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61.
Bioaccumulation of polycyclic aromatic hydrocarbons (PAHs) from coal tar pitch polluted sediments was predicted by (1) a generic approach based on organic carbon-water partitioning and Gibbs linear free energy relationship (between K(OW) and K(OC)), and (2) measurements of freely dissolved concentrations of PAHs in the sediment pore water, using passive samplers and solid phase extraction. Results from these predictions were compared with those from in vivo bioaccumulation experiments using Nereis diversicolor (Polychaeta), Hinia reticulata (Gastropoda), and Nuculoma tenuis (Bivalvia). Measured sediment/water partition coefficients were higher than predicted by the generic approach. Furthermore, predicted biota-to-sediment accumulation factors (BSAFs) derived from measured pore water concentrations were more in agreement with the bioaccumulation observed for two of the three species. Discrepancies associated with the third species (N. tenuis) were likely a result of particles remaining in the intestine (as shown by microscopic evaluation). These results indicate the importance of conducting site-specific evaluations of pore water concentrations and/or bioaccumulation studies by direct measurements to accurately provide a basis for risk assessment and remediation plans. The importance of knowledge regarding specific characteristics of model organisms is emphasized. 相似文献
62.
W. Siebourg H. Schmid F. M. Rateike S. Anders U. Grigo H. Lwer 《Polymer Engineering and Science》1990,30(18):1133-1139
Birefringence is an important substrate property for optical data storage media. The basic definitions of birefringence and its relation to the chemical nature of polycarbonate are outlined. The polarizability of the monomer unit, expressed in the rheo-optical constant and the degree of remaining polymer chain orientation, determines the level of birefringence in polycarbonate disk substrates. Based on this theory, the theory of blending materials with positive and negative rheo-optical constants Is developed, and the current work with polycarbonate/polystyrene blends is reviewed. The biggest disadvantage of the reviewed system Js that only binary systems with low LCST (lower critical solution temperature) (<240°C) can be formulated. Finally, we report on successful development work of a single-phase blend of a modified polycarbonate with a special styrene-acrylonitrile copolymer. The experimental results are compared with the theoretical expectations, and the implications on the injection molding of disk substrates are discussed. 相似文献
63.
Mark Bissett Anders Barlow Cameron Shearer Jamie Quinton Joseph George Shapter 《Carbon》2012,50(7):2431-2441
Substrates with four different nanotube modifications have been prepared and their electron transport properties measured. Two modification techniques were compared; covalent chemical attachment of both single and multi-walled carbon nanotubes to transparent conductive (fluorine doped tin oxide) glass surfaces and chemical vapour deposition (CVD) growth of both single and multi-walled carbon nanotubes on highly doped conductive silicon wafers. These carbon nanotube modified substrates were investigated using scanning electron microscopy and substrates with nanotubes grown via CVD have a much higher density of nanotubes than substrates prepared using chemical attachment. Raman spectroscopy was used to verify that nanotube growth or attachment was successful. The covalent chemical attachment of nanotubes was found to increase substrate electron transfer substantially compared to that observed for the bare substrate. Nanotube growth also enhanced substrate conductivity but the effect is smaller than that observed for covalent attachment, despite a lower nanotube density in the attachment case. In both modification techniques, attachment and growth, single-walled carbon nanotubes were found to have superior electron transfer properties. Finally, solar cells were constructed from the nanotube modified substrates and the photoresponse from the different substrates was compared showing that chemically attached single-walled nanotubes led to the highest power generation. 相似文献
64.
Anna Andersson Anders Magnusson Suzanne Troedsson Stefan Lundmark Frans H. J. Maurer 《应用聚合物科学杂志》2008,109(4):2269-2274
A combination of intumescent components was evaluated as a novel flame retardant system in a flexible polyurethane foam, and the incorporation of these components gave rise to a significant enhancement of the flame retardant properties of the foam. The heat release rate was lowered at an early stage as well as throughout the fire, the total heat production was decreased and the time to ignition was prolonged. Mechanical measurements of the foam revealed enhanced properties in terms of stiffness accompanied by a large decrease in elongation at break as compared with a reference foam. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
65.
This paper presents a fully automatic system intended to detect leaks of dielectric fluid in underground high-pressure, fluid-filled (HPFF) cables. The system combines a number of artificial intelligence (AI) and data processing techniques to achieve high detection capabilities for various rates of leaks, including leaks as small as 15 l per hour. The system achieves this level of precision mainly thanks to a novel auto-tuning procedure, enabling learning of the Bayesian network – the decision-making component of the system – using simulated leaks of various rates. Significant new developments extending the capabilities of the original leak detection system described in [1] and [2] form the basis of this paper. Tests conducted on the real-life HPFF cable system in New York City are also discussed. 相似文献
66.
Sigrid Lædre Ole Edvard Kongstein Anders Oedegaard Frode Seland Håvard Karoliussen 《International Journal of Hydrogen Energy》2012
Stainless steel is attractive as material for bipolar plates in proton exchange membrane fuel cells, due to its high electrical conductivity, high mechanical strength and relatively low material and processing cost. Potentiostatic and potentiodynamic tests were performed in H2SO4 solutions on AISI 316L stainless steel bipolar plates with etched flow fields. The effect of pH and presence of small amounts of fluoride and chloride on the corrosion rate and interfacial contact resistance of the stainless steel bipolar plate were investigated. The tests performed in electrolytes with various pH values revealed that the oxide layer was thinner and more prone to corrosion at pH values significantly lower than the pH one expects the bipolar plate to experience in an operating proton exchange membrane fuel cells. The use of solutions with very low pH in such measurements is thus probably not the best way of accelerating the corrosion rate of stainless steel bipolar plates. By use of strongly acidic solutions the composition and thickness of the oxide layer on the stainless steel is probably altered in a way that might never have happened in an operating proton exchange membrane fuel cell. Additions of fluoride and chloride in the amounts expected in an operating fuel cell (2 ppm F− and 10 ppm Cl−) did not cause significant changes for neither the polarization- nor the contact resistance measurements. However, by increasing the amount of Cl− to 100 ppm, pitting was initiated on the stainless steel surface. 相似文献
67.
C. Anders S. Della-Negra M. Fallavier V. Obnorsky S. Yarmiychuk H.M. Urbassek 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2009,267(15):2503-2514
Au nanoislet targets (∅ 2-60 nm) were bombarded by 200 keV polyatomic ions (40 keV/atom), which deposit their energy mainly in the nuclear stopping mode: ∑(dE/dx)n = 30 keV/nm and ∑(dE/dx)e = 2 keV/nm. The matter desorbed in the form of nanoclusters was registered by TEM. The total transfer of matter was determined by neutron-activation analysis. The total yield of the ejected gold reached high values of up to 2.6 × 104 atoms per Au5 ion. The major part (2 × 104 atoms per ion Au5) of the emission is in the form of nanoclusters. The results are compared with the data of similar experiments with 1 MeV Au5 (200 keV/atom) and other projectiles. The analysis of the experimental data and the comparison to molecular-dynamics simulation results of the desorption process show that the desorption of Au nanoislets is induced by their melting, build-up of pressure and thermal expansion. 相似文献
68.
Ho Sn Lam G. Zimmermann G. Anders G. Bach D. Rennecke W. Zychlinski 《Advanced Synthesis \u0026amp; Catalysis》1985,327(5):759-766
Studies on Thermal Conversion of Phenyleyclopentane, -hexane, -heptane, and -octane in the Gas Phase The title compounds were pyrolyzed from 700 to 780°C in a metallic laboratory tubular reactor in the presence of steam. The reaction products were analyzed by gas chromatography and by a combination of gas chromatography and mass spectrometry. From the phenylcyclanes tested, more than 65 hydrocarbons could be detected in the liquids, besides gaseous reaction products. In most cases unambiguous structures could be derived by using different analytical methods. As typical initial-step products phenylcyclenes, ω-phenyl-1-alkenes and 1-phenyl-1-alkenes are formed by dehydrogenation and isomerization of the title compounds. The detection of phenylalkenes corresponds well with the isomerization of unsubstituted cyclanes to the corresponding α-olefines described in former papers. 相似文献
69.
Tingting Gu Jesper Just Katrine Tang Stenz Yan Yan Peter Sieljacks Jakob Wang Thomas Skjaerlund Groennebaek Jesper Emil Jakobsgaard Emil Rindom Jon Herskind Anders Gravholt Thomas Ravn Lassen Mathias Jrgensen Rikke Bk Eugenio Gutirrez-Jimnez Nina Kerting Iversen Peter Mondrup Rasmussen Jens Randel Nyengaard Malene Mller Jrgensen Frank de Paoli Hans Erik Btker Jrgen Kjems Kristian Vissing Kim Ryun Drasbek 《International journal of molecular sciences》2022,23(6)
Ischemic conditioning and exercise have been suggested for protecting against brain ischemia-reperfusion injury. However, the endogenous protective mechanisms stimulated by these interventions remain unclear. Here, in a comprehensive translational study, we investigated the protective role of extracellular vesicles (EVs) released after remote ischemic conditioning (RIC), blood flow restricted resistance exercise (BFRRE), or high-load resistance exercise (HLRE). Blood samples were collected from human participants before and at serial time points after intervention. RIC and BFRRE plasma EVs released early after stimulation improved viability of endothelial cells subjected to oxygen-glucose deprivation. Furthermore, post-RIC EVs accumulated in the ischemic area of a stroke mouse model, and a mean decrease in infarct volume was observed for post-RIC EVs, although not reaching statistical significance. Thus, circulating EVs induced by RIC and BFRRE can mediate protection, but the in vivo and translational effects of conditioned EVs require further experimental verification. 相似文献
70.
Investigation of potential extreme load reduction for a two‐bladed upwind turbine with partial pitch 下载免费PDF全文
This paper presents a wind turbine concept with an innovative design combining partial pitch with a two‐bladed (PP‐2B) turbine configuration. Special emphasis is on extreme load reduction during storm situations at standstill, but operational loads are also investigated. In order to compare the loads and dynamics of the PP‐2B turbine, a partial pitch three‐bladed (PP‐3B) turbine and a normal pitch regulated three‐bladed (3B) turbine are introduced on the basis of solidity similarity scaling. From the dynamic comparisons between two‐ and three‐bladed turbines, it has been observed that the blade vibrations are transferred differently from the rotor to the tower. For a three‐bladed turbine, blade vibrations seen in a fixed frame of reference are split with ±1P only. A two‐bladed turbine has a similar split of ±1P but also includes contributions on higher harmonics (±2P, ±3P, … etc.). Further on, frequency split is also seen for the tower vibrations, where an additional ±2P contribution has been observed for the two‐bladed turbine. Regarding load comparisons, the PP‐2B turbine produces larger tower load variations because of 2P excitation during the operational cases. However, extreme loads are reduced by approximately 20% for the PP‐2B and 18% for the PP‐3B compared with the 3B turbine for the parked condition in a storm situation. Moreover, a huge potential of 60% is observed for the reduction of the extreme tower bottom bending moment for the PP‐2B turbine, when the wind direction is from ±90° to the turbine, but this also requires that the turbine is parked in a T‐configuration. © 2014 The Authors. Wind Energy published by John Wiley & Sons, Ltd. 相似文献