Vapor Condensation on Curvilinear Disk-Shaped Fin at Microgravity

A problem of the film type condensation of the pure vapor on disk-shaped fin is considered with taking into account the essential influence of the capillary forces. Calculations for FC-72 condensation on such fin have been performed at microgravity conditions. A hump on the condensate film thickness curve is occurred on the concave part of the fin due to the additional curvature of the disc shape. The results have been compared to results for straight fin with the same surface area of condensation. Condensate outflow from the disk-shaped film is greater than from straight fin.     

Sonochemical Preparation and Properties of Pt–3Y-TZP Nano-Composites

A uniformly aggregated 3 mol% yttria-stabilized tetragonal zirconia nano-powder (3Y-TZP) was prepared using thermal hydrolysis and the ultrasonic deagglomeration technique. The possibility of nano-engineering of Pt–3Y-TZP composite aggregates was studied. The as-synthesized Pt nano-particles (∼2 nm) were impregnated into zirconia nano-aggregates (20–45 nm). The morphology manipulation technique allowed production of the composite zirconia-based aggregates in which a significant fraction of the Pt particles was embedded into the densified zirconia aggregates. Using the colloidal technique and low-temperature (1150°C) sintering, we prepared the Pt-zirconia (0.5–1.5 wt% of platinum) nano-composites with average 3Y-TZP grain sizes of 120 nm, and with the platinum grains size in the range of 20–60 nm. The catalytic properties of composite Pt–3Y-TZP nano-composites were studied and described.     

Alkynes Carbonylation Reactions in Solutions of Palladium Complexes as a New Class of Oscillatory Processes

This article dedicated to study of few oscillating reactions in homogeneous systems. The experimental data and preliminary mechanism are reported. The authors affirm they find new type of oscillating processes—the reactions of carbonylation.     

Biclustering in data mining

Biclustering consists in simultaneous partitioning of the set of samples and the set of their attributes (features) into subsets (classes). Samples and features classified together are supposed to have a high relevance to each other. In this paper we review the most widely used and successful biclustering techniques and their related applications. This survey is written from a theoretical viewpoint emphasizing mathematical concepts that can be met in existing biclustering techniques.     

One-Circuit Stabilization of Millimeter-Wave Solid-State Oscillator by Quasi-Optical Resonator

The construction and operating characteristics of the highly stabilized millimeter wave IMPATT oscillator are described. The frequency stability is 8.1 × 10^-7 at 115 GHz. The output power is no less than 15 mW. The sphere-corner-echelette open resonator have been used for oscillator stabilization. This approach is also adaptable to the Gunn oscillator.     

Revisiting tetranitrophenolsulfonephthalein

Among the vast series of phenolsulfonephthalein dyes, the nitro derivatives and especially 3,3′,5,5′‐tetranitrophenolsulfonephthalein (nitrophenol crimson) remain practically unexplored, whereas the halogen and alkyl derivatives have been studied comprehensively. This striking difference is probably due to the enormous influence of the four NO₂ groups on the properties of the dye. As a result, the protolytic behaviour is unlike even that of tetrabromo phenolsulfonephthalein, and the recognised scheme of acid–base and tautomeric equilibrium of the sulfonephthaleins is unable to explain it. The molecular form H₂R was isolated as a sultonic tautomer, and an X‐ray crystal structure analysis was carried out. Our studies of the UV‐vis absorption spectra in water, methanol, dimethyl sulfoxide, acetonitrile, acetone, and dichloromethane, as well as in aqueous micellar solutions of surfactants, allowed us to evaluate the true molar absorptivity of the dianion R^2?, and to elucidate the enormous tendency to form yellow trianionic carbinol ROH^3?, even in the presence of traces of H₂O. Nuclear magnetic resonance and electrospray data confirm the proposed scheme of ionisation and tautomerism of nitrophenol crimson.     

Development of a new procedure for precise determination of viral aerosol lethal dose (ALD50) for birds

This paper describes a new method for precise determination of viral aerosol lethal dose (ALD₅₀) and reports the results obtained for birds exposed by H5N1 Avian influenza A strain under controlled laboratory conditions. The reported method utilizes our recently developed personal bioaerosol sampler capable of monitoring viable virus concentration in the ambient air. Up to six laboratory animals could be located in a specially designed aerosol chamber and exposed in parallel by an airborne strain of interest to generate the amount of data sufficient for representative statistical analysis. A concentration of viable airborne virus was measured by the personal aerosol samplers directly in the breathing zone of each particular bird. The results show a very low inter-sampler variation used for each particular run, which was confirmed by a single factor ANOVA test undertaken for all six personal samplers involved in each experiment. As was shown, the difference in amount of viruses collected by all samplers during each particular run was not statistically significant. It was found that the ALD₅₀ for approximately 400-g birds exposed to H5N1 Avian influenza A strain A/Chicken/Suzdalka/Nov-11/2005 was around 26.5 FFU (focus forming units).     

Rational parameters of profiled workpieces for an upsetting process

An upsetting process of specially profiled workpieces was proposed. Modeling of a workpiece upsetting, profiled as a cylinder with conical and cylindrical ledges was done using a finite element method. During the upsetting of these workpieces, buckling occurs. Schemes of upsetting a workpiece with conical ledges result in a decrease in the irregularity of the equivalent strain distribution in the longitudinal section. This scheme produces a zone of minimal equivalent strain decrease in the workpiece. It was found that during the upsetting process of the workpiece with a conical ledge on the lateral surface and in the center, compressive stresses appear. These stresses contribute to the closure of voids in an ingot during the upsetting process. Rational workpiece parameters were found which allow the production of forgings with minimal irregularity of equivalent strain distribution, minimal formation of a barrel, and a favorable stress state in the workpiece. Experimental research, which confirms the advantages of upsetting specially profiled workpieces, was done.     

Effects of B2O3 on Crystallization,Structure, and Heat Transfer of CaO-Al2O3-Based Mold Fluxes

Metallurgical and Materials Transactions B - The reaction between traditional CaO-SiO2-based mold fluxes and high-Al steel inevitably changes flux composition, and, consequently, flux properties....