Editor's Note

Journal of Materials Synthesis and Processing -     

Temperature Profile Analysis in Combustion Synthesis: I, Theory and Background

An analysis of the use of temperature profiles in the determination of the kinetic parameters of self-sustaining combustion synthesis is provided. Two mathematical approaches are discussed. In the first approach, the analysis focuses on the initial portion of the temperature profile and thus emphasizes the kinetics of the initial stages ( η ≲ 1.0) of this process. The second approach emphasizes both the initial and final stages of the process ( η ∼ 1.0). With the simultaneous measurements of the velocity of the combustion wave, temperature profile analysis provides values for the effective thermal diffusivity of the reactants.     

Mortality of urban and rural young children with cerebral palsy in Bangladesh

In January 1994 mass antibiotic prophylaxis was undertaken in the contiguous villages of Deir el-Asad and B'ine in northern Israel (combined population of 11600) in response to a prolonged outbreak of serogroup B meningococcal infection with an overall annual rate of 37.4 cases of infection per 100000 residents. The average case fatality rate in the villages was 23% compared with 11% in Israel during the same period. Neisseria meningitidis group B was identified in 9 of 13 (69%) cases. Seven of these were subtype P1.7,16. The persistence of the outbreak with its accompanying public reaction prompted the establishment of an intervention programme that included antibiotic prophylaxis for the whole community with monitoring for pharyngeal carriage of meningococci in a stratified sample of the population. The objectives were to achieve a reduction of carriage of the outbreak strain and to reduce morbidity and mortality. A total of 1036 pharyngeal swabs were taken 1 day before and 6 weeks after treatment. Antibiotic prophylaxis was administered in one dose: children under 5-years-old received ceftriaxone i.m.; all others received oral ciprofloxacin. Overall, 96% of the population received treatment. The carriage rate was 8.3% prior to treatment (three serogroup B:14:P1.7,16), and 1.3% afterwards (one serogroup B:14:P1.7,16). The intervention failed to eradicate carriage of the putative outbreak strain, or to reduce the incidence and fatality rates in the villages. The outbreak finally terminated in late 1996. Public health professionals should bear this experience in mind when faced with prolonged, localized, nonexplosive outbreaks of meningococcal disease associated with low carriage rates of the outbreak strain.     

Cost-benefit analysis and ideas for cost sharing of groundwater irrigation: evidence from north-eastern Ethiopia

The government of Ethiopia has invested in groundwater development for smallholder irrigation in the Raya Valley and Kobo Valley, north-eastern Ethiopia, where the hydrogeological potential is large but not fully developed. A cost-benefit analysis shows that investment in deep groundwater irrigation development is viable at a 9.5% discount rate in 75% of the wells. Assuming full cost recovery of capital investment, the annual payment rates (annuity) that irrigation users should pay over the wells’ service life (25 years) were estimated. It is recommended that future investment be based on cost sharing rather than full cost recovery to facilitate uptake and address financial realities.     

Functional finishing and coloration of textiles with nanomaterials

Global demand for functional textiles is continually increasing for both conventional as well as advanced technical applications. Nanomaterials have the potential to transform the textile industry by imparting multifunctional properties such as physical, chemical and biological self‐cleaning, ultraviolet (UV) protection, wrinkle resistance and coloration to textiles without compromising the inherent characteristics of the substrate. This review highlights some of the major applications of nanomaterials to textile substrates to obtain different functional properties. Possible side effects of the nanomaterials on textiles are also reviewed, along with potential hazards to humans and the environment.     

An adaptive handoff strategy for cognitive radio networks

Spectrum handoff plays an important role in spectrum management as it is the process of seamlessly shifting the on-going transmission of a secondary user (SU) to a free channel without degrading the quality of service. In this paper, we develop an adaptive handoff algorithm that allows an SU to detect the arrival of a primary user (via sensing) and adapt to a reactive or a proactive handoff strategy accordingly. The adaptive handoff scheme first allows an SU to decide whether to stay and wait on current channel or to perform handoff. Then, in case of handoff, an SU intelligently shifts between proactive or reactive handoff modes based on primary use (PU) arrival rate. Further, a PU prioritized Markov approach is presented in order to model the interactions between PUs and SUs for smooth channel access. Numerical results show that the proposed handoff scheme minimizes the blocking probability, number of handoffs, handoff delay and data delivery time while maintaining channel utilization and system throughput at maximal level compared to simple reactive and proactive schemes.     

Effect of femtosecond laser beam angle and formed shape on surface roughness and shear bond strength between zirconia and resin cement

Achieving adhesion between resin cement and zirconia requires pretreatment of the surface. This in vitro study aimed to evaluate the effect of femtosecond laser beam angle and the shape of the formed surfaces, on the roughness and shear bond strength (SBS) of resin cement to zirconia ceramic. Seventy Y-TZP ceramic specimens were divided into seven groups (n = 10). A femtosecond laser irradiation was performed on the ceramic surface of three shapes (spiral (SP), square (SQ) and circular (CI) and at two angles (30 and 90°) to give SP-30, SQ-30 and CI-30 and SP-90, SQ-90 and CI-90, respectively. After treatment, the surface roughness of all specimens was evaluated using a profilometer. One specimen from each group was analysed using a scanning electron microscope. The bonded specimens were thermocycled 5000 times and then an SBS test was performed. Kruskal-Wallis and Mann-Whitney U tests were used to analyse surface roughness and SBS values. The control group had statistically lower surface roughness (R_a) values than the treated groups (p < 0.05). SP-30 and SQ-30 laser treated specimens showed higher R_a values than the other specimens. Statistically significant SBS values (p = 0.000) were observed between the groups. All laser treated samples showed greater SBS compared to the control group. SP-30, SQ-30 and SQ-90 groups showed the highest SBS values. Within the limitations of this experimental study, the highest mean values for R_a and SBS were achieved with SP and SQ surfaces using a 30° angle laser beam.     

MOPT: list-based heuristic for scheduling workflows in cloud environment

Cloud computing is a popular and widely adopted computing platform for the execution of scientific workflows as it provides flexible infrastructure and offers access to collection of autonomous heterogeneous resources. Effective scheduling of computationally complex workflows which contain many interconnected tasks is a complex problem and becomes more challenging in cloud environment. Optimal solutions can be obtained by considering not only the heterogeneity of computation costs involved, but also by taking into account the communication costs among the tasks in a way that schedule length of the application is reduced. In this paper, we propose a list scheduling heuristic, namely minimal optimistic processing time (MOPT), with optimized duplication approach. The additional feature is introduced for the entry task and is applied only in scenarios in which duplication is more practical and effective. The prioritization phase of the proposed work is based on an optimistic processing time matrix that is used for ranking of the tasks. The algorithm has same time complexity as state-of-the-art existing algorithms, but notable improvements are acquired in terms of makespan and other performance evaluation parameters. Extensive experimental analysis of the proposed algorithm is carried out using synthesized graphs and graphs from the real-world applications. The results prove that MOPT achieves quality schedules with reduced makespans. As communication cost among the tasks grows higher, performance of the proposed algorithm becomes more effective, thus providing the evidence that the MOPT algorithm is well-suited for communication-intensive applications.

     

Catalytic transesterification of corn oil and tristearin using immobilized lipases from Thermomyces lanuginosa

Thermomyces lanuginosa lipase was employed to catalyze the interesterification reaction between corn oil and tristearin at 45°C in a solvent-free system. HPLC and GC analyses were used to monitor both the distribution of TAG and the concentrations of MAG, DAG, and TAG as the reaction progressed. The positional distribution of the FA residues in the interesterified product was also determined for comparison to that of the original corn oil. Two different weight ratios of corn oil to tristearin were studied. Addition of molecular sieves to the reaction medium reduced the percentage of hydrolysis from 15 to 7. In order to improve the results obtained with Lipozyme TL IM, an immobilization of T. lanuginosa lipase was carried out. At a solids loading of 10% (w/w), the new immobilized lipase reduced the concentration of tristearin from 6 to 0.5% in only 30 min.