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11.
Benjapol Kongsombut Wei Chen Atsushi Tsutsumi Wiwut Tanthapanichakoon Tawatchai Charinpanitkul 《Korean Journal of Chemical Engineering》2008,25(4):838-845
Rapid expansion of supercritical solution (RESS) was used for preparing polymer particles and polymer coating of ultra fine
powders. The polymer of pharmaceutical interest was Poly(lactic-co-glycolic acid) (PLGA with PLA: PGA ratio of 85: 15 and
MW of 50,000–75,000) and the simulated core particles were 1.4-μm SiO2 and 70-nm TiO2 particles. The supercritical solution was prepared by dissolving PLGA in supercritical carbon dioxide with ethanol as a cosolvent.
Supercritical solution of CO2-PLGA was sprayed through capillary nozzles to ambient conditions, resulting in formation of submicron PLGA particles. Similarly,
rapid expansion of supercritical solution of CO2-PLGA suspended with the core particles could provide solvent evaporation and deposition of submicron PLGA particles on the
surface of the core particles, resulting in the formation of coating films on dispersed particles of SiO2 and agglomerates of TiO2. The influences of the core particle size, spray nozzle diameter as well as powder-to-polymer weight ratio were also investigated
and discussed with respect to the coating performance. 相似文献
12.
13.
Vikkasit Atimuttigul Siriporn Damrongsakkul Wiwut Tanthapanichakoon 《Korean Journal of Chemical Engineering》2006,23(4):672-677
Short-oil alkyd resins were prepared by using five different oil types: corn oil, rice bran oil, sunflower oil, soya bean
oil and dehydrated castor oil (DCO). Among these, soya bean oil gave alkyd resin with the darkest color because oxidation
occurred. Auto air-dried coating films were developed and it was shown that film prepared from rice bran oil-based alkyd exhibited
the longest drying time due to the low number of double bonds compared to other and the extra natural antioxidant in rice
bran oil. DCO alkyd-based film revealed the shortest drying time, the greatest hardness but the poorest alkali and sea-water
resistance. This is caused by the differences in the type of fatty acid and double bonds, the high amount of double bonds
being in DCO. In addition, an increase in the reaction temperature only had an influence on darkening the alkyd color and
decreasing the drying time of coating films. In terms of technical properties and cost competitiveness, soya bean oil-based
film is the best. Coating films derived from all oil-based alkyds, except DCO, look promising for use in surfboard manufacturing. 相似文献
14.
Sarawut Rimdusit Passarin Jongvisuttisun Chanchira Jubsilp Wiwut Tanthapanichakoon 《应用聚合物科学杂志》2009,111(3):1225-1234
Effects of resin compositions in ternary systems of benzoxazine, epoxy, and phenolic novolac resins on processability, and thermomechanical properties of their carbon fiber‐reinforced composites are investigated. At suitable range of resin mass ratios, the ternary mixtures can provide a relatively wide processing window ranging from 50 to 200°C by maintaining their low A‐stage viscosity for a relatively long time which is crucial in the fiber preimpregnating process. Furthermore, relatively long shelf‐life of the ternary mixtures stored at room temperature (~ 30°C) up to 270 days is obtained with minimal effect on their processability. The optimum mass ratio of B : E : P was determined to be 3 : 6 : 2, i.e., BEP362 resin. Finally, the carbon fiber composite based on BEP362 was found to exhibit substantial enhancement in its mechanical properties. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
15.
Nawin Viriya-Empikul Noriaki Sano Takeyuki Kikuchi Sareeya Bureekaew Wiwut Tanthapanichakoon Tawatchai Charinpanitkul 《Journal of Industrial and Engineering Chemistry》2010,16(1):63-67
The titanate nanostructures with high UV absorption characteristics could be fabricated by hydrothermal method within a temperature range of 90–150 °C. TEM, XRD, BET analyses, and UV–vis spectroscopy were employed to elucidate the synthesized titanate nanostructure characteristics which were microstructure, phase transformation, specific surface area, and band gap energy, respectively. With an increase in the hydrothermal treating temperature from 90 to 120 °C, the specific surface area of titanate nanostructures was increased from 83 to 258 m2/g, while the band gap energy of titanate nanostructures was increased from 3.44 to 3.84 eV and then slightly decreased to 3.81 eV at 150 °C. The fabricated titanate nanostructures could exhibit higher UV adsorption capability but lower photocatalytic activity when compared with that of commercial TiO2 powders. 相似文献
16.
T. Charinpanitkul P. Limsuwan C. Chalotorn N. Sano T. Yamamoto P. Tongpram P. Wongsarivej A. Soottitantawat W. Tanthapanichakoon 《Journal of Industrial and Engineering Chemistry》2010,16(1):91-95
Synergetic removal of aqueous phenol by decomposition with ozone and adsorption on activated carbon was experimentally investigated. To enhance phenol removal performance, two activated carbons (AC1 and AC2) with BET surface areas of 1106 and 1150 m2 g?1 and average pore diameters of 2.3 and 1.7 nm, respectively, were employed. While the slowest initial removal of phenol was achieved with introduction of ozone only, the much better removal of phenol was obtained with utilization of activated carbon with ozone. Some intermediate products, which were detected as total organic carbon (TOC), were found to remain even after phenol was completely decomposed. Regarding to higher mesopore fraction, AC1 could better remove intermediates than AC2. With the synergetic performance of AC1 and ozone it was found that the highest removal of phenol and TOC was up to 100% and 89%, respectively. 相似文献
17.
Adsorption of phenol and reactive dye from aqueous solution on activated carbons derived from solid wastes 总被引:6,自引:0,他引:6
Nakagawa K Namba A Mukai SR Tamon H Ariyadejwanich P Tanthapanichakoon W 《Water research》2004,38(7):1791-1798
Activated carbons were produced from several solid wastes, namely, waste PET, waste tires, refuse derived fuel and wastes generated during lactic acid fermentation from garbage. Activated carbons having various pore size distributions were obtained by the conventional steam-activation method and via the pre-treatment method (i.e., mixture of raw materials with a metal salt, carbonization and acid treatment prior to steam-activation) that was proposed by the authors. The liquid-phase adsorption characteristics of organic compounds from aqueous solution on the activated carbons were determined to confirm the applicability of these carbons, where phenol and a reactive dye, Black5, were employed as representative adsorbates. The hydrophobic surface of the carbons prepared was also confirmed by water vapor adsorption. The characteristics of a typical commercial activated carbon were also measured and compared. It was found that the activated carbons with plentiful mesopores prepared from PET and waste tires had quite high adsorption capacity for large molecules. Therefore they are useful for wastewater treatment, especially, for removal of bulky adsorbates. 相似文献
18.
Wongsarivej Pratarn Tongprem Pornsiri Swasdisevi Thanit Charinpanitkul Tawatchai Tanthapanichakoon Wiwut 《中国化学工程学报》2011,19(1):76-82
A three phase fluidized bed reactor was used to investigate the combined effect of adsorption and oxidation for phenolic wastewater treatment.Aqueous solutions containing 10 mg·L 1of phenol and ozone were continuously fed co-currently as upward flow into the reactor at constant flow rate of 2 and 1 L·min1,respectively.The phenolic treatment results in seven cases were compared:(a)O3 only,(b)fresh granular activated carbon(GAC),(c) 1st reused GAC,(d)2nd reused GAC,(e)fresh GAC enhanced with O3,(f)1st reused GAC enhanced with O3,and (g)2nd reused GAC enhanced with O3.The phenolic wastewater was re-circulated through the reactor and its concentration was measured with respect to time.The experimental results revealed that the phenolic degradation using GAC enhanced with O3 provided the best result.The effect of adsorption by activated carbon was stronger than the effect of oxidation by ozone.Fresh GAC could adsorb phenol better than reused GAC.All cases of adsorption on GAC followed the Langmuir isotherm and displayed pseudo second order adsorption kinetics.Finally,a differential equation for the fluidized bed reactor model was used to describe the phenol concentration with respect to time for GAC enhanced with O3.The calculated results agree reasonably well with the experimental results. 相似文献
19.
Anongnat Somwangthanaroj Khamkaew Photyotin Sarintorn Limpanart Wiwut Tanthapanichakoon 《Polymer-Plastics Technology and Engineering》2013,52(11):1173-1180
EVOH/clay nanocomposite films were prepared by using four types of surfactants to treat surface of clay because the surfactants were expected to affect the degree of clay dispersion in the EVOH matrix, which would in turn affect the properties of film. The nanocomposite films that contained the single alkyl tail with two repeating units of oxyethylene surfactants or single alkyl tail surfactant showed higher tensile strength, tensile modulus and elongation at break than those with 15 repeating units of oxyethylene surfactants or those with double alkyl tail surfactant. 相似文献
20.
Enzymatic hydrolysis of rawhide using papain and neutrase 总被引:1,自引:0,他引:1
Siriporn Damrongsakkul Kongpob Ratanathammapan Kittinan Komolpis Wiwut Tanthapanichakoon 《Journal of Industrial and Engineering Chemistry》2008,14(2):202-206
Rawhide split was hydrolysed separately by two proteolytic enzymes, papain and neutrase. The effects of enzymatic conditions of the hydrolysis reaction were investigated. During the first 10 min of the enzymatic hydrolysis, the yield of the hydrolysed protein increased sharply, then it slowly increased or became essentially constant due to the limited availability of the substrate. The optimum hydrolysis conditions of papain and neutrase for highest protein yield are at 70 °C, pH 6–7 and 40–50 °C, pH 6–7, respectively. The product from papain hydrolysis is a gelatin with low gel strength and viscosity, while that from neutrase hydrolysis is collagen hydrolysate with viscosity as low as water. This is considered to indicate that longer fragments of protein are obtained from papain hydrolysis than that from neutrase implying different mechanisms of papain and neutrase hydrolysis. 相似文献