The Resource-Energy Nexus as a Key Factor for Circular Economy

The extraction of raw materials is associated with energy input and CO₂ emissions. What is obvious for extraction from mining, however, also applies to recycling. Mostly, recycling is preferred for reasons of climate protection or because of the geological scarcity of raw materials, which is controversially discussed. While in mining, the declining ore grade is a driver for the energy demand, in case of recycling it is the dissipation of materials into products or waste. As concentration decreases, the effort required also increases disproportionately. The “closing the loop” metaphor of Circular Economy is therefore inappropriate in its stricter meaning. It is rather about optimizing the overall system and finding the optimal recycling rate. However, first, it must be clarified what the political goals for Circular Economy are.     

New developments in cold spray based on higher gas and particle temperatures

In cold spraying, bonding is associated with shear instabilities caused by high strain rate deformation during the impact. It is well known that bonding occurs when the impact velocity of an impacting particle exceeds a critical value. This critical velocity depends not only on the type of spray material, but also on the powder quality, the particle size, and the particle impact temperature. Up to now, optimization of cold spraying mainly focused on increasing the particle velocity. The new approach presented in this contribution demonstrates capabilities to reduce critical velocities by well-tuned powder sizes and particle impact temperatures. A newly designed temperature control unit was implemented to a conventional cold spray system and various spray experiments with different powder size cuts were performed to verify results from calculations. Microstructures and mechanical strength of coatings demonstrate that the coating quality can be significantly improved by using well-tuned powder sizes and higher process gas temperatures. The presented optimization strategy, using copper as an example, can be transferred to a variety of spray materials and thus, should boost the development of the cold spray technology with respect to the coating quality. This article was originally published inBuilding on 100 Years of Success, Proceedings of the 2006 International Thermal Spray Conference (Seattle, WA), May 15–18, 2006, B.R. Marple, M.M. Hyland, Y.-Ch. Lau, R.S. Lima, and J. Voyer, Ed., ASM International, Materials Park, OH, 2006.     

Why do fish strand? An analysis of ten years of flow reduction monitoring data from the Columbia and Kootenay rivers,Canada

Stranding of fish due to flow reductions has been documented in the near shore of the Columbia and Kootenay Rivers, Canada, and can result in sub‐lethal or lethal effects on fish. Ten years (1999–2009) of monitoring data have been collected at sites below two hydro‐electric dams (Hugh‐L‐Keenleyside and Brilliant Dam) following flow reductions. A generalized linear mixed effects model analysed the probability of a stranding event in relation to environmental and operational variables including the rate of change in the water levels, the duration of shoreline inundation prior to a reduction (wetted history), the river stage, the magnitude of the reduction, distance downstream from the dam, time of day, day of year (season) and whether a site had been physically altered to mitigate stranding. The results demonstrated statistically significant effects on stranding risk from minimum river stage, day of the year and whether a site had been physically re‐contoured. The combination of investigated factors giving the highest probability of stranding was a large magnitude reduction completed in the afternoon in midsummer, at low water levels when the near shore had been inundated for a long period. This research is significant in its approach to assessing years of ecosystem scale monitoring data and using the modelling results to determine ways for these findings to be applied in regulated river management to minimize fish stranding. It also highlighted data gaps that require addressing and provides ecosystem scale results to compare with stranding studies carried out in mesocosms. © 2014 The Authors. River Research and Applications published by John Wiley & Sons Ltd.     

Backscatter from the data plane – Threats to stability and security in information-centric network infrastructure

Information-centric networking (ICN) raises data objects to first class routable entities in the network and changes the Internet paradigm from host-centric connectivity to data-oriented delivery. However, current approaches to content routing heavily rely on data-driven protocol events and thereby introduce a strong coupling of the control to the data plane in the underlying routing infrastructure. In this paper, threats to the stability and security of the content distribution system are analyzed in theory, simulations, and practical experiments. We derive relations between state resources and the performance of routers, and demonstrate how this coupling can be misused in practice. We further show how state-based forwarding tends to degrade by decorrelating resources. We identify intrinsic attack vectors present in current content-centric routing, as well as possibilities and limitations to mitigate them. Our overall findings suggest that major architectural refinements are required prior to global ICN deployment in the real world.     

Robustness of an aerobic metabolically vinyl chloride degrading bacterial enrichment culture

Degradation of the lower chlorinated ethenes is crucial to the application of natural attenuation or in situ bioremediation on chlorinated ethene contaminated sites. Recently, within mixtures of several chloroethenes as they can occur in contaminated groundwater inhibiting effects on aerobic chloroethene degradation have been shown. The current study demonstrated that metabolic vinyl chloride (VC) degradation by an enrichment culture originating from groundwater was not affected by an equimolar concentration (50 μM) of cis-1,2-dichloroethene (cDCE). Only cDCE concentrations at a ratio of 2.4:1 (initial cDCE to VC concentration) caused minor inhibition of VC degradation. Furthermore, the degradation of VC was not affected by the presence of trans-1,2-dichloroethene (tDCE), 1,1-dichloroethene (1,1-DCE), trichloroethene (TCE), and tetrachloroethene (PCE) in equimolar concentrations (50 μM). Only cDCE and tDCE were cometabolically degraded in small amounts. The VC-degrading culture demonstrated a broad pH tolerance from 5 to 9 with an optimum between 6 and 7. Results also showed that the culture could degrade VC concentrations up to 1,800 μM (110 mg/L).     

Validation of GOES and MODIS active fire detection products using ASTER and ETM+ data

In this study we implemented a comprehensive analysis to validate the MODIS and GOES satellite active fire detection products (MOD14 and WFABBA, respectively) and characterize their major sources of omission and commission errors which have important implications for a large community of fire data users. Our analyses were primarily based on the use of 30 m resolution ASTER and ETM+ imagery as our validation data. We found that at the 50% true positive detection probability mark, WFABBA requires four times more active fire area than is necessary for MOD14 to achieve the same probability of detection, despite the 16× factor separating the nominal spatial resolutions of the two products. Approximately 75% and 95% of all fires sampled were omitted by the MOD14 and WFABBA instantaneous products, respectively; whereas an omission error of 38% was obtained for WFABBA when considering the 30-minute interval of the GOES data. Commission errors for MOD14 and WFABBA were found to be similar and highly dependent on the vegetation conditions of the areas imaged, with the larger commission errors (approximately 35%) estimated over regions of active deforestation. Nonetheless, the vast majority (> 80%) of the commission errors were indeed associated with recent burning activity where scars could be visually confirmed in the higher resolution data. Differences in thermal dynamics of vegetated and non-vegetated areas were found to produce a reduction of approximately 50% in the commission errors estimated towards the hours of maximum fire activity (i.e., early-afternoon hours) which coincided with the MODIS/Aqua overpass. Lastly, we demonstrate the potential use of temporal metrics applied to the mid-infrared bands of MODIS and GOES data to reduce the commission errors found with the validation analyses.     

Hierarchical control of multiple resources in distributed real-time and embedded systems

Real-time and embedded systems have traditionally been designed for closed environments where operating conditions, input workloads, and resource availability are known a priori, and are subject to little or no change at runtime. There is increasing demand, however, for adaptive capabilities in distributed real-time and embedded (DRE) systems that execute in open environments where system operational conditions, input workload, and resource availability cannot be characterized accurately a priori. A challenging problem faced by researchers and developers of such systems is devising effective adaptive resource management strategies that can meet end-to-end quality of service (QoS) requirements of applications. To address key resource management challenges of open DRE systems, this paper presents the Hierarchical Distributed Resource-management Architecture (HiDRA), which provides adaptive resource management using control techniques that adapt to workload fluctuations and resource availability for both bandwidth and processor utilization simultaneously. This paper presents three contributions to research in adaptive resource management for DRE systems. First, we describe the structure and functionality of HiDRA. Second, we present an analytical model of HiDRA that formalizes its control-theoretic behavior and presents analytical assurance of system performance. Third, we evaluate the performance of HiDRA via experiments on a representative DRE system that performs real-time distributed target tracking. Our analytical and empirical results indicate that HiDRA yields predictable, stable, and efficient system performance, even in the face of changing workload and resource availability.     

Combined macro- and microrheometer for use with Langmuir monolayers

A Langmuir monolayer trough that is equipped for simultaneous microrheology and standard rheology measurements has been constructed. The central elements are the trough itself with a full range of optical tools accessing the air-water interface from below the trough and a portable knife-edge torsion pendulum that can access the interface from above. The ability to simultaneously measure the mechanical response of Langmuir monolayers on very different length scales is an important step for our understanding of the mechanical response of two-dimensional viscoelastic networks.     

Neck postures in air traffic controllers with and without neck/shoulder disorders

Prolonged computer work with an extended neck is commonly believed to be associated with an increased risk of neck-shoulder disorders. The aim of this study was to compare neck postures during computer work between female cases with neck-shoulder disorders, and healthy referents. Based on physical examinations, 13 cases and 11 referents were selected among 70 female air traffic controllers with the same computer-based work tasks and identical workstations. Postures and movements were measured by inclinometers, placed on the forehead and upper back (C7/Th1) during authentic air traffic control. A recently developed method was applied to assess flexion/extension in the neck, calculated as the difference between head and upper back flexion/extension. Results: cases and referents did not differ significantly in neck posture (median neck flexion/extension: -10 degrees vs. -9 degrees ; p=0.9). Hence, the belief that neck extension posture is associated with neck-shoulder disorders in computer work is not supported by the present data.     

Effect of pressure on three catalytic partial oxidation reactions at millisecond contact times

The effects of pressure on reactant conversion and product selectivities in three catalytic oxidation systems have been examined at pressures between 1 and > 5 atm. Reaction was sustained autothermally near adiabatic operating conditions at temperatures of 1000°C with residence times over the noble metal catalysts between 10^–4 and 10^–2 s. The three systems investigated were (1) HCN synthesis over Pt-10% Rh gauze catalysts, (2) methane oxidation to synthesis gas (CO and H₂) over rhodium-coated monoliths, and (3) ethane conversion to ethylene over platinum-coated monoliths. We find that selectivities in all three reactions do not change dramatically with approximately a five-fold increase in pressure. This strongly suggests that free radical homogeneous chain reactions are not significant in these processes and that they can be operated reliably above atmospheric pressure. For the synthesis of HCN over Pt-10% Rh gauzes, the selectivity to HCN can be maintained above 0.75 at pressures up to 5.5 atm. Selectivities to synthesis gas (CO and H₂) from a methane-air mixture over a Rh-coated foam monolith at pressures up to 5.5 atm were maintained above 0.90. Over a Pt-coated foam monolith, the selectivity to ethylene from ethane-air and ethane-O₂ mixtures was independent of pressure up to 6.5 atm and conversion rose slightly although it was necessary to maintain constant velocity and residence time over the catalyst to avoid carbon formation.This research was supported by DOE under Grant No. DE-FG02-88ER13878.