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51.
Oregano: chemical analysis and evaluation of its antimalarial, antioxidant, and cytotoxic activities
El Babili F Bouajila J Souchard JP Bertrand C Bellvert F Fouraste I Moulis C Valentin A 《Journal of food science》2011,76(3):C512-C518
Abstract: GC‐FID and GC‐MS analysis of essential oil from oregano leaves (Origanum compactum) resulted in the identification of 46 compounds, representing more than 98% of the total composition. Carvacrol was the predominant compound (36.46%), followed by thymol (29.74%) and p‐cymene (24.31%). Serial extractions with petroleum ether, ethyl acetate, ethanol, and water were performed on aerials parts of Origanum compactum. In these extracts, different chemical families were characterized: polyphenols (gallic acid equivalent 21.2 to 858.3 g/kg), tannins (catechin equivalent 12.4 to 510.3 g/kg), anthocyanins (cyanidin equivalent 0.38 to 5.63 mg/kg), and flavonoids (quercetin equivalent 14.5 to 54.7 g/kg). The samples (essential oil and extracts) were subjected to a screening for antioxidant (DPPH and ABTS assays) and antimalarial activities and against human breast cancer cells. The essential oil showed a higher antioxidant activity with an IC50= 2 ± 0.1 mg/L. Among the extracts, the aqueous extract had the highest antioxidant activity with an IC50= 4.8 ± 0.2 mg/L (DPPH assay). Concerning antimalarial activity, Origanum compactum essential oil and ethyl acetate extract showed the best results with an IC50 of 34 and 33 mg/mL, respectively. In addition, ethyl acetate extract (30 mg/L) and ethanol extract (56 mg/L) showed activity against human breast cancer cells (MCF7). The oregano essential oil was considered to be nontoxic. 相似文献
52.
Claude Descorme Patrick Gélin Michel Primet Christine Lécuyer 《Catalysis Letters》1996,41(3-4):133-138
The adsorption of NO at room temperature on a H-ZSM-5 catalyst exchanged with Pd(NH3)
4
2+
complex and activated in oxygen at 773 K has been examined by FTIR spectroscopy. After the oxidizing treatment, the Pd tetrammine complex decomposed into Pd(II) ions and/or Pd(II) hydroxyl complexes dispersed in the zeolite channels. The subsequent adsorption of NO at room temperature led to the reduction of Pd(II) to Pd(I) entities, resulting in the formation and adsorption of NO2 on H-ZSM-5. The Pd(I) entities were shown to adsorb NO and form mononitrosyl complexes dispersed in the zeolite porosity and characterized by a single infrared absorption band at 1881 cm–1. The Pd(I) mononitrosyl complex was shown to reversibly coordinate water and NO2 molecules. The resulting nitrosyl complex was characterized by a single NO vibration band at 1836 cm–1. 相似文献
53.
54.
Jean Claude Assaf Andr El Khoury Ali Chokr Nicolas Louka Ali Atoui 《International Journal of Dairy Technology》2019,72(2):248-256
This study aimed to develop a new method for detoxification of milk from aflatoxin M1 (AFM1) by using Lactobacillus rhamnosus GG biofilm. After inoculation of milk contaminated with AFM1 into L. rhamnosus GG biofilm, the unbound AFM1 was extracted and quantified by HPLC. The stability of the formed AFM1/biofilm complex using different AFM1 contamination levels of milk was also studied. We found that the percentages of bound AFM1 by L. rhamnosus GG biofilm reached up to 60.74%. While no significant difference in milk proteins content was observed after AFM1 binding, some changes in total dry matter and fat content were noticed. 相似文献
55.
Muoz-Lpez Cesar Nadem Daz-Silvestre Sergio Telles-Padilla J. Guadalupe Rivera-Vallejo Claudia St Thomas Claude Jimnez-Regalado Enrique 《Polymer Bulletin》2020,77(5):2539-2555
Polymer Bulletin - Preparation of associating multiblock copolymer electrolytes mediated by radical addition–fragmentation chain transfer (RAFT) technique has been evaluated and reported in... 相似文献
56.
Nooshin Araghipour Jennifer Colineau Alex Koot Wies Akkermans Jose Manuel Moreno Rojas Jonathan Beauchamp Armin Wisthaler Tilmann D. Märk Gerard Downey Claude Guillou Luisa Mannina Saskia van Ruth 《Food chemistry》2008
The volatile compositions of 192 olive oil samples from five different European countries were investigated by PTR-MS sample headspace analysis. The mass spectra of all samples showed many masses with high abundances, indicating the complex VOC composition of olive oil. Three different PLS-DA models were fitted to the data to classify samples into ‘country’, ‘region’ and ‘district’ of origin, respectively. Correct classification rates were assessed by cross-validation. The first fitted model produced an 86% success rate in classifying the samples into their country of origin. The second model, which was fitted to the Italian oils only, also demonstrated satisfactory results, with 74% of samples successfully classified into region of origin. The third model, classifying the Italian samples into district of origin, yielded a success rate of only 52%. This lower success rate might be due to either the small class set, or to genuine similarities between olive oil VOC compositions on this tight scale. 相似文献
57.
Croizé L Mondelain D Camy-Peyret C Delmotte M Schmidt M 《The Review of scientific instruments》2008,79(4):043101
We have developed a tunable diode laser spectrometer, called SIMCO (spectrometer for isotopic measurements of CO(2)), for determining the concentrations of (12)CO(2) and (13)CO(2) in atmospheric air, from which the total concentration of CO(2) and the isotopic composition (expressed in delta units) delta(13)CO(2) are calculated. The two concentrations are measured using a pair of lines around 2290.1 cm(-1), by fitting a line profile model, taking into account the confinement narrowing effect to achieve a better accuracy. Using the Allan variance, we have demonstrated (for an integration time of 25 s) a precision of 0.1 ppmv for the total CO(2) concentration and of 0.3[per thousand] for delta(13)CO(2). The performances on atmospheric air have been tested during a 3 days campaign by comparing the SIMCO instrument with a gas chromatograph (GC) for the measurement of the total CO(2) concentration and with an isotopic ratio mass spectrometer (MS) for the isotopic composition. The CO(2) concentration measurements of SIMCO are in very good agreement with the GC data with a mean difference of Delta(CO(2))=0.16+/-1.20 ppmv for a comparison period of 45 h and the linearity of the concentration between the two instruments is also very good (slope of correlation: 0.9996+/-0.0003) over the range between 380 and 415 ppmv. For delta(13)CO(2), the comparison with the MS data shows a larger mean difference of Delta(delta(13)CO(2))=(-1.9+/-1.2)[per thousand], which could be partly related to small residual fluctuations of the overall SIMCO instrument response. 相似文献
58.
Declerck Nathalie; Machius Mischa; Joyet Philippe; Wiegand Georg; Huber Robert; Gaillardin Claude 《Protein engineering, design & selection : PEDS》2003,16(4):287-293
Bacillus licheniformis 相似文献
59.
Amédée Djemai Etienne Balan Guillaume Morin Giancarlo Hernandez Jean Claude Labbe Jean Pierre Muller 《Journal of the American Ceramic Society》2001,84(5):1017-1024
Kaolinites with various degrees of structural order and iron content were heated and subsequently analyzed via electron paramagnetic resonance. Iron was present in two different states in the heated materials, either as dilute structural Fe3+ ions or in concentrated Fe3+ phases. During metakaolinization, the environment of dilute Fe3+ ions changed, following modifications of the Al3+ coordination, and the Fe3+ concentration increased. With the breakdown of metakaolinite, the diffusion of Fe3+ ions induced their exsolution in superparamagnetic iron-rich domains (Fe3+ clusters in γ-Al2 O3 and/or Fe3+ oxide nanophases), which produced a decrease in the dilute Fe3+ concentration. The subsequent breakdown of γ-Al2 O3 and the formation of mullite made the dilute Fe3+ concentration increase again, because of the incorporation of Fe3+ ions in the mullite structure. 相似文献
60.
Claude Leger Lucie Fremont Didier Marion Ibrahim Nassour Marie-Françoise Desfarges 《Lipids》1981,16(8):593-600
This paper describes evidence of (n−3) and particularly of 22∶6 (n−3) fatty acid enrichment in trout lipoproteins as well
as in vitellogenin, egg lipovitellin and oil globule. Among the lipoproteins, HDL and LDL were the main forms of blood lipid
transport, whereas phospholipids and cholesteryl esters are the preferential chemical carriers for (n−3) fatty acid transport.
However, cholesteryl esters were less important as esterified fatty acid carriers than in man. Taken together with the data
obtained in mammals, our results suggest that there may be a relationship between EFA activity and the distribution of the
EFA among the lipoprotein lipid fractions in vertebrates, irrespective of the EFA series. Administration of an (n−3) fatty
acid deficient diet for three months prior to trout spawning produced a significant increase in egg lipid content, primarily
as a result of the increase of the oil globule composed almost exclusively of triacylglycerols. This diet decreased the 22∶6
(n−3), as well as the (n−3) fatty acid contents of lipoproteins, lipovitellin, vitellogenin and the oil globule. In contrast,
the (n−3) fatty acid level was always higher in lipoproteins and lipovitellin than in the vitellogenin and the oil globule.
Moreover, the relative levels of 22∶6 (n−3) and total (n−3) fatty acids were quite similar in lipoproteins and lipovitellin
on the one hand, and in vitellogenin and the oil globule on the other. These findings suggest a direct relationship between
the two forms of plasma lipid transport and the two egg compartments. During ovogenesis, dietary lipids seemed to be diverted
from the adipose tissue and essentially deposited in the egg. 相似文献