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11.
Subrata Mallick Satyanarayan Pattnaik Kalpana Swain Pintu K. De Arindam Saha Pushpen Mazumdar 《Drug development and industrial pharmacy》2013,39(7):726-734
This present study is a preliminary exploration of the affinity between a carboxylic model drug ibuprofen and aluminum hydroxide. Ibuprofen was comilled with aluminum hydroxide in different weight ratios in the solid state and was characterized by scanning electron microscopy (SEM), X-ray powder diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR), and in vitro dissolution studies. XRD and SEM studies indicated complete interaction of ibuprofen with aluminum hydroxide and complete amorphization of aluminum hydroxide–ibuprofen complexed salt as well, on comilling with aluminum hydroxide at 1:2 ratio. FTIR data showed the disappearance of acid carbonyl peak with the appearance and the corresponding increase in absorbance of new signal at 1,682 cm?1 in the 1:1 and 1:2 ibuprofen–aluminum hydroxide-comilled powder. The accompanied increase in the absorbance of carboxylate peak in the ibuprofen–aluminum hydroxide physical mixture, and 1:0.1, 1:0.5, 1:1, and 1:2 (IBApm, and IB1A0.1, IB1A0.5, IB1A1, and IB1A2, respectively) comilled powder indicated an acid–base reaction between ibuprofen and aluminum hydroxide. On storage at 40°C and 75% relative humidity (RH) for 10 weeks, XRD study showed the absence of reversion to the crystalline state and FTIR data revealed continued increase of new signal at 1,682 cm?1 relative to carboxylic acid peak and no reappearance of carboxylic acid peak. In vitro dissolution studies revealed that the percent release of ibuprofen from the aluminum hydroxide-comilled powder is in the following order: IB1A2 < IB1A1 < ibuprofen crystal < ibuprofen milled alone < IB1A0.1 < IB1A0.5. Aluminum metal cation might have interacted to form a complex through the carboxyl and carbonyl groups of ibuprofen. Improved dissolution of drug associated with IB1A0.1 and IB1A0.5 is because of the absence of a new signal at 1,682 cm?1 and improved amorphization of the drug to some extent. Dissolution of drug affected in IB1A2 and IB1A1 may be because of the insoluble stable complex formation. 相似文献
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13.
Sabyasachi Swain 《国际聚合物材料杂志》2019,68(13):796-804
In this study, a novel micro porous honeycomb structured Crg-GG-IPN material was incepted to be applicable as scaffold and accomplished. The hydrophilicity was confirmed by FT-IR and OCA. Amorphous nature and micro-rough surface were confirmed by XRD and AFM. Void fraction was 0.61?±?0.04. Void space, hemocompatibility and platelet adhesion were captured by SEM. Degradability of the material was confirmed by in-vitro degradation study. Incision method using mice model was a clear evidence for cell attachment and non-toxicity and was confirmed from hematology and histopathology. Thus, it appears that Crg-GG scaffolds can be useful as wound healing material for clinical applications. 相似文献
14.
Ganesh Swain Ravi Kumar Sonwani Balendu Shekhar Giri Ram Sharan Singh Ravi Prakash Jaiswal Birendra Nath Rai 《Water and Environment Journal》2021,35(1):285-294
The impact of external mass transport on the biodegradation rate of phenol in a packed bed bioreactor (PBBR) was studied. A potential bacterial species, Bacillus flexus GS1 IIT (BHU), was isolated from the petroleum‐contaminated soil. Low‐density polyethylene (LDPE) immobilized with the B. flexus GS1 IIT (BHU) was used as packing material in the PBBR. The PBBR was operated by varying the inlet feed flow rate from 4 to 10 mL/min, and the corresponding degradation rate coefficients were found to be in the range of 0.119–0.157 L/g h. In addition, the highest removal rate of phenol was obtained to be 1.305 mg/g h at an inlet feed rate of 10 mL/min. The external mass transfer was studied using the model . A new empirical correlation for the biodegradation of phenol in the PBBR was developed after the evaluation at various values of K and n. 相似文献
15.
Sunita Barik Sudhir K. Kisku Lingaraj Behera Sarat K. Swain 《Polymer Composites》2015,36(11):2140-2144
The in situ polymerization technique was used for synthesis of polyacrylonitrile nanocomposites (PAN/LDH) by reinforcement of different concentrations of Mg‐Al layered double hydroxide (LDH). Molecular interaction between Mg/Al LDH and PAN matrix was studied by Fourier transform infrared spectroscopy. The morphology of PAN/LDH nanocomposite was investigated by field emission scanning electron microscopy. Energy dispersive spectroscopy of nanocomposites were noticed to establish the elemental composition of the composite. High resolution transmission electron microscopy was used to study the nanostructural distribution of LDH with PAN matrix, whereas crystalline patterns were explained by selected area electron diffraction studies. The thermal properties of nanocomposites were studied by thermo‐gravimetric analysis. It was found that, the thermal property of PAN was substantially enhanced due to strong interfacial adhesion of Mg‐Al‐LDH with PAN matrix. Further, it was noticed that the thermal stability of PAN/LDH nanocomposites were increased with increasing concentration of LDH. POLYM. COMPOS., 36:2140–2144, 2015. © 2014 Society of Plastics Engineer 相似文献
16.
R. N. P. Choudhary Biswajit Pati Piyush R. Das R. R. Dash Subhashree Swain 《Journal of Materials Science: Materials in Electronics》2014,25(1):202-216
The current research work presents the preparation and characterization of some new electronic materials using bismuth oxide (Bi2O3) and industrial waste red mud in different proportion by weight using a cost-effective mixed-oxide technique. Preliminary X-ray structural analysis exhibits the formation of compounds with structure analogous to that of BiFeO3 compound along with some impurity phases. Studies of dielectric parameters (εr and tanδ) of these compounds as a function of temperature and frequency exhibit that they are almost temperature independent in the low temperature range and possess high relative permittivity with low loss in the high temperature range. Detailed studies of impedance and related parameters exhibit that the electrical properties of these materials are strongly dependent on temperature, and bear a good correlation with their microstructures. The bulk resistance, evaluated from complex impedance spectra, is found to be decreasing with rise in temperature, exhibiting a typical negative temperature co-efficient of resistance (NTCR)—type behavior similar to that of semiconductors. Studies of electric modulus indicate the presence of hopping conduction mechanism in the system with non-exponential type of conductivity relaxation. The low leakage current and NTCR behavior of the sample have been verified from I–V characteristics. The nature of variation of dc conductivity with temperature confirms the Arrhenius and NTCR behavior in the material. The ac conductivity spectra show a typical-signature of an ionic conducting system, and are found to obey Jonscher’s universal power law. 相似文献
17.
Abstract We consider a three-level atom in any of its possible configurations, ladder, lambda or vee, which interacts with two classical, resonant, monochromatic electromagnetic fields. We suppose the levels 相似文献
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19.
Despite a great success, one of the key issues facing in dental implantation clinic is a mismatch of mechanical properties between engineered and native biomaterials, which makes osseointegration and bone remodeling problematical. Functionally Graded Material (FGM) has been proposed as a potential upgrade to some conventional implant materials like titanium for selection in prosthetic dentistry. The idea of FGM dental implant is that the property would vary in a certain pattern to match the biomechanical characteristics required at different regions in the hosting bone. However, mating properties do not necessarily guarantee the best osseointegration and bone remodeling. No existing report has been available to develop an optimal design of FGM dental implant for promoting a long-term success. This paper aims to explore this critical issue by using the computational bone remodeling and design optimization. A buccal–lingual sectional model, which consists of a single unit implant and four other adjacent teeth, was constructed from computerized tomography (CT) scan images. Bone remodeling induced by use of various FGM dental implants is calculated over the period of 4 years. Based upon remodeling results, response surface method (RSM) is adopted to develop a multi-objective optimal design for FGM implantation FGM designs. 相似文献
20.
Lucksanasombool P Higgs WA Higgs RJ Swain MV 《Journal of materials science. Materials in medicine》2002,13(8):745-750
The mechanical properties of glass-ionomer cements (GICs) have been satisfactory for dental applications and have shown their potential in orthopedic surgery. Because the physiological environment in orthopedics is different from dentistry by unavoidable contamination with blood and other fluids such as normal saline used during an operation, the determination of GICs for orthopedic applications should be performed in an appropriate environment. The properties of a novel resin-modified GIC, S430, for orthopedic applications were evaluated in simulated orthopedic conditions by an early exposure to and long-term storage in normal saline. An early exposure to normal saline caused 20–60% reduction of its compressive and flexural properties, whereas long-term storage in normal saline showed slight changes of its mechanical properties. The effects were probably due to the disturbance of the cross-linking formation in the acid-base reaction and also the reduction of electrostatic interactions of the cross-linking polymeric chain of hydroxyethyl methacrylate (HEMA) in resin-modified GIC. 相似文献