全文获取类型
收费全文 | 1476篇 |
免费 | 55篇 |
国内免费 | 2篇 |
学科分类
工业技术 | 1533篇 |
出版年
2024年 | 3篇 |
2023年 | 8篇 |
2022年 | 20篇 |
2021年 | 33篇 |
2020年 | 16篇 |
2019年 | 22篇 |
2018年 | 18篇 |
2017年 | 27篇 |
2016年 | 31篇 |
2015年 | 30篇 |
2014年 | 35篇 |
2013年 | 99篇 |
2012年 | 57篇 |
2011年 | 97篇 |
2010年 | 86篇 |
2009年 | 68篇 |
2008年 | 94篇 |
2007年 | 69篇 |
2006年 | 67篇 |
2005年 | 65篇 |
2004年 | 50篇 |
2003年 | 48篇 |
2002年 | 60篇 |
2001年 | 22篇 |
2000年 | 35篇 |
1999年 | 35篇 |
1998年 | 29篇 |
1997年 | 19篇 |
1996年 | 25篇 |
1995年 | 19篇 |
1994年 | 30篇 |
1993年 | 19篇 |
1992年 | 16篇 |
1991年 | 20篇 |
1990年 | 12篇 |
1989年 | 13篇 |
1988年 | 11篇 |
1987年 | 13篇 |
1986年 | 8篇 |
1985年 | 8篇 |
1984年 | 13篇 |
1983年 | 17篇 |
1982年 | 12篇 |
1981年 | 19篇 |
1980年 | 11篇 |
1979年 | 7篇 |
1978年 | 5篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1969年 | 1篇 |
排序方式: 共有1533条查询结果,搜索用时 15 毫秒
41.
Panitha Phulkerd Atsuro Yamazaki Shohei Iwasaki Masayuki Yamaguchi 《Polymer Engineering and Science》2021,61(2):367-378
In this study, polypropylene (PP) films containing the β nucleating agent, N,N′-dicyclohexyl-2,6-naphthalenedicarboxamide, were prepared using PP with three different molecular weights (low, medium, and high) by extrusion process with T-shaped die. The structure and morphology of the films were studied after stretching. It was found that a unique molecular orientation, in which both the c-axis and crystalline lamellae were oriented perpendicular to the flow direction, was formed in all undrawn film samples, irrespective of the molecular weights of the PP. In the PP sheets stretched in the machine direction, the low-molecular-weight sample containing the nucleating agent exhibited brittle properties owing to a lack of tie chains in the stretching direction. In contrast, cavitation was prominent in the medium (M-PP)- and high (H-PP)-molecular-weight samples. Notably, M-PP containing the nucleating agent, with a high degree of molecular orientation, promoted the formation of a large number of voids. In H-PP containing the nucleating agent, the presence of numerous tie chains inhibited cavitation, resulting in fewer voids. The experimental results demonstrated the influence of the molecular weight on the void structure, which will be useful in the field of microporous membranes. 相似文献
42.
Blending a crosslinked high‐density polyethylene (xHDPE) enhances melt strength and strain hardening behavior in elongational viscosity of high‐density polyethylene (HDPE) to a great degree. Gel fraction of xHDPE has a stronger effect on the strain hardening than sol fraction, although sol fraction also enhances the strain hardening to some degree. Further, the xHDPE crosslinked by peroxide in a compression mold exhibits more pronounced effect than xHDPE by radiation, which is attributed to the difference in the amount of the gel fraction. The xHDPE, which enhances the strain hardening, has sparse crosslink points in the network. Moreover, it was found from linear viscoelastic measurements, such as oscillatory modulus and relaxation modulus, that the xHDPE is characterized as a critical gel, which was also supported by the result of tensile testing. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 73–78, 2002 相似文献
43.
Aritomo Yamaguchi Norihito Hiyoshi Osamu Sato Mitsumasa Osada Masayuki Shirai 《Catalysis Letters》2008,122(1-2):188-195
Lignin gasification in supercritical water over charcoal supported ruthenium trivalent salts was studied using a batch reactor
at 673 K. Ruthenium (III) nitrosyl nitrate on charcoal (Ru(NO)(NO3)3/C) was more active than ruthenium (III) chloride on charcoal (RuCl3/C) for the gasification reaction. EXAFS analysis revealed that ruthenium metal particles were formed in both RuCl3/C and Ru(NO)(NO3)3/C catalysts during the lignin gasification and that the size of ruthenium metal in Ru(NO)(NO3)3/C was smaller than that in RuCl3/C. It was concluded that well-dispersed ruthenium metal particles were active for the lignin gasification in supercritical
water. 相似文献
44.
In Vivo Incorporation of Azide Groups into DNA by Using Membrane‐Permeable Nucleotide Triesters 下载免费PDF全文
Dr. Masayuki Tera Dr. Stella M. K. Glasauer Prof. Dr. Nathan W. Luedtke 《Chembiochem : a European journal of chemical biology》2018,19(18):1939-1943
Metabolic incorporation of bioorthogonal functional groups into cellular nucleic acids can be impeded by insufficient phosphorylation of nucleosides. Previous studies found that 5azidomethyl‐2′‐deoxyuridine (AmdU) was incorporated into the DNA of HeLa cells expressing a low‐fidelity thymidine kinase, but not by wild‐type HeLa cells. Here we report that membrane‐permeable phosphotriester derivatives of AmdU can exhibit enhanced incorporation into the DNA of wild‐type cells and animals. AmdU monophosphate derivatives bearing either 5′‐bispivaloyloxymethyl (POM), 5′‐bis‐(4‐acetoxybenzyl) (AB), or “Protide” protective groups were used to mask the phosphate group of AmdU prior to its entry into cells. The POM derivative “POM‐AmdU” exhibited better chemical stability, greater metabolic incorporation efficiency, and lower toxicity than “AB‐AmdU”. Remarkably, the addition of POM‐AmdU to the water of zebrafish larvae enabled the biosynthesis of azide‐modified DNA throughout the body. 相似文献
45.
Automated Synthesis of (rac)‐, (R)‐, and (S)‐[18F]Epifluorohydrin and Their Application for Developing PET Radiotracers Containing a 3‐[18F]Fluoro‐2‐hydroxypropyl Moiety 下载免费PDF全文
Dr. Tomoteru Yamasaki Yiding Zhang Wakana Mori Dr. Masayuki Hanyu Katsushi Kumata Akiko Hatori Dr. Lin Xie Nobuki Nengaki Prof. Dr. Ming‐Rong Zhang 《ChemMedChem》2018,13(16):1723-1731
To introduce the 3‐[18F]fluoro‐2‐hydroxypropyl moiety into positron emission tomography (PET) radiotracers, we performed automated synthesis of (rac)‐, (R)‐, and (S)‐[18F]epifluorohydrin ([18F] 1 ) by nucleophilic displacement of (rac)‐, (R)‐, or (S)‐glycidyl tosylate with 18F? and purification by distillation. The ring‐opening reaction of (R)‐ or (S)‐[18F] 1 with phenol precursors gave enantioenriched [18F]fluoroalkylated products without racemisation. We then synthesised (rac)‐, (R)‐, and (S)‐ 2‐{5‐[4‐(3‐[18F]fluoro‐2‐hydroxypropoxy)phenyl]‐2‐oxobenzo[d]oxazol‐3(2H)‐yl}‐N‐methyl‐N‐phenylacetamide ([18F] 6 ) as novel radiotracers for the PET imaging of translocator protein (18 kDa) and showed that (R)‐ and (S)‐[18F] 6 had different radioactivity uptake in mouse bone and liver. Thus, (rac)‐, (R)‐, and (S)‐[18F] 1 are effective radiolabelling reagents and can be used to develop PET radiotracers by examining the effects of chirality on their in vitro binding affinities and in vivo behaviour. 相似文献
46.
Rheological properties in a molten state are studied extensively for poly(3‐hydroxybutyrate‐co‐3‐hydroxyvalerate), PHB‐HV, with a small amount of crosslinked poly(epichlorohydrin), PECH, having low density of crosslink points. It is found that adding 2 wt % of xPECH greatly enhances the melt elasticity of PHB‐HV, one of the serious defects of microbial PHB, whereas it has no effect on the shear viscosity. As a result, viscoelastic nature, and thus processability, of PHB‐HV can be controlled by blending the crosslinked PECH. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
47.
Nanoparticles were prepared by the thermosensitive aggregation of the elastin model polypeptide, (GVGVP)251, and gamma-ray crosslinking. Three different heating processes, “slow heating,” “fast heating,” and “heat shock,” were used
for the aggregation of the peptide, followed by gamma-ray crosslinking. Only the “heat shock” process successfully yielded
stable nanoparticles with diameters of less than ca. 150 nm and a narrow size distribution. Circular dichroism (CD) spectrometry
showed that this polypeptide formed a type-II β-turn structure when the temperature was increased to above the cloudy point
in the case of the “heat shock” process; suggesting that this structure might contribute to stable nanoparticle formation
by gamma-rays. CD spectrometry also suggested that this structure would be affected during the formation of stable crosslinked
particles. 相似文献
48.
Polymer films consisting of nematic liquid crystal (LC) droplets and polymer networks were prepared by using a low-energy electron beam to irradiate a homogeneous mixture of nematic LC and bifunctional methacrylate monomer. Influences of such polymerization conditions as polymerization temperature, monomer concentration, and radiation energy on electrooptical properties of the compound films were examined. The polymer yield, affecting to a large extent the film properties, depended on the monomer concentration and the radiation energy. Compound films, which have a switching function from the scattering state to transparency by applying approximately 20–30 V between the two sides of the film, were obtained. In addition, it was found that a compound film with excellent electrooptical properties was prepared by changing impure LC in the droplets into pure LC. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 65:1675–1681, 1997 相似文献
49.
Tran Thi Ngoc Lan Rokuro Nishimura Yukihiro Satoh Masayuki Yokoi 《Corrosion Science》2005,47(4):1023-1038
The atmospheric corrosion of marble was evaluated in terms of SO2 concentration as air pollution and climatic factors such as rainfall, relative humidity, temperature and so on under the field exposure. Marble of calcite type (CaCO3) was exposed to outdoor atmospheric environment with and without a rain shelter at four test sites in the southern part of Vietnam for 3-month, 1- and 2-year periods from July 2001 to September 2003. The thickness loss of marble was investigated gravimetrically. X-ray diffraction and X-ray fluorescent methods were applied to study corrosion products on marble. The corrosion product of marble was only gypsum (CaSO4 · 2H2O) and was washed out by rain under the unsheltered exposure condition. It was found that the most substantial factors influencing the corrosion of marble were rainfall, SO2 concentration in the air and relative humidity. Based on the results obtained, we estimated the dose-response functions for the atmospheric corrosion of marble in the southern part of Vietnam. 相似文献
50.