Extraction and separation of Ga(Ⅲ) and T1(Ⅰ) or In(Ⅲ) and T1(Ⅰ) from chloride media with CA-12 in sulphonating kerosene

The extraction behavior and mechanism of gallium(Ⅲ) and thallium(Ⅰ) or indium(Ⅲ) and thallium(Ⅰ) with Sec-octylphenoxy acetic acid (CA-12) from hydrochloric acid solution in sulphonating kerosene were studied. Optimum extraction conditions were evaluated from critical study of various experimental parameters and the probable composition of the extracted species is ascertained from lg D-lg C plots. The effects of different ions on the determination of these ions were examined.     

New development in welding thin-shell aluminum alloy structures with high strength

From the viewpoint of welding mechanics, two new welding methods-welding with trailing peening and welding with trailing impactive rolling were introduced. For aluminum alloy thin-shell structures with high strength, welding will lead to hot cracking, poor joint and distortion. In order to solve them, trailing impactive device was used behind welding torch to impact the different positions of welded joints, thus realizing the welding with free-hot cracking, low distortion and join tstrengthening. By use of impactive rolling wheels instead of peening heads, the outlook of welded specimen can be improved and stress concentration at weld toes can be reduced. Equipment of this technology is simple and portable. It can used to weld sheets, longitudinal and ring-like beams of tube-like structures, as well as the thin-shell structures with closed welds such as flanges and hatches. So the technology has the wide application foreground in the fields of aviation and aerospace.     

Ni-Cr-Al纳米晶合金在1000℃的高温氧化行为

研究了纳米晶Ni-Cr-Al合金的高温氧化行为，发现与 铸态合金不同，随成分不同纳米晶合金在1000℃氧化时，氧化物可分为四个区：A单一Al2O3区；B复杂氧化膜含一连续Al2O3内层区； C复杂氧化膜含内氧化物区；D Al2O3和NiAl2O4共生区.纳米晶化明显扩展了Al2O3生成区的成份范围.     

机械合金化Ag-30Cr合金在0.1 Mpa纯氧气中的氧化

采用机械合金化方法制备了Cr含量为30％(质量分数)的两相颗粒极细的Ag—Cr合金，在700℃，800℃及0．1MPa纯氧气中氧化时，机械合金化Ag-30Cr合金外层为Ag层，其下方为复合氧化物AgCrO2，最内层为连续的Cr2O3，这一结构不同于粗晶粒粉末冶金Ag—Cr合金的复杂的混合氧化膜。这主要是由于晶粒的细化加快了Cr颗粒的溶解，加速了Cr从合金到膜的扩散，从而有效地促进Cr2O3层的形成。     

INVESTIGATION ON CRYSTALLIZATION KINETICS OF Pd-Cu-Si GLASS

The crystallization kinetics of Pd-Cu-Si glass was studied by means of diferential scanningcalorimetry-Ⅱ.According to Kissinger peak shift meth(?)d and Arrhenius equation,theapparent activation energy was calculated.The crystallization kinetics follows Johnson-Mehl-Avrami equation with n=3.0 within 0.15相似文献   

Resistance welding of carbon fibre reinforced polyetheretherketone composites using metal mesh and PEI film

Weldability of polyetheretherketone( PEEK) with polyetherimide( PEI) is tested. And carbon fiber reinforced PEEK laminates are resistance welded using stainless steel mesh heating element. The effects of the welding time and welding pressure on the lap shear strength of joints are investigated. Results show that PEEK can heal with PEI well in welding condition and the lap shear strength of PEEK/CF(carbon fibre) joint increases linearly with welding time, but reaches a maximum value when welding pressure ranging from 0.3 MPa to 0.5 MPa with constant welding time. The fracture characteristics of surface are analyzed by SEM techniques, and four types of fracture modes of lap shear joints are suggested.     

TiAl/Ti/V/Cu/40Cr钢扩散连接界面组织结构对接头强度的影响

研究了TiAl/Ti/V/Cu/40Cr钢的扩散连接，结果显示：在TiAl/Ti界面处形成了对接头强度有利的Ti3Al TiAl双相层及Ti固溶体层，而Ti/V/Cu/40Cr界面处未出现金属间化合物及其它脆性相，接头最高拉伸强度可达420MPa，接近TiAl母材。     

防锈油膜在5% Na2SO4溶液中的半导体导电行为

采用电位—电容法及Mott-Schottky分析技术研究了自腐蚀电位条件下防锈油膜在5% Na2SO4溶液中失效过程的导电机制转变行为.防锈油膜在5% Na2SO4溶液中的失效过程存在半导体导电特征，随着浸泡时间的延长，防锈油膜从浸泡初期的p型半导体转变为n型半导体，转变过程中，防锈油膜中出现两个空间电荷过渡层.随着浸泡时间的延长，防锈油膜中的空间电荷层厚度皆逐渐减小，载流子密度则逐渐增加，并且计算了不同转变时期防锈油膜中的电子给体（ND）和电子受体（NA）密度大小.     

NUMERICAL STUDY OF HYDRODYNAMICS OF MULTIPLE TANDEM JETS IN CROSS FLOW

The hydrodynamics of a single jet and four tandem jets in a cross flow are simulated by using the Computational Fluid Dynamics (CFD) software Fluent. The realizable model is used to close the Reynolds-Averaged equations. The flow characteristics of the jets, including the jet trajectory, the velocity field and the turbulent kinetic energy are obtained with various jet-to-cross flow velocity ratios in the range of 2.38-17.88. It is shown that a single jet penetrates slightly deeper than the first jet in a jet group at the same , although the difference decreases with the decrease of . It is also found that the way in which the velo-city decays along the centerline of the jet is similar for both a single jet and the first jet in a group, and the speed of the decay increases with the decrease of . The downstream jets in a group are found to behave differently due to the sheltering effect of the first jet in the group. Compared with the first jet, the downstream jets penetrate deeper into the cross flow, and the velocity decays more slowly. The circulation zone between the two upstream jets in the front is stronger than those formed between the downstream jets. The Turbulent Kinetic Energy (TKE) sees a distinct double-peak across the cross-sections close to each nozzle, with low values in the jet core and high values in the shear layers. The double-peak gradually vanishes, as the shear layers of the jet merge further away from the nozzle, where the TKE assumes peaks at the jet centerline.     

EXPERIMENTAL STUDY ON SEDIMENT RESUSPENSION IN TAIHU LAKE UNDER DIFFERENT HYDRODYNAMIC DISTURBANCES

Contaminants resuspension in sediments induced by wind-wave could influence the water quality in shallow lakes. Resuspension of surface sediments from the Zhushan Bay, Taihu Lake was simulated under different wind forcing by using a pneumatic annular flume in this study. Acoustic Doppler Velocimeter (ADV) was used to measure flow velocity at each wind speed, and the characteristics of sediment resuspension were studied with the layered sampling technology. The experimental results show that the flow velocity increases with wind speed obviously and 6m/s is a critical wind speed which affected hydrodynamic conditions significantly. The distribution of flow velocity and water depth is different from that in ordinary open channel. With the enhanced hydrodynamic factors, the Suspended Solids Concentration (SSC) in water increases accordingly, and the incipient velocity of sediment resuspension is about 0.21 m/s. Based on the analysis of wind speed and average SSC in water column, the quantitative relationship is obtained. The SSC of the bottom layer is higher than the content of surface layer under different hydrodynamic conditions, and there are similar distributions between SSC and flow velocity in different water layers.