Layer‐by‐layer assembly of halogen‐free polymeric materials on nylon/cotton blend for flame retardant applications

Thin films of environmentally safe, halogen free, anionic sodium phosphate and cationic polysiloxanes were deposited on a Nyco (1:1 nylon/cotton blend) fabric via layer‐by‐layer (LbL) assembly to reduce the inherent flammability of Nyco fabric. In the coating process, we used three different polysiloxane materials containing different amine groups including, 35–45% (trimethylammoniummethylphenythyl)‐methyl siloxane‐55‐65% dimethyl siloxane copolymer chloride salt (QMS‐435), aminoethylaminopropyl silsesquioxane‐methylsilsesquioxane copolymer oligomer (WSA‐7021) and aminopropyl silesquioxane oligomers (WSA‐991), as a positive polyelectrolyte. Thermo‐gravimetric analysis showed that coated fabric has char yield around 40% at 600 °C whereas control fabric was completely consumed. The vertical flame test (VFT) on the LbL‐coated Nyco fabric was passed with after flame time, 2 s, and the char length of 3.81 cm. Volatile and nontoxic degradation products of flame retardant‐coated fabric were analyzed by pyrolysis gas chromatography mass spectroscopy (Py‐GCMS). Surface morphology of coated fabrics and burned fabric residues were studied by scanning electron microscopy. Copyright © 2014 John Wiley & Sons, Ltd.     

Object‐oriented wrappers for the Linux kernel

Linux is an open‐source operating system, which has increased in its popularity and size since its birth. Various studies have been conducted in literature on the evolution of the Linux kernel, which have shown that there are considerable maintenance problems arising out of the coupling issues in the Linux kernel and this may hamper the evolution of the kernel in future. We propose an object‐oriented (OO) wrapper‐based approach to Linux kernel to provide OO abstractions to external modules. As the major growth of the size of the Linux kernel is in device drivers, our approach provides substantial benefits in terms of developing the device drivers in C++, although the kernel is in C. Providing reusability and extensibility features to device drivers improves the maintainability of the kernel. The OO wrappers provide several benefits to module developers in terms of understandability, development ease, support for OO modules, etc. The design and implementation of C++ wrappers for Linux kernel and the performance of a device driver re‐engineered in C++ are presented in this paper. Copyright © 2008 John Wiley & Sons, Ltd.     

Optimization of shock response within a military vehicle space frame

Space frames are usually used to enhance the structural strength of a vehicle while reducing its overall weight. The space frame of a military vehicle is subjected to significantly different loading than what is experienced in civilian vehicles, such as projectile impact or mine blast. In this work, a finite element (FE) model for the upper half of an armored vehicle with internal space frame is developed. The behavior of the vehicle is studied when subjected to a high impact load that simulates a projectile impact. The objective of this work is to minimize shocks at identified critical locations on the space frame while maintaining the overall structural integrity of the vehicle. Several variables that can affect shock propagation are identified including, the cross-sectional parameters of the internal space frame and outer armor. The optimization problem is solved using the Successive Heuristic Quadratic Approximation (SHQA) technique, which combines successive quadratic approximation with an adaptive random search while varying the bounds of the search space. The entire optimization process is carried out within the MATLAB environment. The results show that a significant reduction in the shock can be achieved using this approach.     

Palladium(II)‐Catalyzed Sequential Aminopalladation and Oxidative Coupling with Acetylenes/Enones: Synthesis of Newly Substituted Quinolines from 2‐Aminophenyl Propargyl Alcohols

Palladium catalyzed conversion of 1‐(2‐aminophenyl)‐propargyl alcohols to 3‐alkynyl quinolines is realized via a cascade that involves aminopalladation, oxidative coupling with alkynes and dehydration. The method is shown to have a broad substrate scope with respect to propargyl alcohols as well as alkynes. Vinyl ketones as coupling partners in the same reaction afforded 3‐alkenyl quinolines with equal ease.

     

Comparison of corrosion performance of various conversion coatings on magnesium alloy using electrochemical techniques

Comparative studies on some of the important chemical conversion coatings, namely, phosphate–permanganate, galvanic black anodizing, dichromate treatment, and micro arc oxidized and modified acid fluoride anodizing on magnesium alloy AZ31B have been conducted. The surface morphology and composition of the coatings were examined through SEM and EDX techniques. Corrosion resistances of these coatings were compared using electrochemical impedance spectroscopy (EIS) and linear polarization studies. The corrosion resistances of the coatings investigated were found to be according to the order as follows: modified acid fluoride > micro arc oxidized phosphate > micro arc oxidized silicate > dichromate > galvanic black anodizing > phosphate-permanganate > bare magnesium.     

Structural,vibrational and magnetic properties of Cu-substituted Mn0.5Zn0.5Fe2O4 nanoparticles

Journal of Materials Science: Materials in Electronics - Nanoparticles of quaternary Mn0.5?xCuxZn0.5Fe2O4 ferrite (x?=?0.05, 0.15, 0.25, and 0.35) have been investigated to...     

Microstructural and Mechanical Properties Investigation of TiC Reinforced Hardface Alloy Deposited on Mild Steel Substrate

Wear is one of the major problems faced in industry that reduces the life of industrial components and increases the operating costs. Therefore, hardfacing is widely employed by engineers to minimize components’ wear, in which single or multiple layers of hard material that mainly consists of carbides deposited on the base metal. However, these carbide-based materials suffer from solidification cracking due to lack of ductility. In this study, titanium carbide (TiC) reinforced alloy steel deposited using self-shielded flux cored arc welding technique. The microstructure and phase analysis in the hardfaced deposit by scanning electron microscope, energy dispersive x-ray and X-ray diffractometer revealed that the microstructure consists of finely distributed TiC within matrix of martensite and some retained austenite. Microhardness test and pin-on-disk wear test had shown that the clad deposit posses better hardness and wear resistance. Retained austenite formation and TiC precipitation were discussed in detail and correlated with the mechanical properties.     

Synthesis and characterization of highly photoresponsive fullerenyl dyads with a close chromophore antenna-C(60) contact and effective photodynamic potential

We report the synthesis of a new class of photoresponsive C(60)-DCE-diphenylaminofluorene nanostructures and their intramolecular photoinduced energy and electron transfer phenomena. Structural modification was made by chemical conversion of the keto group in C(60)(>DPAF-C(n)) to a stronger electron-withdrawing 1,1-dicyanoethylenyl (DCE) unit leading to C(60)(>CPAF-C(n)) with an increased electronic polarization of the molecule. The modification also led to a large bathochromic shift of the major band in visible spectrum giving measureable absorption up to 600 nm and extended the photoresponsive capability of C(60)-DCE-DPAF nanostructures to longer red wavelengths than C(60)(>DPAF-C(n)). Accordingly, C(60)(>CPAF-C(n)) may allow 2γ-PDT using a light wavelength of 1000-1200 nm for enhanced tissue penetration depth. Production efficiency of singlet oxygen by closely related C(60)(>DPAF-C(2) (M)) was found to be comparable with that of tetraphenylporphyrin photosensitizer. Remarkably, the (1)O(2) quantum yield of C(60)(>CPAF-C(2) (M)) was found to be nearly 6-fold higher than that of C(60)(>DPAF-C(2) (M)), demonstrating the large light-harvesting enhancement of the CPAF-C(2) (M) moiety and leading to more efficient triplet state generation of the C(60)> cage moiety. This led to highly effective killing of HeLa cells by C(60)(>CPAF-C(2) (M)) via photodynamic therapy (200 J cm(-2) white light). We interpret the phenomena in terms of the contributions by the extended π-conjugation and stronger electron-withdrawing capability associated with the 1,1-dicyanoethylenyl group compared to that of the keto group.