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61.
In this study, AOT [sodium bis(2-ethylhexyl) sulfosuccinate] combined with fluorinated cosurfactant or alcohol was used to form a water-in-CO2 (W/C) microemulsion. The amount of water uptake in the microemulsion was closely related to the PFPE-PO4/AOT (P/A) ratio. The stability of the microemulsion decreased with the amount of water. Lower temperature and higher pressure stabilize W/C microemulsions. The extraction efficiencies of metals (Cd, Co, Cu, Pb, Zn), when this W/C microemulsion method was used, exceeded 90% (AOT + octanol). The efficiencies for the extraction of Eu, La, and Sr could exceed 94% (AOT + PFPE-PO4) in sc-CO2. 相似文献
62.
Partial acidulation of phosphate rock (PR) or compaction of PR with soluble P fertilizers can improve the usefulness of unreactive PR for use as P fertilizer. A greenhouse study was conducted to evaluate nonconventional phosphate fertilizers derived from a low reactive Sukulu Hills PR from Uganda. Raw PR (which contained 341.0 g kg–1 Fe2O3), beneficiated or concentrate PR, partially acidulated PR (PAPR) and PR compacted with triple superphosphate (TSP) were evaluated. Compacted materials had a P ratio of PR:TSP = 50:50. PAPR materials were made by 50% acidulation with H2SO4. TSP was used as a reference fertilizer. Fertilizers were applied to an acidic (pH = 5.4) Hiwassee loam (clayey, kaolinitic, thermic Rhodic Kanhapludults) at rates of 0, 50, 100, 200, 300 and 400 mg P kg–1 soil. Two successive corn (Zea mays L.) crops were grown for 6 weeks. Compacted concentrate PR + TSP and raw PR + TSP were 94.4 and 89.7% as effective as TSP, respectively, in increasing dry-matter yields for the first corn crop. PAPR from the concentrate was 54.8% as effective as TSP. Raw PR, concentrate PR and the PAPR from the raw PR were ineffective in increasing dry-matter yields. The same trends were obtained when P uptake was used to compare effectiveness. Ineffectiveness of the raw PR and its corresponding PAPR was attributed to a high Fe2O3 content in the raw PR. Bray I and Pi paper were found to be nearly equally suitable at estimating available P in the soils treated with responsive fertilizer materials. Mehlich 1 overestimated available P in soil treated with raw PR, concentrate PR or the PAPR from the raw PR. 相似文献
63.
Thermoplastic polyvinyl alcohol/multiwalled carbon nanotube composites: Preparation,mechanical properties,thermal properties,and electromagnetic shielding effectiveness 下载免费PDF全文
Jia‐Horng Lin Zheng‐Ian Lin Yi‐Jun Pan Chien‐Teng Hsieh Chien‐Lin Huang Ching‐Wen Lou 《应用聚合物科学杂志》2016,133(21)
This study uses the solution mixing method to combine plasticized polyvinyl alcohol (PVA) as a matrix, and multiwalled carbon nanotubes (MWCNTs) as reinforcement to form PVA/MWCNTs films. The films are then laminated and hot pressed to create PVA/MWCNTs composites. The control group of PVA/MWCNTs composites is made by incorporating the melt compounding method. Diverse properties of PVA/MWCNTs composites are then evaluated. For the experimental group, the incorporation of MWCNTs improves the glass transition temperature (Tg), crystallization temperature, Tc), and thermal stability of the composites. In addition, the test results indicate that composites containing 1.5 wt % of MWCNTs have the maximum tensile strength of 51.1 MPa, whereas composites containing 2 wt % MWCNTs have the optimal electrical conductivity of 2.4 S/cm, and electromagnetic shielding effectiveness (EMI SE) of ?31.41 dB. This study proves that the solution mixing method outperforms the melt compounding method in terms of mechanical properties, dispersion, melting and crystallization behaviors, thermal stability, and EMI SE. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43474. 相似文献
64.
Chun-Yen Lai Tzu-Chiao Chien Ting-Yi Lin Teng Ke Shih-Han Hsu Yun-Ju Lee Chien-ying Su Jeng-Tzong Sheu Ping-Hung Yeh 《Nanoscale research letters》2014,9(1):281
In this work, we have demonstrated that amorphous ZnO nanobranches (a-ZnO NBs) could spontaneously react from the crystalline ZnO NWs (c-ZnO NWs) at specific humid environment. The spontaneous reaction mechanism and result can be analyzed by humidity controlling and optical microscope (OM)/scanning electron microscope (SEM)/Kelvin probe force microscopy (KPFM)/transmission electron microscopy (TEM) system. We can make the c-ZnO NWs spontaneous reaction happen at different humid environments and suppress the a-ZnO NBs spontaneous reaction by oxygen/hydrogen plasma surface passivation. The hydrogen plasma surface treatment also can improve the UV sensing sensitivity more than twofold. This work provides the mechanism and methods of the a-ZnO NBs spontaneous growth and offers the passivation treatment for strengthening and enhancing ZnO-based nanodevice application in humid environment and UV light detection, respectively. 相似文献
65.
BACKGROUND: It is difficult to clearly distinguish and identify specific species of the Lactobacillus casei group using phenotypic and genotypic (16S ribosomal DNA sequence analysis) techniques alone. Some species of this group are probiotic and are widely used in the food and feed industries. The objective of this study was to develop species‐specific primers based on randomly amplified polymorphic DNA (RAPD) fingerprinting for species identification within the closely related L. casei group of bacteria. RESULTS: Three random primers termed OPT‐14, OPA‐11 and OPT‐16 were developed for analysis. The primer pairs each produced a species‐specific band found only in the tested Lactobacillus rhamnosus, Lactobacillus paracasei subsp. tolerans and Lactobacillus zeae isolates respectively. These specific fragments were then sequenced for further analysis. The species‐specific primers were designed according to cloned sequencing, which was employed for polymerase chain reaction (PCR) with the template DNA of Lactobacillus strains. Single 102, 179 and 451 bp species‐specific bands were found only in L. rhamnosus, L. paracasei subsp. tolerans and L. zeae respectively. CONCLUSION: Using PCR, the novel species‐specific primers have been shown to rapidly, accurately and effectively identify species of L. rhamnosus, L. paracasei subsp. tolerans and L. zeae from within the L. casei group of probiotic bacteria. Copyright © 2009 Society of Chemical Industry 相似文献
66.
W. -M. Chien D. Chandra A. K. Helmy J. Franklin C. J. Rawn 《Journal of Phase Equilibria and Diffusion》2005,26(2):115-123
The solid-state phase transitions in ammonium nitrate (AN)-potassium nitrate (KN) system, and the equilibrium AN-KN phase
diagram have been determined by using differential scanning calorimetry and high-temperature in situ x-ray diffractometry.
Sample preparation was performed in a special “dry room” with very low humidity. A single phase region (AN III) with no phase
transitions to 373 K was observed in the composition range 5 to 20% KN; this is critical for use in air bag gas generators.
The high-temperature KN phase (KN I) has a wide range of stability from 20 to 100 wt.% KN. There are one eutectic, two eutectoid,
three peritectoid, and one congruent transformations in this phase diagram. Two new nonstoichiometric phases were found at
lower temperatures in the mid-composition range between the AN and KN terminal solid solutions. Details of the phase equilibria
are presented. 相似文献
67.
Because various phosphate (P) fertilizers differ widely in their solubility, it is commonly observed that crop response to P fertilizers varies under the same soil and crop conditions. Furthermore, a major problem encountered in the methods for determining the relative effectiveness (RE) of water-insoluble P fertilizer (e.g., phosphate rock) with respect to water-soluble P fertilizers, e.g., single superphosphate (SSP) and triple superphosphate (TSP), is that their growth response curves are usually nonlinear and often do not share a common maximum yield. In this paper, we review and discuss the advantages and disadvantages of the three most commonly used methods for calculating the RE of phosphate rock with respect to TSP (or SSP). The three methods are vertical comparison, horizontal (substitution rate) comparison, and linear-response comparison. 相似文献
68.
Kuo‐Hui Wu Yi‐Yin Kuo Chien‐An Chen Yi‐Ling Huang Han‐Mou Gau 《Advanced Synthesis \u0026amp; Catalysis》2013,355(5):1001-1008
Aryl addition reactions of ArTi(O‐i‐Pr)3 to aromatic, heteroaromatic, or α,β‐unsaturated ketones are described, producing tertiary alcohols in good to excellent enantioselectivities of up to 97% ee. The structure of the dititanium complex [(i‐PrO)2Ti{μ‐(S)‐BINOLate}(μ‐O‐i‐Pr)TiPh(O‐i‐Pr)2] [(S)‐ 4 ] that simultaneously bears a chiral directing ligand and a nucleophile is reported. Complex (S)‐ 4 possesses a pocket structure and has been illustrated as the key active species for addition reactions of both aldehydes and ketones. Mechanistic and stereochemical insights concerning addition reactions of organometallic reagents to organic carbonyls are rationalized based on the pocket structure and pocket size of (S)‐ 4 . 相似文献
69.
70.
Abstract CORDIC is a rotation based computation kernel algorithm which has been found to be very attractive for problems which require intensive, frequent evaluations of elementary functions. This paper addresses the implementation issues in the design of a VLSI CORDIC processor for digital signal processing and numerical linear algebra computations. The first part of this paper will discuss various design considerations for practical CORDIC algorithms. In particular, we have established criteria for the selection of nearly optimal shift sequences which are crucial to the performance of the CORDIC computation. The various design considerations of a CORDIC processor are discussed. Finally, the architecture of a prototype CORDIC processor data path chip is described. 相似文献