Performance of a twin cylinder dual-fuel diesel engine using blends of neat Karanja oil and producer gas

In the present study, performance and emission analysis are done in a twin cylinder four-stroke dual-fuel diesel engine in two cases of operation. In the first case, the engine is tested using diesel, K10 (10% neat oil+90% diesel) and K20 (20% neat oil+80% diesel) in single mode and in the dual-fuel mode with an optimum producer gas flow rate of 21.49 kg/h under different load conditions. In the second case, the engine is tested using the same test fuels in the dual-fuel mode at different gas flow rates under a constant load of 10 kW. The study reveals that the dual-fuel operation of all test fuels shows a lower engine performance and better control of smoke and oxide of nitrogen emission compared with their single-mode operation under all load conditions. Whereas other emission parameters such as carbon monoxide, carbon dioxide and hydrocarbon are at a higher level.     

Structural,Mechanical and Dielectric Properties of Microwave-Assisted High-Energy Ball Milling Synthesis of Hydroxyapatite

Abstract

In the present work, the effect of high-energy ball milling (HEBM) of starting precursors of hydroxyapatite (Ca₁₀(PO₄)₆(OH)₂)/HA system on the processing temperature, morphological, mechanical, and electrical properties are highlighted. Calcination and sintering of HA system were carried out in microwave furnace. XRD study confirmed the evolution of HA phase and EDX analysis confirmed Ca/P ratio ～1.65. Grain size of HA samples, synthesized by using microwave-assisted HEBM technique was found to be in the order of 54–75?nm. Enhanced dielectric and mechanical properties were obtained in HA samples.     

Temperature and energy performance of refrigerated retail display and commercial catering cabinets under test conditions

An analysis of the performance of well freezers, chest freezers, frozen and chilled door cabinets (solid or glass door) and open fronted chilled cabinets under EN441 test conditions demonstrated that maximum temperatures in cabinets were generally in the most exposed (to ambient) areas and that minimum temperatures were located in the least exposed areas. Detailed positions of maximum and minimum temperature varied between cabinet types. In chest freezers 95% of the maximum temperature positions were located in the top layer and 95% of the minimum temperature positions were located in the middle layer of the cabinets. In full door frozen cabinets the maximum temperature position was in the majority of cases on the top shelf (64%) with most maximum packs being at the front of the top shelf (53%). In the chilled full door cabinets 94% of the maximum temperature packs were situated at the front of the cabinet. In open fronted cabinets the majority of maximum temperature packs (97%) were located at the front of the cabinet, the largest number (60%) being at the front of the base of the cabinet. In well cabinets the majority of maximum temperature packs (81%) were located in the top layer of the cabinet and the majority (91%) of minimum temperature packs were located in the bottom of the cabinet.Large differences in energy consumed by cabinets of similar size and temperature performance were found indicating that large reductions in energy and CO₂ emissions could be achieved by selection of the most efficient cabinets.     

Micromechanical Characterization of Electrophoretic-Deposited Green Films

Low-load indentation experiments have been performed on electrophoretic-deposited films of SiC particles on a graphite substrate. Films with thicknesses between 60 and 300 µm prepared at two current intensities and subsequently dried under different humidities were indented with spherical indenters with nominal radii of 10, 50, and 150 µm. Force-displacement data were analyzed to determine contact pressure and elastic modulus versus depth results. The modulus and contact pressure behavior with depth exhibited opposite trends with indenter radius: the modulus increase was least for the 10 µm and greatest for the 150 µm, whereas the contact pressure was the inverse. The results may be rationalized by plotting modulus normalized to the ratio "contact radius/film thickness" ( a / t ), whereas the contact pressure results at small a / t could be normalized when plotted versus contact strain, i.e., contact radius divided by indenter radius ( a / R ). These approaches enabled the properties of the variously deposited films to be compared. Additional interesting microstructural and cracking behavior patterns are also reported.     

Emulsifier‐free emulsion polymerization of acrylonitrile: Effect of in situ developed Cu(II)/glycine chelate complex initiated by monopersulfate

The catalytic effect of various Cu(II) salts and Cu(II) chelate complexes of certain amino acids on the emulsion polymerization of acrylonitrile in the absence of added emulsifier was investigated in experiments. The CuSO₄/glycine chelate complex was chosen for a detailed kinetic study of acrylonitrile polymerization. The polymerization was studied at varying concentrations of initiator, monomer, Cu(II), glycine, solvents, and TiO₂ over a temperature range of 30–60°C. The overall activation energy and the viscosity average molecular weight of the polymer were computed. From the kinetic and spectrophotometric studies, the mechanism of KHSO₅ decomposition by the Cu(II)/glycine complex and initiation of polymerization was suggested. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 74: 2785–2790, 1999     

Electroanalytical performance of nitrogen-containing tetrahedral amorphous carbon thin-film electrodes

Tetrahedral amorphous carbon (ta-C) consists of a mixture of sp(3)- and sp(2)-bonded carbon ranging from 60 to 40% (sp(3)/sp(3)+sp(2)) depending on the deposition conditions. The physical, chemical, and electrochemical properties depend on the sp(2)/sp(3) bonding ratio as well as the presence of incorporated impurities, such as hydrogen or nitrogen. The ability to grow ta-C at lower temperatures (25-100 °C) on a wider variety of substrates as compared to CVD diamond is an advantage of this material. Herein, we report on the structural and electrochemical properties of nitrogen-incorporated ta-C thin films (ta-C:N). The incorporation of nitrogen into the films decreases the electrical resistivity from 613 ± 60 (0 sccm N(2)) to 1.10 ± 0.07 Ω-cm (50 sccm N(2)), presumably by increasing the sp(2)-bonded carbon content and the connectedness of these domains. Similar to boron-doped diamond, these materials are characterized by a low background voltammetric current, a wide working potential window (~ 3 V), and relatively rapid electron-transfer kinetics for aqueous redox systems, including Fe(CN)(6)(-3/-4) and Ru(NH(3))(6)(+3/+2), without conventional pretreatment. Additionally, there is weak molecular adsorption of polar molecules (methylene blue) on the ta-C surface. Overall, the properties of the ta-C and ta-C:N electrodes are such that they could be excellent new choices for electroanalytical measurements.     

Oxygen Barrier of Multiwalled Carbon Nanotube/Polymethyl Methacrylate Nanocomposites Prepared by in situ Method

Multiwalled carbon nanotubes (MWCNTs)/poly(methyl methacrylate) (PMMA) nanocomposites were prepared by ultrasonic assisted emulsifier free emulsion polymerization technique with variable concentration of functionalized carbon nanotubes. MWCNTs were functionalized with H 2 SO 4 and HNO 3 with continuing sonication and polished by H 2 O 2 . The appearance of Fourier transform infrared absorption bands in the PMMA/MWCNT nanocomposites showed that the functionalized MWCNT interacted chemically with PMMA macromolecules. The surface morphology of functionalized MWCNT and PMMA/MWCNT nanocomposites were studied by scanning electron microscopy. The dispersion of MWCNT in PMMA matrix was evidenced by high resolution transmission electron microscopy. The oxygen permeability of PMMA/MWCNT nanocomposites gradually decreased with increasing MWCNT concentrations.     

Recent progress on cooled avalanche photodiodes for single photon detection

Abstract

Recent results on the properties of cooled avalanche photodiodes for single photon detection are presented. Results from Hamamatsu silicon photodiodes, originally developed as radiation-hard photodetectors for high energy physics experiments, are extremely encouraging. Gains of approximately 10,000 can be achieved with the APD operating in proportional mode. Together with a low noise amplifier they allow photon counting with extremely high efficiency and very low noise making cold APDs almost ideal single photon detectors. Operation of APDs in Geiger mode is also reported, together with measurements of detection efficiency and noise as function of operating voltage. Prospects and hopes for future work are briefly summarized.     

Effect of Laser Linewidths on Nonlinear Optical Processes Exploiting Electromagnetically Induced Transparency

Abstract

We investigate the effects of laser linewidths on the efficiency of sum-frequency generation when electromagnetically induced transparency is exploited in the manner suggested by Harris and his co-workers, which makes use of pump lasers and an intense coupling laser. The linewidths are assumed to be due to phase diffusion. Analytic expressions are obtained which are an excellent approximation when the coupling laser is strong. It is found that increasing the coupling-laser linewidth strongly increases the opacity of the medium; a first consideration is therefore to minimize this linewidth. The relative efficiency of sum-frequency generation is measured by the ratio R of the absolute value of the third-order susceptibility, χ₃, to the imaginary part of the first order susceptibility, χ₁. For large intensities of the coupling field, we show that |χ₃| is independent of the laser linewidths, whereas it increases the value of Im(χ₁).