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21.
Chatzikokolakis Konstantinos Zissis Dimitrios Spiliopoulos Giannis Tserpes Konstantinos 《GeoInformatica》2021,25(4):601-622
GeoInformatica - The overall aim of this work is to perform a systematic analysis of several off-the-shelf machine learning classification algorithms and to assess their ability to classify Search... 相似文献
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Grigoris Antonis Nikos Manolis Giannis Guido Efie Nikolas Dimitris Manolis Giannis Antonis Panagiotis Constantinos Rena Dimitris 《Data & Knowledge Engineering》2008,64(3):662-687
In this work, we present the design and implementation of a system for proof explanation in the Semantic Web, based on defeasible reasoning. Trust is a vital feature for Semantic Web. If users (humans and agents) are to use and integrate system answers, they must trust them. Thus, systems should be able to explain their actions, sources, and beliefs. Our system produces automatically proof explanations using a popular logic programming system (XSB), by interpreting the output from the proof’s trace and converting it into a meaningful representation. It also supports an XML representation for agent communication, which is a common scenario in the Semantic Web. In this paper, we present the design and implementation of the system, a RuleML language extension for the representation of a proof explanation, and we give some examples of the system. The system in essence implements a proof layer for nonmonotonic rules on the Semantic Web. 相似文献
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The origin of the phenomenon of stress oscillation during step-wise stretching at room temperature for amorphous poly(ethylene terephthalate) (PET) was investigated using vibrational spectroscopy. For the first time, transmission Fourier transform infrared (FT-IR), attenuated total reflection (ATR) FT-IR, and micro-Raman spectroscopies were used in order to investigate the correlation of the orientation of the molecular chains, their conformational transformations, and the appearance of stress-induced crystallization to the phenomenon of stress oscillation during the step-wise stretching procedure. The phenomenon of stress oscillation occurs when amorphous PET is exposed to mechanical stress during which the extension rate is increased in a step-wise manner. This phenomenon leads to the formation of a pattern of opaque and transparent stripes ('striated' or oscillating region), clearly distinguished from the unstretched ('bulk') and the 'necking' regions. Both infrared and Raman spectroscopic investigations revealed that the main conformational transformations and a significant increase of the crystallinity occur simultaneously in the 'striated' region. Polarized infrared experiments showed the presence of increased molecular orientation, which is more profound for the 'intense striated' region. Finally, micro-Raman spectroscopy allowed the study of opaque and transparent stripes individually and showed that the opaque stripes are more crystalline. Thus, our findings provide conclusive experimental support for the theory, which directly correlates the appearance of the stress-oscillation phenomenon with the induction of crystallinity and heat release and is based on Barenblatt's model. Our study also provides new conformational assignments for the infrared bands in PET for the high-frequency region from 3200 to 3800 cm(-1). Specifically, the bands at 3336 cm(-1) and at 3298 cm(-1) have been attributed to the trans and gauche conformations, respectively. 相似文献
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Mpourmpakis G Tylianakis E Papanikolaou D Froudakis GE 《Journal of nanoscience and nanotechnology》2006,6(12):3731-3735
We investigated the effect of the curvature in lithium storage at single-walled carbon nanotubes, with both ab-initio and Molecular Dynamics simulations. Our results show that the carbon rings of nanotubes develop strong cation-pi- interactions with Li ion. These interactions result in positioning the alkali metal cation on top of a phenyl group. By using different types of carbon nanotubes it was revealed that the interaction is not affected by the type or the curvature of the nanotubes. Molecular Dynamics simulations of lithium intercalated nanotube bundles pointed at the fact that the cations remain attached to the nanotubes even at room temperature, with a maximum Li to C ratio of 1:2.1. 相似文献
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Noncontact optical imaging in mice with full angular coverage and automatic surface extraction 总被引:1,自引:0,他引:1
Meyer H Garofalakis A Zacharakis G Psycharakis S Mamalaki C Kioussis D Economou EN Ntziachristos V Ripoll J 《Applied optics》2007,46(17):3617-3627
During the past decade, optical imaging combined with tomographic approaches has proved its potential in offering quantitative three-dimensional spatial maps of chromophore or fluorophore concentration in vivo. Due to its direct application in biology and biomedicine, diffuse optical tomography (DOT) and its fluorescence counterpart, fluorescence molecular tomography (FMT), have benefited from an increase in devoted research and new experimental and theoretical developments, giving rise to a new imaging modality. The most recent advances in FMT and DOT are based on the capability of collecting large data sets by using CCDs as detectors, and on the ability to include multiple projections through recently developed noncontact approaches. For these to be implemented, we have developed an imaging setup that enables three-dimensional imaging of arbitrary shapes in fluorescence or absorption mode that is appropriate for small animal imaging. This is achieved by implementing a noncontact approach both for sources and detectors and coregistering surface geometry measurements using the same CCD camera. A thresholded shadowgrammetry approach is applied to the geometry measurements to retrieve the surface mesh. We present the evaluation of the system and method in recovering three-dimensional surfaces from phantom data and live mice. The approach is used to map the measured in vivo fluorescence data onto the tissue surface by making use of the free-space propagation equations, as well as to reconstruct fluorescence concentrations inside highly scattering tissuelike phantom samples. Finally, the potential use of this setup for in vivo small animal imaging and its impact on biomedical research is discussed. 相似文献
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Emily E. Freeman James J. Neeway Radha Kishan Motkuri Jeffrey D. Rimer Giannis Mpourmpakis 《American Institute of Chemical Engineers》2020,66(12):e17107
Zeolites are porous aluminosilicate materials that find various applications in the chemical industry in separations, catalysis, ion exchange, and so forth. However, despite their widespread use, the reaction mechanisms occurring during zeolite growth are still unclear. Herein, we use density functional theory calculations to gain insights into the thermodynamics of oligomerization, which constitute the initial steps of zeolite growth. By taking into consideration solvent and temperature effects, our results demonstrate that the growth of aluminosilicate systems is significantly more exothermic than their pure silicate counterparts. Under pH neutral conditions, water prefers to dissociate on the early-growth-stage aluminosilicate complexes rather than desorb, thus generating potential Brønsted acid sites on the oligomers. Additionally, (alumino)silicate growth pathways are evaluated in the presence of Na+ cation, as well as the Ca2+ cation for the pure silicate pathway. The presence of cations increases the exothermicity of growth, with Ca2+ exhibiting the most energetically favorable growth environment for the silicate systems. Importantly, we demonstrate through reaction extent analysis that the presence of cations modulates the speciation of the formed oligomers, with Na+ favoring linear species in addition to the generally preferred cyclic ones. Overall, this work provides a fundamental understanding of the thermodynamics of complex reaction paths that occur during early stages of zeolite growth and suggests that the initial growth steps can have significant impact on the final zeolite structure. 相似文献
27.
We introduce a novel diagnostic approach for the uncovering of hidden content in layered documents, based on a photoacoustic imaging set‐up with optimised acoustic detection parameters. By exploiting the laser‐induced ultrasound following the intense absorption of pulsed optical radiation by printed ink, this traditional biomedical imaging method is proven capable of revealing text characters buried under several layers of stacked paper sheets at high spatial resolution and excellent contrast levels. Such a remarkable performance benefits from the effective combination of strong light scattering by paper fibrils and the virtually unobstructed propagation of the generated ultrasonic waves through multiple layers, enabling thus the accurate recording of text, even in double‐sided prints, with minimum shadowing artefacts. The imaging effectiveness, the implementation simplicity, the robustness, and the relatively low‐cost features offered by the proposed photoacoustic modality are anticipated to contribute in its wide adoption by the preservation of cultural heritage community, as a powerful diagnostic tool for the in‐depth investigation of complex multilayered objects. 相似文献
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Aggelos Pappas Athanasios Tsiokanos Ioannis G. Fatouros Athanasios Poulios Dimitris Kouretas Nikos Goutzourelas Giannis Giakas Athanasios Z. Jamurtas 《International journal of molecular sciences》2021,22(7)
Spirulina plantensis is a popular supplement which has been shown to have antioxidant and performance enhancing properties. The purpose of this study was to evaluate the effects of spirulina supplementation on (a) redox status (b) muscle performance and (c) muscle damage following an eccentric bout of exercise that would induce muscle damage. Twenty-four healthy, recreationally trained males participated in the study and were randomly separated into two groups: a spirulina supplementation (6 g per day) and a placebo group. Both groups performed an eccentric bout of exercise consisting of 5 sets and 15 maximum reps per set. Blood was collected at 24, 48, 72 and 96 h after the bout and total antioxidant capacity (TAC) and protein carbonyls (PC) were assessed in plasma. Delayed onset muscle soreness (DOMS) was also assessed at the same aforementioned time points. Eccentric peak torque (EPT) was evaluated immediately after exercise, as well as at 24, 48, 72 and 96 h post exercise. Redox status indices (TAC and PC) did not change significantly at any time point post exercise. DOMS increased significantly 24 h post exercise and remained elevated until 72 h and 96 h post exercise for the placebo and spirulina group, respectively. EPT decreased significantly and immediately post exercise and remained significantly lower compared to baseline until 72 h post exercise. No significant differences between groups were found for DOMS and EPT. These results indicate that spirulina supplementation following a muscle damaging protocol does not confer beneficial effects on redox status, muscle performance or damage. 相似文献
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