Sn-9Zn-3Bi/Cu钎焊接头在170℃时效过程中的显微结构

采用ST50润湿实验仪完成了钎焊并研究分析了Sn-9Zn-3Bi/Cu接头在170℃下长期时效的显微结构变化.结果表明:Sn-9Zn-3Bi/Cn接头时效至200 h后在界面处形成单一连续的Cu5Zn8化合物层;时效至500 h和1000 h后,界面处形成了3层化合物层,从铜母材侧起,分别为Cu-Sn化合物层,Cu-Zn化合物层和Sn-Cu化合物层;随着时效时间的增加,整个金属化合物层变厚,而Cu-Zn化合物层减薄,表明Cu-Zn化合物层在时效过程中具有不稳定性.     

Conductivity enhancement in transparetn ZnO films via Al-dopping produced by CW-CO2 laser-induced evaporation

Highly conductive transparent aluminium-doped ZnO (ZnO:A1) films were successfully deposited by CW-CO₂ laser-induced evaporation. Optimisation of evaporation parameters was based on laser power, substrate temperature, O₂ partial pressure in the vacuum chamber and amount of Al in the ZnO source pellet. ZnO:A1 films with an electrical resistivity as low as 6.6 × 10⁻²Ω·cm and an optical transmission of 80% at 500nm were obtained at laser power of 15 W, substrate temperature of about 200°C, O₂ partial pressure of 6—7 × 10⁻⁴ Torr and 5wt.% Al. Conductivity of ZnO films can be increased one order via Al-doping in ZnO films. The films obtained by laser-induced evaporation have compared quite favorably with the high quality films obtained by sputtering.     

高性能纤维的弯曲疲劳断裂研究

在自制弯曲疲劳装置上 ,对 3种高强对位芳纶及超高相对分子质量聚乙烯纤维 (Dyneema SK65 )进行双面弯曲疲劳试验。结果表明 ,Twaron 2 0 0 0弯曲疲劳寿命的自然对数与预加应力、弯曲角度呈线性关系 ,Dyneema SK65弯曲疲劳寿命明显长于对位芳纶 ,Twaron 2 0 0 0 ,Kevlar 12 9相近 ,都比Kevlar 2 9略长 ;高强型对位芳纶的弯曲疲劳断裂断口芯层呈现出“毛笔头”或“拔丝形”原纤化分裂形态 ,超高相对分子质量聚乙烯纤维弯曲疲劳断裂断口有明显的脆性折断形态 ,无原纤出现。     

Plasma graft polymerization of acrylamide onto crosslinked HTPB based PU membrane for pervaporation

Pervaporation of water-ethanol mixtures through plasma graft polymerization of acrylamide onto crosslinked hydroxyl terminated poly-butadiene (HTPB) based PU membranes, plasma graft polymerization of acrylamide onto crosslinked PU membrane (AAm-p-CPU), were investigated. The grafting was dependent on the discharge power and pretreatment period. The effects of crosslinking, plasma treatment conditions, feed compositions, and feed temperature on the performance of these membranes were studied. The physical properties of crosslinked membrane were better than those of the uncrosslinked membrane. In addition, compared with crosslinked PU membranes (CPU), the plasma modified crosslinked PU membranes effectively improve the pervaporation separation performances.     

Synthesis and property of nanosized palladium catalysts protected by chitosan/silica

A chitosan (CTN)/silica‐supported nanosized palladium catalyst was obtained from a silica‐supported chitosan palladium complex through a complex transition method. An adsorption model was employed to simplify the structure of the di‐supporter. It was indicated that when the polymer coil adsorbed on the silica surface with even a monolayer the catalytic activity would reach an optimum value, and different situations of the, nanosized palladium particles would cause a different catalysis. The molar ratio of the chitosan structure unit to the palladium would affect the metal's size, which therefore influenced its catalytic activity. The experimental results corresponded with the inferences. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 989–994, 2002     

浅谈如何提高化工原理的教学质量

化工原理是化工类及相近专业的一门主干课。要提高教学质量,必须加强教师自身建设,进一步强化课程内容和课程体系的改革,不断探索教学方法的改进,强化多媒体教学手段的运用。     

Numerical Analysis of the Constrained Blister Test

The constrained blister test is investigated through finite element analysis to determine the applicabilities and the limitations of the new technique. Numerical results confirm that the strain energy release rate asymptotically approaches a constant value. These results also show that the test technique and the approximate solution for strain energy release rate are applicable for some practical cases.     

The mechanism of color reversion in soybean salad oil

An enzymatic reaction might be the major cause of color reversion in soybean oil. During the soybean flaking process, enzymatic reactions take place to convertγ-tocopherol to 5-(tocopheryloxy)-γ-tocopherol (γ-TED), and then further convertγ-TED to the precursors which are the cause of color reversion. The variations ofγ-tocopherol andγ-TED contents in soybean oil are accompanied by an inverse change in the precursors’ concentration. Therefore, the contents ofγ-tocopherol orγ-TED in crude soybean oil could be used as an index for predicting the color quality (color reversion) of soybean salad oil. Almost all the precursors (such as tocored) were converted to color-reverted substances under catalysis after bleaching treatment, and they were converted back to the precursors during deodorization. Those precursors might be gradually reconverted into the color reverted substances during storage to cause the color reversion in soybean salad oil.     

Properties of recycled high density polyethylene from milk bottles

The effect of virgin, high-density polyethylene (HDPE)/recycled HDPE composition on the physical properties of the blends was investigated. The recycled HDPE was obtained from a postconsumer cycle of milk bottles. It was found that elongation at break was the mechanical property mostly affected by the content of recycled HDPE. Overall, however, the recycled HDPE from milk bottles was found to be a material with useful properties not largely different from those of virgin resin and thus could be used, at an appropriate concentration in virgin HDPE, for different applications.     

Moisture Distribution and Dewatering Efficiency for Wet Materials

This review paper summarizes current research efforts toward a comprehensive view of wet material dewatering, considering the binding energy as the strength to hold water, and rupture energy given to remove moisture from materials.