Resources for research: the 1991 census of population

The author discusses population censuses in general and describes their utility for research, with a focus on the arrangements under which researchers at institutes of higher education are being provided with data sets from the census. "Although much of the discussion will be specific to the United Kingdom, many of the issues raised will be important in other countries."     

The effect of iron additions on the microstructure and properties of the “Tribaloy” Co-Mo-Cr-Si wear resistant alloys

The effect of iron additions in the range 5 to 15 wt % iron inclusive on the microstructure and properties of two Co-Mn-Cr-Si wear resistant alloys (Tribaloys T400 and T800) has been investigated. Iron additions were found to stabilize the f c c form of the cobalt solid solution, to give a fully eutectic matrix and to decrease the volume fraction of the primary Laves phase. These microstructural modifications have little effect on the plane strain fracture toughness but result in a significant increase in the modulus of rupture. The addition of iron induces only minor changes in the corrosion and oxidation resistance of T800, whereas the performance of T400 deteriorates.     

Decomposition of solid explosives by laser irradiation: A mass spectrometric study

Experimental investigations have been made in which single crystals of solid explosives such as cyclotrimethylene trinitramine, RDX, pentaerythritol tetranitrate, PETN, AgN₃ and Pb(N₃)₂, were irradiated with a focused laser beam of wavelength 266 nm and duration 5 nsec in an ultra high vacuum system housing a fast and sensitive time-of-flight mass spectrometer. From the mass spectra (both +ve and -ve ions) of the chemical species obtained, possible decomposition schemes of RDX and PETN have been proposed. For silver and lead azides, the laser irradiation did not cause explosions if the power density was sufficiently low, but micrometre size craters were formed. In the mass spectra of AgN₃ products N₃ ^– and silver cluster ions, Ag _n ⁺, have been found for the first time. It has been suggested that such investigations may possibly throw some light on our understanding of the reactions taking place in a deflagration/detonation wave.     

Equilibrium and dynamics of acetylene sorption in multiwalled carbon nanotubes

Multiwalled carbon nanotubes (MWCNT) were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and by adsorption of N₂ and acetylene. The dynamics of acetylene sorption was studied by frequency response spectroscopy. The average tube dimension and the shell number were determined from a statistical evaluation of the TEM images. This value agreed with that obtained from XRD via the Scherrer equation only if a shape factor of 0.49 was used. The diffusion of acetylene in the nanotubes of the MWCNT sample was found to be the rate-controlling step of the sorption process. Relationships between the tube dimensions and the equilibrium and dynamic sorption properties were demonstrated.     

A Glass–Ceramic Derived from High TiO2-Containing Slag: Microstructural Development and Mechanical Behavior

A novel glass–ceramic material was developed from the melt of a TiO₂-containing iron-making slag with additional waste glass. The high percentage (∼20 wt% TiO₂) of this network-modifying oxide has promoted a crystallization of the parent glass, resulting in a fine-grained, homogeneous polycrystalline material with high mechanical properties ( E =120 GPa, flexural strength=∼180 MPa, and Vickers hardness=7 GPa) after a heat treatment at 1100°C for 2 h. The room temperature and elevated temperature fracture toughness were also studied. The main crystalline phases of the glass–ceramic material were of the pyroxene series until heat-treatment temperature reached 1000°C, at which titanium-rich perovskite and armalcolite crystals became the dominant phases. The end material is high-strength, aesthetically acceptable (metallic gray or opaque brown colored), and suitable for structural and architectural applications.     

Effect of vanadium and chromium on the microstructural features of V–Cr–Mn–Ni spheroidal carbide cast irons

The objective of this investigation is to study the influence of vanadium（5.0wt%–10.0wt%） and chromium（0–9.0wt%） on the microstructure and hardness of Cr-V-Mn-Ni white cast irons with spheroidal vanadium carbides. The alloys＇ microstructural features are presented and discussed with regard to the distribution of phase elements. The structural constituents of the alloys are spheroidal VC, proeutectoid cementite, ledeburite eutectic, rosette-shaped carbide eutectic（based on M7C3）, pearlite, martensite, and austenite. Their combinations and area fraction（AF） ratios are reported to be influenced by the alloys＇ chemical composition. Spheroidized VC particles are found to be sites for the nucleation of carbide eutectics. Cr and V are shown to substitute each other in the VC and M7C3 carbides, respectively. Chromium alloying leads to the formation of a eutectic（γ-Fe ＋ М7С3）, preventing the appearance of proeutectoid cementite in the structure. Vanadium and chromium are revealed to increase the total carbide fraction and the amount of austenite in the matrix. Cr is observed to play a key role in controlling the metallic matrix microstructure.     

In vivo fluorescence microscopy for the assessment of microvascular reperfusion injury in small bowel transplants in rats

With the use of in vivo fluorescence microscopy we have analyzed microvascular reperfusion injury of small bowel isograft transplants in rats. Following 1 hr cold storage in University of Wisconsin solution, the small bowel was transplanted heterotopically, and the intestinal microcirculation was quantitatively analyzed 20-60 min after onset of reperfusion. The intestinal grafts' capillary perfusion of both the mucosa and the circular and longitudinal muscles was not found altered when compared with the intestinal capillary perfusion of sham-operated controls. In contrast, leukocyte-endothelial cell interaction, including leukocyte rolling (40 +/- 5%) and sticking (280 +/- 100 mm-2) in submucosal postcapillary venules, was significantly increased when compared with nontransplanted controls (12 +/- 8% and 20 +/- 10 mm-2, P < 0.01 and P < 0.05, respectively). Leukocyte-endothelial cell interaction was associated with a marked alteration of lymphatic capillary drainage, as indicated by the low functional density of lymphatic microvessels of 10.2 +/- 6.1 cm-1 (P < 0.01 vs. sham-operated controls (39.2 +/- 6.1 cm-1)). From these results we propose that leukocyte-endothelial cell interaction, not capillary "no-reflow," is the primary step in the manifestation of microvascular reperfusion injury following a short period of cold ischemia in small bowel grafts.     

Estimating and projecting the populations of urban communities

"The author describes a model for estimating and projecting the populations of communities living in small areas within cities. The model provides a means of updating the demographic inputs needed for projection between censuses and means of developing scenarios of demographic change and housing development. The method for estimating small-area populations between censuses is evaluated with recently published 1991 [U.K.] Census data. Single-year age-group detail is provided and the associated databases are embedded in a flexible user interface. Illustrative projections are discussed and interpreted for the northern English city of Bradford.... The model, although particular to districts of West Yorkshire, has been specified in a general way and could be adapted for use with any British district."     

Recent advances in amperometric glucose biosensors for in vivo monitoring

The substance-use, positive health practices, diet and eating habits, driving behaviours and preventive health care practices of 113 nurses living in the southeast of England were assessed by means of a postal questionnaire. Females were generally more compliant than males with most of the behaviours assessed. Females reported taking greater risks with driving behaviours by an occasional tendency to "drink and drive". Many males reported both a lack of knowledge of how to self-examine their testicles for signs of cancer and little compliance with this behaviour. This sample reported more smoking and alcohol use than previously reported samples of American nurses and U.K. norms. The nurses in this sample were more likely to avoid foods high in cholesterol, add fibre to their diet and be more vigilant in their driving behaviour than American nurses and British non-nurses.