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991.
Yunpeng Wang Zhaoyun Wang Changyi Zhao Hongjun Wang Jinzhong Liu Jialan Lu Dehan Liu 《Journal of Petroleum Geology》2007,30(4):339-356
In this paper we derive kinetic parameters for the generation of gaseous hydrocarbons (C1‐5) and methane (C1) from closed‐system laboratory pyrolysis of selected samples of marine kerogen and oil from the SW Tarim Basin. The activation energy distributions for the generation of both C1‐5 (Ea = 59‐72kcal, A = 1.0×1014 s?1) and C1 (Ea = 61‐78kcal, A = 6.06×1014 s?1) hydrocarbons from the marine oil are narrower than those for the generation of these hydrocarbons from marine kerogen (Ea = 50‐74kcal, A = 1.0×1014 s?1 for C1‐5; and Ea = 48‐72kcal, A=3.9×1013 s?1 for C1, respectively). Using these kinetic parameters, both the yields and timings of C1‐5 and C1 hydrocarbons generated from Cambrian source rocks and from in‐reservoir cracking of oil in Ordovician strata were predicted for selected wells along a north‐south profile in the SW of the basin. Thermodynamic conditions for the cracking of oil and kerogen were modelled within the context of the geological framework. It is suggested that marine kerogen began to crack at temperatures of around 120°C (or 0.8 %Ro) and entered the gas window at 138°C (or 1.05 %Ro); whereas the marine oil began to crack at about 140 °C (or 1.1 %Ro) and entered the gas window at 158 °C (or 1.6%Ro). The main geological controls identified for gas accumulations in the Bachu Arch (Southwest Depression, SW Tarim Basin) include the remaining gas potential following Caledonian uplift; oil trapping and preservation in basal Ordovician strata; the extent of breaching of Ordovician reservoirs; and whether reservoir burial depths are sufficiently deep for oil cracking to have occurred. In the Maigaiti Slope and Southwest Depression, the timing of gas generation was later than that in the Bachu Arch, with much higher yields and generation rates, and hence better prospects for gas exploration. It appears from the gas generation kinetics that the primary source for the gases in the Hetianhe gasfield was the Southwest Depression. 相似文献
992.
993.
基于WebGIS的水资源管理系统的开发与实现 总被引:1,自引:0,他引:1
本文在WebGIS实现技术的基础上,结合水资源管理的需求,以ArcIMS为地理信息服务平台,设计开发了水资源管理系统,实现了地图数据和专题数据的网络共享,促进了水资源的数字化管理,并在都江堰水资源管理中取得了良好的应用效果。 相似文献
994.
Biofiltration is an efficient technology for treatment of gaseous waste. Its disadvantages, however, include large volume of bioreactor and slow adaptation to fluctuating concentrations in waste gas. Catalytic oxidation offers a high destructive efficiency at relatively low operating temperature and small unit. A bench scale system integrated with a biofilter and a catalytic oxidation unit for the treatment of gases containing o-xylene was investigated in this study. The catalytic oxidation unit was packed with Cu/Al2O3 catalyst. The results showed that 90% of o-xylene could be removed in the biofilter at the load below 38.2 g m−3 h−1. High o-xylene concentration in inlet gas resulted in an overload of the biofilter. Using the Cu/Al2O3 catalytic oxidation unit, the concentration of o-xylene could be reduced evidently. The combination of the chemical and microbial processes not only led to a high and stable efficiency of o-xylene conversion, but also improved capacity resisting the shock loads. The Cu/Al2O3 was studied for o-xylene oxidation in temperature range of 90–320 °C. The o-xylene conversion was improved correspondingly with the increasing of oxidation temperature. The reaction mechanism of o-xylene oxidation on Cu/Al2O3 was also investigated using diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). 相似文献
995.
文章主要针对我省河道堤防的现状、存在的主要问题和对问题产生原因的分析,提出了相应的解决途径和可以采取的主要措施。 相似文献
996.
为适应城市发展需要,必须加强城市水利工作,通过对舒兰市水资源现状分析,对解决城市供水水源工程建设的措施进行探讨。 相似文献
997.
针对目前弱碱型三元复合驱采出液油水分离困难的问题,通过测试模拟采出液的水相弹性模量及热沉降后水相含油量、油层上部含水率和脱出水量,考察了模拟三元复合驱采出液中残留的碱、表面活性剂和聚合物对采出液水相流变性及油水分离特性的影响。结果表明,水相弹性模量主要取决于所含聚合物的相对分子质量和含量。并且随聚合物相对分子质量和含量的增加而增大。当表面活性剂含量相同时,采出液在经过90min热沉降后,脱出水量随水相弹性模量的增大明显降低。水相弹性模量可以代替聚合物含量和相对分子质量这2个因素与脱出水量进行关联。碱、表面活性剂和聚合物含量增大,油层上部含水率和水相含油量均呈现变大的趋势。采出液乳化严重、稳定性提高、油水分离困难。弱碱型三元复合驱采出液可采用热化学脱水工艺实现油水分离。 相似文献
998.
999.
1000.
综述了苯直接氧化制苯酚的国内外研究进展.苯直接氧化制苯酚主要方法有N2O氧化法、O2氧化法、H2O2氧化法.从反应条件、催化剂的制备、催化剂活性以及失活等方面对这些方法的优缺点进行了评述.苯直接氧化制苯酚工艺实现工业化要解决的问题包括催化剂的制备、反应条件优化以及后处理的简化、原料的获得等,制备出价廉、高效、可重复利用的催化剂是研究的重点. 相似文献