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21.
M. Ueda 《Reactive and Functional Polymers》1996,30(1-3):125-132
A series of ordered polymers can be prepared by direct polycondensation of nonsymmetric monomers using diphenyl(2,3-dihydro-2-oxo-3-benzothiazolyl)phosphonate (1) as a condensing agent. The methodology and requirements for the preparation of ordered polymer are first presented. Then, the following ordered polymer syntheses are described: (1) ordered polyamides (head-to-head or tail-to-tail) from a symmetric monomer and a nonsymmetric monomer. (2) the ordered polyamide (head-to-tail) from a symmetric monomer and a nonsymmetric monomer. (3) the ordered (-abcd-) polymer from a pair of two symmetric monomers and a nonsymmetric monomer. (4) the ordered (-abcdef-) polymer from nonsymmetric monomers, XabX, YcdY, and ZefZ. 相似文献
22.
Koji Tsukuma Kuniyoshi Ueda Masahiko Shimada 《Journal of the American Ceramic Society》1985,68(1):4-C-5
Composites of Al2 O3 and Y2 O3 partially-stabilized ZrO2 were isostatically hot-pressed using submicrometer powders as the starting material. The addition of Al2 O3 resulted in a large increase in bending strength. The average bending strength for a composite containing 20 wt% Al2 O3 was 2400 MPa, and its fracture toughness was 17 MN·w−3/2 相似文献
23.
An addition reaction of maleic anhydride with polypropylene takes place in the presence of radical reagents or sunlight. The initial rate of the reaction was proportional to the concentration of polypropylene and maleic anhydride, and one-half power of the concentration of the radical reagents. The increase in the temperature from 80 to 120°C increased the rate of the reaction and di-cumyl peroxide was effective as a radical reagent for this reaction. Ionic crosslinked rubber-like polymers were obtained from the reaction of maleic polypropylene with some alkali metal compounds. They showed the characteristic absorption band due to ? COO? in their infrared spectra. 相似文献
24.
25.
Imoto Taiji; Ueda Tadashi; Tamura Tomohiro; Isakari Yoshimasa; Abe Yoshito; Inoue Makoto; Miki Takeyoshi; Kawano Keiichi; Yamada Hidenori 《Protein engineering, design & selection : PEDS》1994,7(6):743-748
Mutations around His15 which lie far away from the active site,stimulated glycol chitin activity of lysozyme at physiologicaltemperature. Del-Argl4Hisl5 lysozyme, a mutant lysozyme whoseArgl4 and Hisl5 were deleted together, and has the highest activityamong these mutant lysozymes, had a similar binding abilityto a trimer of N-acetyl-glucosamine, a substrate analogue, relativeto native lysozyme. This suggests that the increased activitywas due to an increased kcat in the catalysis reaction. TheH-D exchange rate of the N-1 proton in the Trp63 which is locatedin the active site cleft, was enhanced in the Del-Argl4Hisl5lysozyme, while 2-D proton NMR analysis revealed no conformationalchange around Trp63. We conclude that some sort of fluctuationat the active site might be required for the manifestation ofactivity. This theory is supported by the finding that the Del-Argl4Hisl5lysozyme showed a shift in temperature dependency of activityto lower temperatures compared with that of native lysozyme. 相似文献
26.
Catalytic performances of various metal molybdates were tested in the oxidative dehydrogenation of propane to propene with molecular oxygen under an atmospheric pressure. Most of the molybdates tested promoted the selective oxidative conversion of propane to propene and among them cobalt and magnesium molybdates were found highest in the activity and selectivity. It was also found that their catalytic activities were highly sensitive to the catalyst composition, and it turned out that Co0.95MoO
x
and Mg0.95MoO
x
catalysts which have slightly excess molybdenum showed the highest activity in the oxidative dehydrogenation of propane. Under the optimized reaction conditions, higher reaction temperatures and lower partial pressures of oxygen, these catalysts gave 60% selectivity to propene at 20% conversion of propane. Since the molybdates having the surface enriched with molybdenum oxide tended to show high activity for the propane oxidation, surface molybdenum oxide clusters supported on metal molybdate matrix seem to be the active sites for the selective oxidative dehydrogenation of propane. 相似文献
27.
Maeda Yoshitake; Koga Hiroshi; Yamada Hidenori; Ueda Tadashi; Imoto Taiji 《Protein engineering, design & selection : PEDS》1995,8(2):201-205
To increase the folding yield of concentrated reduced lysozyme,we developed a renaturation method by means of dialysis fromconcentrated urea with redox agents. After lysozyme was incubatedin the reducing buffer (8 M urea solution) with oxidized glutathione,renaturation of reduced lysozyme was started by dialysis againstthe dialyzing buffer containing 8 M urea with redox agents.The urea concentration of the dialyzing bottle was graduallydiluted with dialyzing buffer without urea at a flow rate of0.1 ml/min by high pressure pump. Using this systematic dialysis,a concentration as high as 5 mg/ml of reduced lysozyme couldbe renaturated in 80% yield, while the folding yield was <5%even at a concentration of 1 mg/ml using a conventional rapiddilution method [Goldberg et al. (1991) Biochemistry, 30, 27902797].Therefore, it was concluded that gentle removal of urea fromdenatured proteins, dissolved in concentrated urea solution,by means of dialysis should be useful to renature denaturedproteins effectively. 相似文献
28.
Miyahara Daiki Ueda Itaru Hayashi Yu-ichi Mizuki Takaaki Sone Hideaki 《International Journal of Information Security》2021,20(5):729-740
International Journal of Information Security - Card-based cryptography is an attractive and unconventional computation model; it provides secure computing methods using a deck of physical cards.... 相似文献
29.
Bo Ren Longbiao Wang Liang Lu Yuma Ueda Atsuhiko Kai 《Multimedia Tools and Applications》2016,75(9):5093-5108
The performance of speech recognition in distant-talking environments is severely degraded by the reverberation that can occur in enclosed spaces (e.g., meeting rooms). To mitigate this degradation, dereverberation techniques such as network structure-based denoising autoencoders and multi-step linear prediction are used to improve the recognition accuracy of reverberant speech. Regardless of the reverberant conditions, a novel discriminative bottleneck feature extraction approach has been demonstrated to be effective for speech recognition under a range of conditions. As bottleneck feature extraction is not primarily designed for dereverberation, we are interested in whether it can compensate for other carefully designed dereverberation approaches. In this paper, we propose three schemes covering both front-end processing (cascaded combination and parallel combination) and back-end processing (system combination). Each of these schemes integrates bottleneck feature extraction with dereverberation. The effectiveness of these schemes is evaluated via a series of experiments using the REVERB challenge dataset. 相似文献
30.