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81.
Masaharu Takeda Hiroyuki Hiraishi Toshikazu Takesako Sumio Tanase Norio Gunge 《Yeast (Chichester, England)》1996,12(3):241-246
The 36K protein attached at the 5′ end of the linear DNA plasmid pGKL2 from the yeast Kluyveromyces lactis was first purified and characterized. The terminal protein was purified from cells (1 kg wet weight) by ammonium sulphate precipitation and two rounds of centrifugation to equilibrium in CsCl gradients. The pGKL2 was present only in the post-microsomal supernatant. Approximately 10 mg of the purified pGKL2 was recovered and digested with DNase I. The terminal protein (final ca. 0·8 mg) was homogeneous by electrophoresis and we determined the N-terminal amino acid sequence up to ten residues, showing that it existed in the cryptic N-terminal domain of pGKL2-ORF2 (DNA polymerase) sequence. 相似文献
82.
83.
Metal-atom migration outside from a defective fullerene cage of a metallofullerene Gd@C(82) (Ca@C(82)), where the Gd(3+) (Ca(2+)) ion is incorporated inside the C(2)(v)()-C(82) cage, is discussed in detail at the B3LYP DFT level of theory. The metal-atom migrations are initiated by the formation of vacancy-type defects involving two coordinatively unsaturated C atoms. This step, which is assumed to proceed due to energy-particle irradiation, leads to the formation of antibonding orbitals between the two C atoms. Since the antibonding orbitals can interact with vacant d-orbitals of the Gd(3)(+)() ion in an in-phase fashion, the attractive interactions allow the Gd ion to insert into the two C atoms in the defect. As a result, the metal ion passes through the defect under energy-particle irradiation. In contrast, the Ca(2+) ion with the vacant s-orbitals does not have such orbital interactions, and thus, a C-C bond is reformed between the two C atoms, which prohibits the Ca ion from penetrating the defected C(82) cage. DFT calculations nicely demonstrate that the orbital interactions control metal-atom migration around the defect site using their orbital symmetries, and therefore, the vacancy-type defect acts as a "gate" that permits a specific atom to go out from a defected fullerene cage. 相似文献
84.
Shirahata N Nakanishi T Furumi S Sakka Y 《Journal of nanoscience and nanotechnology》2006,6(6):1823-1825
We demonstrate here a novel method for self-assembling in dimensional alignment the alkoxy-capped silicon nanoparticles synthesized through a room-temperature chemical route. The alkoxy-capped silicon nanoparticles were prepared via a reduction of silicon tetrachloride with sodium-naphthalide and subsequent surface capsulation with 1-octanol monolayers. In the present method, a sublimation process, which was employed as a final purification process for removing the residual naphthalene, influenced significantly on the final morphology of the resultant nanoparticles. Scanning transmission electron microscope (STEM) confirmed the spherical nanoparticles on a holey carbon grid after sublimation process, while only the fibril-like morphology just before sublimation process. In the former sample, the resultant particle size was measured by STEM to be about 9.5 nm +/- 3.4 nm. On the other hand, in the latter sample, the fibril-like structures were shaped by self-assembled silicon nanoparticles in dimensional alignment. The diameters and lengths of the fibril-like assemblies were approximately measured to be 10 to 20 nm and over 5 microm, respectively. 相似文献
85.
Vasylkiv O Borodianska H Badica P Grasso S Sakka Y Tok A Su LT Bosman M Ma J 《Journal of nanoscience and nanotechnology》2012,12(2):959-965
Boron carbide B4C powders were subject to reactive spark plasma sintering (also known as field assisted sintering, pulsed current sintering or plasma assisted sintering) under nitrogen atmosphere. For an optimum hexagonal BN (h-BN) content estimated from X-ray diffraction measurements at approximately 0.4 wt%, the as-prepared BaCb-(BxOy/BN) ceramic shows values of Berkovich and Vickers hardness of 56.7 +/- 3.1 GPa and 39.3 +/- 7.6 GPa, respectively. These values are higher than for the vacuum SPS processed B4C pristine sample and the h-BN -mechanically-added samples. XRD and electronic microscopy data suggest that in the samples produced by reactive SPS in N2 atmosphere, and containing an estimated amount of 0.3-1.5% h-BN, the crystallite size of the boron carbide grains is decreasing with the increasing amount of N2, while for the newly formed lamellar h-BN the crystallite size is almost constant (approximately 30-50 nm). BN is located at the grain boundaries between the boron carbide grains and it is wrapped and intercalated by a thin layer of boron oxide. BxOy/BN forms a fine and continuous 3D mesh-like structure that is a possible reason for good mechanical properties. 相似文献
86.
Vasylkiv O Demirskyi D Sakka Y Ragulya A Borodianska H 《Journal of nanoscience and nanotechnology》2012,12(6):4577-4582
Two-stage densification process of nanosized 3 mol% yttria-stabilized zirconia (3Y-SZ) polycrystalline compacts during consolidation via microwave and spark-plasma sintering have been observed. The values of activation energies obtained for microwave and spark-plasma sintering 260-275 kJ x mol(-1) are quite similar to that of conventional sintering of zirconia, suggesting that densification during initial stage is controlled by the grain-boundary diffusion mechanism. The sintering behavior during microwave sintering was significantly affected by preliminary pressing conditions, as the surface diffusion mechanism (230 kJ x mol(-1)) is active in case of cold-isostatic pressing procedure was applied. 相似文献
87.
On the basis of EnergyPlus’s codes, the catalogue and performance parameters from some related companies, a special simulation module for variable refrigerant flow system with a water-cooled condenser (water-cooled VRF) was developed and embedded in the software of EnergyPlus, the building energy simulation program. To evaluate the energy performance of the system and the accuracy of the simulation module, the measurement of the water-cooled VRF is built in Dalian, China. After simulation and comparison, some conclusions can be drawn. The mean of the absolute value of the daily error in the 9 days is 11.3% for cooling capacity while the one for compressor power is 15.7%. At the same time, the accuracy of the power simulation strongly depends on the accuracy of the cooling capacity simulation. 相似文献
88.
Zhen-Yan Deng Ye-Bin Tang Li-Li Zhu Yoshio Sakka Jinhua Ye 《International Journal of Hydrogen Energy》2010
Three different modification agents, γ-Al2O3, α-Al2O3, and TiO2 were used to modify Al particle surfaces. The effect of different modification agents on hydrogen-generation by the reaction of modified Al powder with water was investigated. It was found that different modification agents have different effect on the reaction dynamics of Al with water. The complete hydrogen-generation time of γ-Al2O3 modified Al powder is obviously shorter than that of α-Al2O3 and TiO2 modified Al powders, because of their different induction time for the beginning of the reaction. Possible mechanism analyses indicated that the phase transformation and resultant weakening of Al particle surface layer during processing strongly depends on the nucleation energy barrier on modification oxide grains. As γ-Al2O3 has a low nucleation energy barrier, the phase transformation of Al particle surface layer is relatively complete so that γ-Al2O3 modified Al powder has a short induction and complete reaction time with water. This implies that the Al surface modification probably originates from the phase change of its surface layer. 相似文献
89.
Synthesis of (Gd0.95−xLnxEu0.05)2O3 (Ln = Y and Lu, x = 0–0.95) powders via ammonium hydrogen carbonate (AHC) precipitation has been systematically studied. The best synthesis parameters are found to be an AHC/total cation molar ratio of 4.5 and an ageing time of 3 h. The effects of Y3+ and Lu3+ substitution for Gd3+, on the nucleation kinetics of the precursors and structural features and optical properties of the oxides, have been investigated. The results show that (i) different nucleation kinetics exist in the Gd–Y–Eu and Gd–Lu–Eu ternary systems, which lead to various morphologies and particle sizes of the precipitated precursors. The (Gd,Y)2O3:Eu precursors display spherical particle morphologies and the particle sizes increase along with more Y3+ addition. The (Gd,Lu)2O3:Eu precursors, on the other hand, are hollow spheres and the particle sizes increase with increasing Lu3+ incorporation, (ii) the resultant oxide powders are ultrafine, narrow in size distribution, well dispersed and rounded in particle shape, (iii) lattice parameters of the two kinds of oxide solid solutions linearly decrease at a higher Y3+ or Lu3+ content. Their theoretical densities linearly decrease with increasing Y3+ incorporation, but increase along with more Lu3+ addition and (iv) the two kinds of phosphors exhibit typical red emissions at ∼613 nm and their charge-transfer bands blue shift at a higher Y3+ or Lu3+ content. Photoluminescence/photoluminescence excitation intensities and external quantum efficiency are found to decrease with increasing value of x, and the fluorescence lifetime mainly depends on the specific surface areas of the powders. 相似文献
90.
Gustavo Suárez Byung-Koog Jang Esteban F. Aglietti Yoshio Sakka 《Metallurgical and Materials Transactions A》2013,44(9):4374-4381
Highly concentrated zirconia-carbon nanotube (CNT) water suspensions were prepared using an advanced milling technique. The bead-milling operation parameters were optimized for this system and used to prepare zirconia-stabilized water-based suspensions with different CNT contents. The effects of different milling conditions were studied. The particle dispersion was evaluated by SEM observations on dried suspension. Green’s density and SEM observations of compacts were used to follow the colloidal dispersability of the composites. Materials of tetragonal zirconia and CNTs were prepared with a high concentration of CNTs (1, 5, and 10 wt pct CNT). The homogeneous dispersion and distribution of the fibers in the bulk material after slip casting of the suspension were examined. The samples were sintered using spark plasma sintering (SPS) at 1473 K (1200 °C) and finally, fully dense materials were obtained. The mechanical properties were evaluated using the Vickers indentation technique. 相似文献