryam Farokhi Parisa Padidar Mojtaba Falahati 《International journal of molecular sciences》2015,16(8):17289-17302
In this study the effect of surface modification of mesoporous silica nanoparticles (MSNs) on its adsorption capacities and protein stability after immobilization of beta-lactoglobulin B (BLG-B) was investigated. For this purpose, non-functionalized (KIT-6) and aminopropyl-functionalized cubic Ia3d mesoporous silica ([n-PrNH2-KIT-6]) nanoparticles were used as nanoporous supports. Aminopropyl-functionalized mesoporous nanoparticles exhibited more potential candidates for BLG-B adsorption and minimum BLG leaching than non-functionalized nanoparticles. It was observed that the amount of adsorbed BLG is dependent on the initial BLG concentration for both KIT-6 and [n-PrNH2-KIT-6] mesoporous nanoparticles. Also larger amounts of BLG-B on KIT-6 was immobilized upon raising the temperature of the medium from 4 to 55 °C while such increase was undetectable in the case of immobilization of BLG-B on the [n-PrNH2-KIT-6]. At temperatures above 55 °C the amounts of adsorbed BLG on both studied nanomaterials decreased significantly. By Differential scanning calorimetry or DSC analysis the heterogeneity of the protein solution and increase in Tm may indicate that immobilization of BLG-B onto the modified KIT-6 results in higher thermal stability compared to unmodified one. The obtained results provide several crucial factors in determining the mechanism(s) of protein adsorption and stability on the nanostructured solid supports and the development of engineered nano-biomaterials for controlled drug-delivery systems and biomimetic interfaces for the immobilization of living cells. 相似文献
90.
Lahiji R. R. Sharifi H. Katehi L. P. B. Mohammadi S. 《Microwave Theory and Techniques》2010,58(1):48-56