全文获取类型
收费全文 | 131617篇 |
免费 | 12650篇 |
国内免费 | 7958篇 |
学科分类
工业技术 | 152225篇 |
出版年
2024年 | 422篇 |
2023年 | 1759篇 |
2022年 | 3297篇 |
2021年 | 5084篇 |
2020年 | 3779篇 |
2019年 | 3176篇 |
2018年 | 3515篇 |
2017年 | 4040篇 |
2016年 | 3695篇 |
2015年 | 5382篇 |
2014年 | 6902篇 |
2013年 | 8156篇 |
2012年 | 9506篇 |
2011年 | 10482篇 |
2010年 | 9641篇 |
2009年 | 9166篇 |
2008年 | 9157篇 |
2007年 | 8804篇 |
2006年 | 8476篇 |
2005年 | 6935篇 |
2004年 | 5037篇 |
2003年 | 4133篇 |
2002年 | 3985篇 |
2001年 | 3398篇 |
2000年 | 2941篇 |
1999年 | 2490篇 |
1998年 | 1652篇 |
1997年 | 1443篇 |
1996年 | 1284篇 |
1995年 | 1052篇 |
1994年 | 829篇 |
1993年 | 632篇 |
1992年 | 457篇 |
1991年 | 348篇 |
1990年 | 263篇 |
1989年 | 237篇 |
1988年 | 173篇 |
1987年 | 118篇 |
1986年 | 99篇 |
1985年 | 42篇 |
1984年 | 35篇 |
1983年 | 39篇 |
1982年 | 45篇 |
1981年 | 31篇 |
1980年 | 23篇 |
1979年 | 10篇 |
1977年 | 14篇 |
1976年 | 5篇 |
1959年 | 17篇 |
1951年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
32.
33.
聚乙二醇-三聚氰胺甲醛和聚乙烯醇半互穿网络的构建及表征 总被引:1,自引:0,他引:1
为提高三聚氰胺甲醛(MF)树脂制品的柔韧性,以聚乙二醇接枝三聚氰胺(M-PEG)替代部分三聚氰胺,并与甲醛、聚乙烯醇(PVA)在碱性条件下合成了聚乙二醇-三聚氰胺甲醛(PEG-MF)与PVA的半互穿聚合物网络体系(SemiIPN)。采用红外光谱、拉曼光谱、热重分析、差示扫描量热法等手段对Semi-IPN的微观结构进行了剖析,并分析了PEG、PVA等柔性链段对Semi-IPN黏度、游离甲醛含量、柔韧性等性能的影响。结果表明,PVA作为线型结构贯穿于聚乙二醇-三聚氰胺甲醛树脂交联网络体系结构中,形成了半互穿网络结构;所形成的Semi-IPN的热分解温度比MF树脂降低了60℃左右;Semi-IPN的韧性比纯MF树脂提高了800%,最高可达到19.700kJ/m2。 相似文献
34.
35.
Xiaoyan Qiu Yongqiang Zhang Haitao Wu Rui Yang Jun Yang Rongjuan Liu Yong Liu Zhiping Zhou Tongfan Hao Yijing Nie 《Polymer International》2019,68(2):218-224
The crystallization of capped ultrathin polymer films is closely dependent on film thickness and interfacial interaction. Using dynamic Monte Carlo simulations, the crystallization behaviors of polymer films confined between two substrates were investigated. The crystallization rate of confined polymers is reduced with high interfacial interactions. Above a critical strength of interfacial interaction, polymer crystallization in the thin film is inhibited within the simulation time scales. An increase in film thickness leads to a rise in critical interfacial interaction. In thicker films, the chains have more space to change conformation to form crystal stems. In addition, there are fewer absorbed segments in confined chains for the thicker films, and thus the chains have stronger ability to adjust their conformation. Therefore an increase in film thickness can cause a reduction in the entropic barrier required for the formation of crystals and thus an increase in the critical interfacial interaction. © 2018 Society of Chemical Industry 相似文献
37.
Qi Yang Qilong Wu Yang Liu Shuiping Luo Xiaotong Wu Xixia Zhao Haiyuan Zou Baihua Long Wen Chen Yujia Liao Lanxi Li Pei Kang Shen Lele Duan Zewei Quan 《Advanced materials (Deerfield Beach, Fla.)》2020,32(36):2002822
Engineering novel Sn-based bimetallic materials could provide intriguing catalytic properties to boost the electrochemical CO2 reduction. Herein, the first synthesis of homogeneous Sn1−xBix alloy nanoparticles (x up to 0.20) with native Bi-doped amorphous SnOx shells for efficient CO2 reduction is reported. The Bi-SnOx nanoshells boost the production of formate with high Faradaic efficiencies (>90%) over a wide potential window (−0.67 to −0.92 V vs RHE) with low overpotentials, outperforming current tin oxide catalysts. The state-of-the-art Bi-SnOx nanoshells derived from Sn0.80Bi0.20 alloy nanoparticles exhibit a great partial current density of 74.6 mA cm−2 and high Faradaic efficiency of 95.8%. The detailed electrocatalytic analyses and corresponding density functional theory calculations simultaneously reveal that the incorporation of Bi atoms into Sn species facilitates formate production by suppressing the formation of H2 and CO. 相似文献
38.
Wenshu Chen Jiajun Gu Yongping Du Fang Song Fanxing Bu Jinghan Li Yang Yuan Ruichun Luo Qinglei Liu Di Zhang 《Advanced functional materials》2020,30(25)
Large‐scale production of hydrogen from water‐alkali electrolyzers is impeded by the sluggish kinetics of hydrogen evolution reaction (HER) electrocatalysts. The hybridization of an acid‐active HER catalyst with a cocatalyst at the nanoscale helps boost HER kinetics in alkaline media. Here, it is demonstrated that 1T–MoS2 nanosheet edges (instead of basal planes) decorated by metal hydroxides form highly active / heterostructures, which significantly enhance HER performance in alkaline media. Featured with rich / sites, the fabricated 1T–MoS2 QS/Ni(OH)2 hybrid (quantum sized 1T–MoS2 sheets decorated with Ni(OH)2 via interface engineering) only requires overpotentials of 57 and 112 mV to drive HER current densities of 10 and 100 mA cm?2, respectively, and has a low Tafel slope of 30 mV dec?1 in 1 m KOH. So far, this is the best performance for MoS2‐based electrocatalysts and the 1T–MoS2 QS/Ni(OH)2 hybrid is among the best‐performing non‐Pt alkaline HER electrocatalysts known. The HER process is durable for 100 h at current densities up to 500 mA cm?2. This work not only provides an active, cost‐effective, and robust alkaline HER electrocatalyst, but also demonstrates a design strategy for preparing high‐performance catalysts based on edge‐rich 2D quantum sheets for other catalytic reactions. 相似文献
39.
利用计算机实现自动、准确的秀丽隐杆线虫(C.elegans)的各项形态学参数分析,至关重要的是从显微图像上分割出线虫体态,但由于显微镜下的图像噪声较多,线虫边缘像素与周围环境相似,而且线虫的体态具有鞭毛和其他附着物需要分离,多方面因素导致设计一个鲁棒性的C.elegans分割算法仍然面临着挑战。针对这些问题,提出了一种基于深度学习的线虫分割方法,通过训练掩模区域卷积神经网络(Mask R-CNN)学习线虫形态特征实现自动分割。首先,通过改进多级特征池化将高级语义特征与低级边缘特征融合,结合大幅度软最大损失(LMSL)损失算法改进损失计算;然后,改进非极大值抑制;最后,引入全连接融合分支等方法对分割结果进行进一步优化。实验结果表明,相比原始的Mask R-CNN,该方法平均精确率(AP)提升了4.3个百分点,平均交并比(mIOU)提升了4个百分点。表明所提出的深度学习分割方法能够有效提高分割准确率,在显微图像中更加精确地分割出线虫体。 相似文献
40.
Dongdong Ji Zheng Liu Bailing Jiang Xiaofei Luo 《International Journal of Hydrogen Energy》2021,46(27):13960-13970
The evaluation of cell's weatherability is of practical interest. To further improve the soluble lead flow battery's weatherability, physiochemical properties of electrolytes containing fluoborate, perchlorate, methanesulfonate and trifluoromethanesulfonate are investigated from ?60 to 50 °C. Activities of CF3SO3H and HClO4 are poor in trifluoromethanesulfonate and perchlorate solutions due to common anion effect. The solubility of lead salt can be improved by increasing temperature, but worsened by increasing acid's content. With the temperature increasing, the conductivity is enhanced, and the viscosity is lowered for four solutions. The same results have been found by increasing acid's content except for CF3SO3H. The high energy efficiency can be achieved for cells over ?40–0 °C using fluoborate and perchlorate solutions, 73.2% at ?40 °C and 78.1% at ?30 °C respectively. Over the temperature range of 20–50 °C, the cells with methanesulfonate and trifluoromethanesulfonate solutions have good performance, 77.4% and 73.7% at 50 °C respectively. 相似文献