Bi-Pb-Tl三元系相图

用室温、高温X射线衍射及淬火的方法,测定了Bi-Pb-Tl三元系25℃的等温截面及该体系中的相结构。     

CHARACTERISTICS OF INTERNAL FRICTION AND MODULUS ASSOCIATED WITH NON-EQUILIBRIUM DIFFUSION-TYPE PHASE TRANSFORMATION IN EUTECTOID Al-Zn ALLOY

The characteristics of the low frequency internal friction and the modulus effect associatedwith the non-equilibrium spinodal pretransformation and the following discontinuous trans-formation was investigated in an as-quenched eutectiod Al-Zn alloy.It was observed that theloss of the stability in the lattice,which corresponded to the large-amplitude long-wavelengthstatic concentration wave in the non-equilibrium spinodal pretransformation,did not induceany effect of localized soft modulus.Although there are two aging internal friction peaks inphase transformation which correspond to the appearance and disappearance of the coherencyin spinodal pretransformation and the maximum of the interface area in the discontinuoustransformation respectively,the effect of localized soft modulus did not take place yet.     

FRACTURE ANALYSIS OF HYDROGEN-INDUCED CRACKING FOR STEEL 12Ni3CrMoV

本文通过插销断口分析,研究了含硼12Ni3CrMoV钢焊接热影响区氢浓度及应力大小与断口形态之间的关系,结果表明,插销断口具有氢脆准解理特征,断口上氢脆准解理区域随氢浓度的升高而增加,随负载应力的加大而减小.准解理断裂面为{110}面.     

La在KCl-NaCl和LaCl_3-KCl-NaCl熔体中的溶解行为SCIEI

本文利用透明槽技术、电化学循环V-A法及量子化学EHMO三种方法,研究了La在KCl-NaCl(1:1mol)及LaCl_3-KCl-NaCl熔体中的溶解行为。初步认为:溶解在KCl-NaCl熔体中的La是以中性金属状态存在。在LaCl_3-KCl-NaCl熔体中,溶解的La与La^(3+)作用生成低价La^(2+)离子,La^(2+)又与周围的La^(3+)作用形成原子簇离子La_m^(n+)赋存于熔体之中。     

Calculation of cooling rate of amorphous aluminum alloy melt-spun ribbons

Based on the heat transfer theory and liquid solidification theory, the heat transfer during the rapid solidification process of amorphous ribbons prepared by melt spinning was approximately modeled by one-dimensional heat conduction equation. Besides, integration with the temperature gradient, the relationship between the ribbon thickness and solidification time was derived according to the boundary conditions of ribbon-copper wheel. A simply theoretical model was obtained to calculate the cooling rates of aluminum amorphous ribbons. According to the above theoretical model, the critical cooling rate of aluminum amorphous ribbons by melt spinning is above 10^6 K/s, which proves that the aluminum based alloys belong to the marginal glass forming ability of alloys. The calculated results are in good agreement with other estimated values reported previously.     

Ti-Al基合金中的Hall-Petch关系及影响因素分析

研究了全层片状组织Ti-Al基合金的室温拉伸性能与品团尺寸的关系。Ti-Al基合金的室温拉伸屈服强度和断裂强度与晶团尺寸成Hall-Petch关系。当合金中添加替代元素Cr和Nb时，其Hall-Petch斜率不变；而添加间隙元素C和B时，其Hall-Petch斜率增加。Ti-Al基合金的室温延伸率与晶团尺寸不满足Hall-Petch关系。     

铝合金时效-屈服强度的实验与模型化研究

以析出热力学、长大动力学及位错理论为基础，研究了铝合金在时效过程中盘／片状、棒／针状析出相尺寸、体积分数对时效合金强化效果的影响，从微观-宏观相结合的角度建立了具有盘／片状、棒／针状细小时效强化相铝合金的时效工艺-屈服强度量化模型，并通过513K温度下时效Al-Cu-Mg合金和463K温度下时效Al-Mg-Si合金的实验结果对模型进行了验证，取得了较满意的吻合结果，并对本模型的模拟精度与时效析出相参数之间的关系进行了讨论。     

金属及合金中射程参数的研究SCIEI

本文应用金属中Wigner-Sietz(W-S)半径数据和引入等效电荷概念,结合Ziegler的质子注入数据,导出了计算重离子注入各种金属中的电子阻止本领S_c(E)的公式,计算结果与文献中的实测值结果甚为一致。同样,应用合金中的W-S半径,导出了适用于合金硼化物和CsCl型合金的S_c(E)计算公式。计算结果表明,公式对单硼或二硼化合物符合得较好,而对一些复杂结构的合金以及Cr_5B_3和W_2B_5是不适合的。对CsCl型合金,S_c(E)对Bragg定律的偏离系数γ和合金中电荷转移量成正比,后者越大表明金属键越强,则合金对离子的阻止本领越大,这与实验结果是吻合的。合金中两元素在同一周期中位置相差越远,这种趋势越明显。不同周期元素组成的合金更加强了这种趋势。     

AB INITIO CALCULATION OF THE ELASTIC AND OPTICAL PROPERTIES OF Al_3Sc COMPOUND

The ab initio method has been performed to explore the elastic and optical properties of Al3Sc compound, based on a plane wave pseudopotential method. It can be seen that the calculated equilibrium lattice parameter and elastic constants are in reasonable agreement with the previous experimental data. The elastic constants satisfy the requirement for mechanical stability in the cubic structure of the Al3Sc compound. The optical property calculations show that a strong absorptive peak exists from 0-15eV and a relative small absorptive peak exists around 30eV. The form is caused by the optical transitions between high s, p, and d bands, and the latter results from the optical transitions from high s, p, and d bands to the low 2p band.     

六铝酸钙材料的合成及其显微结构研究

分别采用轻质碳酸钙和活性氧化铝 ,或纯铝酸钙水泥和活性氧化铝为初始原料 ,反应烧结合成了六铝酸钙 (CA6)材料 ,研究了原料和成型压力对合成材料的烧结性能和显微结构的影响 ,同时借助于XRD、TG -DSC、SEM和EDAX等测试手段对其反应过程、物相变化和显微结构进行了分析和观察。研究结果表明 :(1) 130 0℃时 ,合成材料的主晶相为刚玉相和CA2 ,并开始有CA6形成 ;温度升至14 0 0℃ ,CA6大量生成 ;15 0 0℃时反应完成 ,产物全部为CA6相。 130 0～ 15 0 0℃时 ,上述反应表现为体积膨胀过程 ,试样的体积密度和径向线收缩率随温度的变化不大 ;而高于 15 0 0℃时 ,试样明显趋向烧结 ,体积密度升高 ,线收缩率加大。采用纯铝酸钙水泥和活性氧化铝合成的试样的体积密度均高于采用轻质CaCO3 和活性氧化铝的 ,尤其在烧成温度高于 15 0 0℃时。坯体的成型压力对这两种合成试样的烧结性能均没有显著影响。 (2 )合成六铝酸钙材料的晶粒形貌与合成工艺有关 ,制备片状晶粒的六铝酸钙材料需满足两个条件 :一是晶核有足够的发育空间 ,二是从晶核生长形成片状结构需足够的物质扩散。采用纯铝酸钙水泥和活性氧化铝为原料的试样 ,其CA6晶核很容易发育成片状晶形 ,且随着坯体成型压力的增加 ,片状CA6有向等轴状发展的趋势 ;采用