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11.
The kinetics of the methanation of carbon dioxide was investigated using an alumina supported Ni-La2O2 catalyst in a differential and integral reactor. In the differential reactor the molar ratio of H2 to CO2 was varied from 0.6 to 30. In the integral reactor the rates were measured with up to 90% conversion. Both reactor tests were carried out at temperatures between 513 and 593 K. The experimental results were described by a Langmuir-Hinshelwood type equation. The kinetics can be explained by assuming equilibrium of dissociative carbon dioxide and hydrogen adsorption, and assuming hydrogenation of surface carbon as the rate determining step. 相似文献
12.
Tsunehiro Aki Kazutaka Hachida Megumi Yoshinaga Yuko Katai Takashi Yamasaki Seiji Kawamoto Toshihide Kakizono Takashi Maoka Seiko Shigeta Osamu Suzuki Kazuhisa Ono 《Journal of the American Oil Chemists' Society》2003,80(8):789-794
Thraustochytrids, marine protists whose dominant genera are Thraustochytrium and Schizochytrium, belong to the kingdom Chromista and are known as an industrial source of DHA. We describe here that thraustochytrid strain
KH105, isolated as a DHA producer, also accumulates significant levels of β-carotene and xanthophylls including canthaxanthin
and astaxanthin. A4-d cultivation using a medium composed of 10% glucose and less than 0.3% of nitrogen sources in a half-concentration
of seawater gave an astaxanthin production up to 6.1 mg/L, and canthaxanthin content reached more than 10 mg/L under conditions
where a higher concentration of nitrogen sources (6%) was employed. It might be advantageous in mass production systems for
these carotenoids to be extracted readily by simply suspending the cells with organic solvents such as acetone and chloroform.
Analyses on the morphological and life history features of the KH105 strain revealed that it belongs to the genus Schizochytrium. This particular species of thraustochytrids is thus considered to be a promising source of xanthophylls as well as DHA for
use in the food industry. 相似文献
13.
Gopal P. Khanal Ichiro Fujii Shintaro Ueno Satoshi Wada 《Journal of the American Ceramic Society》2021,104(9):4649-4658
The <110>-oriented BaTiO3 ceramics were fabricated using BaCO3 matrix and H1.08Ti1.73O4.nH2O (HTO) template particles, and the mechanism of BaTiO3 phase formation was investigated. The dielectric, ferroelectric, and piezoelectric properties were also investigated. The transformation of the HTO phase into the TiO2 bronze or TiO2 (B) phase was observed at 600°C, where the BaTiO3 nucleation was accompanied by the formation of a Ba2TiO4 phase. The TiO2 phase reacted with the Ba2TiO4 phase at 800°C to give a BaTiO3 phase, whereas its reaction with the BaTiO3 resulted in the formation of BaTi2O5 phase that got decomposed into BaTiO3 and Ba6Ti17O40 phase at sintering temperature ≥1300°C. Sintering with samples’ embedding in BaTiO3 powders prevented the formation of the Ba6Ti17O40 secondary phase. The crystallographic orientation along the <110> direction (F110) was developed by the epitaxial grain growth mechanism. In addition to the contribution of the grain-size increment for enhancing the F110, the preservation of the platelike structure was also found to have a significant impact. The ceramics prepared by the embedded sintering (grain size ≈12.4 µm and F110 = 83%) exhibited the room-temperature dielectric constant of 1708 and piezoelectric strain constant of 445 pm/V, which are higher than those of the BaTiO3 ceramics with randomly oriented grains. 相似文献
14.
Fusaomi Nagata Takanori Mizobuchi Shintaro Tani Tetsuo Hase Zenku Haga Keigo Watanabe Maki K. Habib 《Artificial Life and Robotics》2010,15(1):106-110
In this article, a new desktop orthogonal-type robot, which has the capacity of stick-slip motion control based on cutter
location data, is presented for lapping small metallic molds with a curved surface. The robot consists of three single-axis
devices with a high position resolution of 1 μm. A thin wooden stick tool with a ball-end shape is attached to the tip of
the z-axis. In order to improve the lapping performance, a novel stick-slip motion control method is developed in the control system.
The small stick-slip motion is orthogonally generated in the direction of the tool’s movement. The effectiveness of stick-slip
motion control is examined through an actual lapping test of an LED lens cavity. 相似文献
15.
Takayuki Kobayashi Hedong Zhang Kenji Fukuzawa Shintaro Itoh 《Microsystem Technologies》2016,22(6):1285-1290
A fundamental understanding of the diffusion phenomena of submonolayer polar liquid films is important for achieving reliable lubrication between moving mechanical parts separated by a nanometer-sized gap. To acquire this understanding, we conducted molecular dynamics (MD) simulations of diffusion phenomena of submonolayer polar perfluoropolyether (PFPE) Zdol films on solid surfaces. To improve the accuracy of these simulations, we developed an all-atom model that includes hydrogen-bond potential and refined atomic charges for Zdol molecules and tested it through MD simulations of spreading of step-shaped submonolayer PFPE films. Our MD simulations reproduced the experimentally observed effects of polar end groups on the diffusion speed and molecular conformation of Zdol. We then conducted MD simulations of self-diffusion of submonolayer Zdol films; these simulations demonstrated that as the thickness of the submonolayer Zdol films decreases, molecular conformation becomes flatter and the self-diffusion coefficient decreases. These changes in molecular conformation partially explain our experimental finding that the spreading of step-shaped submonolayer polar PFPE films slows down with decreasing initial thickness. 相似文献
16.
Shintaro Okazaki Ph.D. Radoslav Skapa Ph.D. Ildefonso Grande Ph.D. 《Journal of Computer-Mediated Communication》2008,13(4):827-855
We adapt the technology acceptance model (TAM) to examine the factors influencing mobile gaming adoption among “global youth.” Our model replaces usefulness with convenience, incorporating visual appeal and escapism as antecedents of fun, and perceived novelty and economic value as antecedents of convenience. Questionnaire surveys were conducted in the U.S., Spain, and the Czech Republic, producing 432 usable responses. In the structural model assessment with the pooled sample, convenience exercises greater effects on attitude toward mobile games than fun, suggesting that the most important driver is probably the capability of being used flexibly at any time and in any place, rather than mere enjoyment. Tests of latent means suggest that most dimensions are perceived more strongly in the Czech Republic. 相似文献
17.
Kazuko Yamasaki Kenneth J. Mackin Masanori Ohshiro Kotaro Matsushita Eiji Nunohiro 《Artificial Life and Robotics》2008,12(1-2):122-124
We studied the networks of the temperature record in the atmosphere. They are made by the strength of the synchronization,
including the delay between temperatures at locations on Earth. We consider these locations as nodes, and we consider a pair
of locations as a link if the synchronization between them is stronger than a threshold. The network is scale-free, which
is thought to contribute to the stability of the climate.
This work was presented in part at the 12th International Symposium on Artificial Life and Robotics, Oita, Japan, January
25–27, 2007 相似文献
18.
H. Takahashi L. H. Liu Y. Yashiro K. Ioku G. Bignall N. Yamasaki T. Kori 《Journal of Materials Science》2006,41(5):1585-1589
The reduction of CO2 under hydrothermal conditions has been investigated. In typical experiment, Fe-powder, Ni-powder, solvent, and CO2 have been reacted in a batch-type micro autoclave under hydrothermal conditions for several hours. Methane, formic acid,
and hydrogen were generated after treatment in water. With the rise of Ni amount, the methane yield increased while hydrogen
and formic acid decreased. It is supposed that Ni has acted as a hydrogenation catalyst. In basic solution, CO2 was converted to formic acid selectively at 300°C involved with trace of methane. Considering the reduction characteristics
of formic acid, the reaction pathway has been discussed. In experiments with the mixture of Fe and Fe3O4, trace of methanol was detected at the experiments with less amount of metallic Fe. It is inferred that the control on the
effect of reductant is indispensable for oxygenated organic compound formation. Experiment on the effect of water has been
conducted using hydrogen. Ethane yield increased with the amount of water, while there was no drastic change in the yield
of methane. From these results, it is supposed that the steam reforming reaction of methane was involved in the reduction
of CO2, and effected on the C–C bond formation. 相似文献
19.
Z. Jing N. Matsuoka F. Jin N. Yamasaki K. Suzuki T. Hashida 《Journal of Materials Science》2006,41(5):1579-1584
Solidification of Coal Fly-ash (CFA) has been carried out using a hydrothermal processing method. In the hydrothermal processing,
the CFA was first compacted in a mold at 20 - 50 MPa, and then hydrothermally cured in an autoclave. The hydrothermal curing
was performed at 150 – 250°C for 15 – 60 h. The experimental results showed that NaOH solution, Ca(OH)2 content, compaction pressure, autoclave curing temperature and time significantly affected the strength of solidified bodies.
The most important strength-producing constituent in the solidified bodies produced with CFA was tobermorite, or tobermorite-like
calcium silicate hydrate. When the CaO/SiO2 ratio of the starting material was close to 0.83, tobermorite readily formed and the formed tobermorite enhanced the strength
of solidified bodies. The tensile strength determined by the Brazilian test reached more than 10 MPa under the hydrothermal
processing. As such, the hydrothermal processing method may provide a high potential for recycling CFA on a large scale. 相似文献
20.
Fujihiko Matsumoto Shintaro Nakamura Hiroki Wasaki Yasuaki Noguchi 《International Journal of Circuit Theory and Applications》2004,32(4):255-274
This paper presents design of linear bipolar OTAs, which are composed of two function blocks; one is an exponential‐law circuit and the other is a core cell. Multi‐tanh cells are employed as the core cell. This kind of OTA has lower power dissipation relatively to the conventional multi‐tanh cell. According as the order of the multi‐tanh core cell becomes higher, the number of circuit realization for the core cell increases. For example, we have two OTAs for the core circuit of an emitter‐coupled pair and four OTAs for the doublet core cell. Thus, we consider the generalized OTAs for an arbitrary order n of the core cell and obtain a formula to give the realization number of the linear OTAs for n. According to the formula, there must be eight OTAs in the case of n=3. All of the eight OTAs are examined. Analysis and simulation results show that the OTAs have advantage in their characteristics, such as linear input range, power dissipation, noise, and frequency response. Copyright 2004 John Wiley & Sons, Ltd. 相似文献