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91.
Priyanka Marathey Biren Patel Sakshum Khanna Anjali Vanpariya Abhijit Ray 《International Journal of Hydrogen Energy》2021,46(30):16431-16439
Cuprous oxide is one of the inexpensive options of highly efficient visible light-based photocathode for hydrogen generation in photoelectrochemical cells. Highly photoactive cuprous oxide (Cu2O) films are obtained by cathodic electrodeposition using lactate stabilized copper sulphate precursor exhibiting a photo-current density of ~1 mA/cm2 at ?0.1 V vs. RHE. Although Cu2O is a decent choice for photoelectrochemical applications, including hydrogen evolution reaction (HER), it faces serious issues related to photodegradation and instability. To address this issue, a comparative study of two types of thin films, Al (2%)-doped ZnO (AZO) and NiOx (usually, x > 2 at low T to x→1 at high T annealing) as photo-corrosion protective overlayers is made. The improved stability of the protected photoelectrodes is observed as noted from the photocurrent degradation of 3.5%, 0.16% and 0.03% in Cu2O (bare), Cu2O/AZO, and Cu2O/NiOx photocathodes, respectively. Furthermore, the electrochemical impedance spectroscopy reveals that electrode protected with NiOx exhibit faster charge transfer kinetics and minimum photocurrent degradation as compare to the Cu2O/AZO and Cu2O(bare) photoelectrodes, proving its potential in HER kinetics. 相似文献
92.
Multimedia Tools and Applications - This paper focuses on segmentation of ischemic stroke lesion from the dataset contributed by Ischemic Stroke Lesion Segmentation (ISLES)-2015 Sub-acute Ischemic... 相似文献
93.
Source apportionment of ambient VOCs in Delhi City 总被引:7,自引:0,他引:7
Source apportionment using chemical mass balance (CMB) model was carried using a data set of 360 four hourly samples collected at 15 locations of five categories namely residential, commercial, industrial, traffic intersections and petrol pumps during August 2001-July 2002 in Delhi. The results indicate that emissions from diesel internal combustion engines dominate in Delhi. Vehicular exhaust and evaporative emissions also contribute significantly to VOCs in ambient air. Emission of VOCs associated with sewage sludge was also found to contribute to VOCs in Delhi's air. This points to the fact that open defecation and leaking sewage manholes are a problem in all categories of locations. 相似文献
94.
ABSTRACTCervical cancer is one of the major challenges in developing nations like India.In recent years, a lot of research has been done todetect cervical cancer at an early stage through the pap-smear test, human papillomavirus test (HPV), etc. In this study, we have proposed athree-stage cervical cancer classifier to classify cervical cells among normal and abnormal cells using a hybrid ensemble classifier based onfeatures extracted using pre-trained neural networks. Furthermore, this work extends to classify the cells among different levels of dysplastic mainly mild, moderate and severe. The accuracy achieved for 2-class classification among normal and abnormal cells is up to 100% while for 4-class classification among normal, mild, moderate and severe dysplastic cells is up to 98.91% and 99.12% for new and old Herlev university hospital datasets respectively. 相似文献
95.
Bimetallic nanoparticles, a new class of materials for catalysis, were intensively investigated. Highly dispersed Ir–Ni bimetallic nanoparticles with varying mole fractions were synthesized by modified polyol reduction method from the solution of iridium trichloride and nickel chloride in ethylene glycol, which acts as both solvent and reducing agent. The particles were characterized for their size, morphology and composition using various techniques like UV–Vis, Fourier transform infrared (FT-IR), X-ray diffraction (XRD), transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM) and X-ray photo electron spectroscopic (XPS) techniques. The synthesized nanoparticles were in pseudo-spherical morphology and utilized as catalyst for the degradation of dyes. The feasibility of degradation of an azo dye i.e., metanil yellow (MY) in aqueous alkaline medium by hexacynoferrate (III) ions using Ir–Ni bimetals as catalyst, prepared in different molar ratios, was investigated. Results show that Ir–Ni (2:1) bimetals have good catalytic activity and degradation as compared to Ir–Ni (1:2) due to their small size and high stability for the oxidation of MY. 相似文献
96.
Clean Technologies and Environmental Policy - Pharmaceuticals are one of the persistent emerging contaminants that are ubiquitous in the aquatic environment due to their extensive application as... 相似文献
97.
Amino group-terminated poly(methylene diphenylene terephthalamide) (PMDTA) was prepared using a phosphorylation technique that was then converted into Schiff's base coordination polymers by their reaction with Co(II), Ni(II), and Cu(II) complexes of salicylaldehyde [M(SAL)2] and 2-hydroxy-1-naphthaldehyde [M (NAPTHAL)2]. The resulting coordination polymers were characterized by IR, elemental analysis, magnetic susceptibility measurements, and thermogravimetric analysis (TGA). TGA shows that coordination polymers are more thermally stable than is the ligand under similar conditions. On the basis of observed results, an oxygen-and nitrogen-coordinated structure for polyar-amid-metal complexes has been proposed. © 1993 John Wiley & Sons, Inc. 相似文献
98.
Anjali Thakur Balbir Singh Patial Nagesh Thakur 《Journal of Electronic Materials》2017,46(3):1516-1524
In the present paper, the dielectric parameters such as the dielectric constant ε′(ω), dielectric loss ε″(ω) and alternating current (ac) conductivity have been investigated for bulk amorphous chalcogenide Se80?x Te20Pb x (x = 0, 1 and 2) glasses in the frequency range 10 Hz to 500 kHz and within the temperature range from 300 K to 320 K. Dielectric constant ε′(ω) and dielectric loss ε″(ω) are found to be highly frequency (ω) and temperature dependent, and this behavior is interpreted on the basis of Guintini’s theory of dielectric dispersion. The ac conductivity (σ ac) is found to be temperature independent and obey the power law ω s , where s < 1 and decreases as temperature rises. The obtained results are discussed in terms of the correlation barrier hopping model proposed by Elliot. The composition dependence of the dielectric constant, dielectric loss and ac conductivity are also discussed and reported here. 相似文献
99.
Anjali B. Riise T. H. Johansen H. Bratsberg 《Journal of Superconductivity and Novel Magnetism》1997,10(2):151-158
Magnetization loops in the critical state for the critical current density
and
are calculated. The geometry considered is an infinitely long superconductor with a finite cross-section in the shape of
a rectangle or circle. Explicit formulas are derived for the various branches of the complete high-field hysteresis loop.
In the discussion emphasis is put on the behavior of the width, δM, of the hysteresis loop, and a simple graphical method
to fit model parameters to experimental data is outlined. 相似文献
100.
Moni U. Khobragade Ashish Kumar Nayak Anjali Pal 《Clean Technologies and Environmental Policy》2016,18(4):1003-1020
Surfactant-modified alumina (SMA) was prepared and used for the removal of Mn(II), Ni(II), and Cu(II) from aqueous environment. Batch studies were conducted to find out optimum pH of the medium, adsorbent dose of SMA, and contact time. They were further optimized using response surface methodology (RSM). In the present study, a three-factor, three-level Box–Behnken experimental design was used to derive a second-order polynomial equation and construct three-dimensional (3D) surface plots and two-dimensional (2D) contour plots to examine the response. The level of significance for each independent variable and their interaction effects were examined by means of analysis of variance (ANOVA), F test, and Student’s t test results. In addition, the percentage effects of the different factors and their interactions on the removal efficacy were also investigated by plotting a Pareto chart. The models were validated for accurate prediction of the percentage (%) removal by performing numerical optimization. The optimum values of three tested variables were determined at pH 6.2, 8.2, and 5.3; adsorbent dose = 20, 5, and 4 g/L; and contact time = 30, 60, and 75 min for the adsorption of Mn(II), Ni(II), and Cu(II) ions, and the corresponding removal efficiency was found to be 77.04, 93.83, and 97.23 %, respectively. 相似文献