Exergetic analysis of an LPG evaporator/regulator with thermal storage

In this study, the efficiency of an LPG evaporator/regulator (E/R) is investigated on both energy and exergy concept. The E/R, which is a key part of LPG conversion systems that enables gasoline engines to be operated on LPG when desired, has been transformed to a thermal energy storage (TES) system using an adequate amount of phase change material (PCM) to be able to store waste energy of the engine coolant, so that the engine can be operated on LPG rather than gasoline even at cold start to decrease fuel consumption and exhaust emissions. The engine has been tested at idle speed at 4 °C environment temperature. The PCM application provided the engine to be operated on LPG at cold start and increased the efficiency of the E/R in a considerable extent on both energy and exergy bases. It was observed that using PCM in the E/R for thermal storage, the net efficiency differences of the E/R with PCM application reach to the values of 20% and 10%, respectively for the energy and exergy calculations. The net 2nd law efficiencies were lower than the ones that of 1st law with the values of about 11% for gasoline operation, and 8% for LPG operation of the engine.     

The effects of hypercapnia on early and later phases of phrenic neurogram during early maturation

In this paper, we investigate the influence of hypercapnia on the early and late phases of the phrenic neurogram using the matching pursuit (MP) method in the decebrated piglets. The phrenic neurogram was recorded from 8 piglets (4-7 days old) during control (40% O2 with 5% end-tidal CO2), the mild hypercapnia (40% O2 with 7% end-tidal CO2), and the severe hypercapnia (40% O2 with 15% end-tidal CO2). The time-frequency representations, atoms, of the phrenic neurogram are calculated from the 5 consecutive phrenic neurogram burst for each piglet for each condition using the MP method after vagotomy and chemodenervation. Our results show that the energy percentage of atoms representing the nonperiodic neural activities (NPNAs) significantly increased when the CO2 concentration was shifted from 7% to 15% in the early phase (the first half) of the phrenic neurogram. In addition, the energy percentage of atoms representing the periodic neural activities (PNAs) decreased in the late phase (the second half) when the CO2 concentration was shifted from 7% to 15% (p < 0.01). As a summary, our result suggest that hypercapnia results in significant changes in the phrenic neurogram, an output of the respiratory neural networks in the medulla, both in time and frequency domians during early maturation.     

A tribological and biomimetic study of PI–CNT composites for cartilage replacement

This article presents an investigation into the possible matching of mechanical properties of a polyimide (PI)–carbon nanotube (CNT) composite system to natural cartilage tissue. Currently used ultrahigh molecular weight polyethylene (UHMWPE) used in total joint replacements presents certain drawbacks due to a mismatch in mechanical and tribological properties with those of a natural bone joint. Natural cartilage tissue is a composite material itself, being composed of collagen fibers, hydrophilic proteoglycan molecules, cells and other constituents. The current investigation attempts to mimic the mechanical and tribological properties of natural cartilage tissue by varying the CNT concentration in a PI matrix. Nanoindentation and pin-on-flat tribological tests were conducted for this purpose. It was found that the coefficient of friction (COF) reached a minimum at a concentration of 0.5% CNT (by volume) when articulated against Ti6Al4V alloy. When articulated against Ti6Al4V alloy in the presence of a lubricant, the minimum COF was obtained at a concentration of 0.2% CNT. The maximum penetration depth under nanoindentation varied with CNT concentration and indicated that the mechanical properties could be tailored to match that of cartilage tissue. A closer investigation into this behavior was carried out using scanning electron, transmission electron, and atomic force microscopy. It was noticed that there is good bonding between the CNTs and polyimide matrix. There was a ductile to brittle transition as the concentration of CNT was increased. Competing interactions between nanotube–matrix and nanotube–nanotube are possible reasons for the deformation and friction behavior identified.     

Concentration of phenolic compounds from apple pomace extracts by nanofiltration at lab and pilot scale with a techno‐economic assessment

Apple pomace can be used as resource for the extraction of phenolic compounds with antioxidant properties. Pressing of apple in juice and pomace at lab scale in open air (aerobic) and under N₂ atmosphere (anaerobic) showed a recovery of phenolic compounds of 85% in juice and pomace after anaerobic pressing, compared to 43% after aerobic pressing, indicating loss of phenolic compounds by oxidation and the advantage of anaerobic over aerobic pressing. After a membrane screening and concentration test at lab scale, the commercial nanofiltration membrane NFX was selected to concentrate phenolic compounds in an ethanol : water extract of apple pomace. At pilot scale, the concencentration of 10 selected phenolic compounds and quinic acid increased from 59.5 mg/L in the ethanol : water extract to 1256.1 mg/L in the final retentate, that is, by a factor 21.1. The volume of the crude extract was reduced by a factor of 28.5 during the filtration, indicating some loss of phenolic compounds during pilot testing due to membrane fouling or oxidation of polyphenols. The pilot concentration test using a spiral‐wound membrane module showed good flux and concentration of phenolic compounds, indicating the technical feasibility of membrane technology for efficient concentration of polyphenols in an ethanol : water extraction solvent. Unfortunately, the extraction and concentration process was not economically feasible under the assumptions made.

Practical applications

The valorization of food waste for the production of high‐added value products is an increasingly hot topic. Phytochemicals are present in relatively low concentration in the fruit matrix, and concentration in the extraction solvent is necessary to develop an industrially relevant process. In this study, membrane filtration was selected for concentration due to its low energy consumption and mild processing conditions compared to other technologies. Membrane screening and testing at lab and pilot scale with techno‐economic assessment can be used by food and nutraceutical industries to evaluate membrane technology for concentration of phytochemicals extracted from agroindustrial by‐products.     

Comparison of textile dyeing effluent adsorption on commercial activated carbon and activated carbon prepared from olive stone by ZnCl2 activation

Adsorption of Remazol Red B on activated carbon prepared from olive stone and commercial activated carbon from aqueous solutions was compared. Different activating agent (ZnCl₂) amounts and adsorbent particle size were studied to optimize adsorbent surface area. The adsorptive property of commercial activated carbon and activated carbon prepared from olive stone were investigated in terms of adsorbent dose, temperature, equilibrium time and pH. Then the obtained results were compared for all parameters, According to the results, the equilibrium time, optimum pH, adsorbent dosage were found 60 min, pH < 3–4 and 1.0 g/50 ml respectively. Lower adsorption capacity for RRB on activated carbon prepared from olive stone was found. The kinetic data for both adsorbents supports pseudo-second order model (r² > 0.99) and intra-particle model (r² > 0.95) but the first order kinetic model did not adequately fit to the experimental values (r² < 0.76). The equilibrium adsorption data were interpreted using Langmuir and Freundlich models. The adsorption of Remazol Red B was better represented by the Langmuir equation. In addition, the thermodynamic parameters, standard free energy (ΔG°), standard enthalpy (ΔH°), standard entropy (ΔS°) of the adsorption process were calculated for both adsorbents. To reveal the adsorptive characteristics of the produced active carbon, surface area measurements were carried out and structural analysis was performed using SEM-EDS.     

The Effects of Electromagnetic Brake on Liquid Steel Flow in Thin Slab Caster

Computational fluid dynamics (CFD) model with magneto hydro dynamics (MHD) is developed for a thin slab caster to investigate the effects of electromagnetic brake (EMBr) on liquid steel flow in continuous casting mold and to determine the EMBr practices which lead to optimal flow structure. Particle Image Velocimetry (PIV) tests in water model and meniscus flow measurements in real caster are performed to validate the predictions obtained with CFD models. The performance of different submerged entry nozzle designs, SEN 1 and SEN 2, are evaluated. The effects of nozzle submergence in relation to the applied magnetic field on mold flow structure are quantified. There are significant differences between flow structures obtained with SEN 1 and SEN 2, even though both designs have fundamental similarities and contain four ports. EMBr mainly reduces the meniscus velocities for SEN 2 as opposed to the foremost influence of EMBr for SEN 1 that is to significantly slow down the downward jet coming from the bottom ports. In addition, reducing the EMBr strength for shallow nozzle submergence and increasing the EMBr strength for deep nozzle submergence help to maintain similar meniscus activity for all conditions.     

n-Channel semiconductor materials design for organic complementary circuits

Organic semiconductors have unique properties compared to traditional inorganic materials such as amorphous or crystalline silicon. Some important advantages include their adaptability to low-temperature processing on flexible substrates, low cost, amenability to high-speed fabrication, and tunable electronic properties. These features are essential for a variety of next-generation electronic products, including low-power flexible displays, inexpensive radio frequency identification (RFID) tags, and printable sensors, among many other applications. Accordingly, the preparation of new materials based on π-conjugated organic molecules or polymers has been a central scientific and technological research focus over the past decade. Currently, p-channel (hole-transporting) materials are the leading class of organic semiconductors. In contrast, high-performance n-channel (electron-transporting) semiconductors are relatively rare, but they are of great significance for the development of plastic electronic devices such as organic field-effect transistors (OFETs). In this Account, we highlight the advances our team has made toward realizing moderately and highly electron-deficient n-channel oligomers and polymers based on oligothiophene, arylenediimide, and (bis)indenofluorene skeletons. We have synthesized and characterized a "library" of structurally related semiconductors, and we have investigated detailed structure-property relationships through optical, electrochemical, thermal, microstructural (both single-crystal and thin-film), and electrical measurements. Our results reveal highly informative correlations between structural parameters at various length scales and charge transport properties. We first discuss oligothiophenes functionalized with perfluoroalkyl and perfluoroarene substituents, which represent the initial examples of high-performance n-channel semiconductors developed in this project. The OFET characteristics of these compounds are presented with an emphasis on structure-property relationships. We then examine the synthesis and properties of carbonyl-functionalized oligomers, which constitute second-generation n-channel oligothiophenes, in both vacuum- and solution-processed FETs. These materials have high carrier mobilities and good air stability. In parallel, exceptionally electron-deficient cyano-functionalized arylenediimide derivatives are discussed as early examples of thermodynamically air-stable, high-performance n-channel semiconductors; they exhibit record electron mobilities of up to 0.64 cm(2)/V·s. Furthermore, we provide an overview of highly soluble ladder-type macromolecular semiconductors as OFET components, which combine ambient stability with solution processibility. A high electron mobility of 0.16 cm(2)/V·s is obtained under ambient conditions for solution-processed films. Finally, examples of polymeric n-channel semiconductors with electron mobilities as high as 0.85 cm(2)/V·s are discussed; these constitute an important advance toward fully printed polymeric electronic circuitry. Density functional theory (DFT) computations reveal important trends in molecular physicochemical and semiconducting properties, which, when combined with experimental data, shed new light on molecular charge transport characteristics. Our data provide the basis for a fundamental understanding of charge transport in high-performance n-channel organic semiconductors. Moreover, our results provide a road map for developing functional, complementary organic circuitry, which requires combining p- and n-channel transistors.     

Preparation and application of glycidyl methacrylate and methacrylic acid monomer mixture‐grafted poly(ethylene terephthalate) fibers for removal of methylene blue from aqueous solution

A novel fibrous adsorbent that grafts glycidyl methacrylate (GMA) and methacrylic acid (MAA) monomer mixture onto poly(ethylene terephthalate) (PET) fibers was used for removal of methylene blue (MB) in aqueous solutions by a batch equilibration technique. The operation parameters investigated included, pH of solution, removal time, graft yield, dye concentration, and reaction temperature. The adsorption rate of MB is much higher on the MAA/GMA‐grafted PET fibers than on the ungrafted PET fibers. MB was removed 99% the initial dye concentration at 10 mg L⁻¹ and 93% at 200 mg L⁻¹ by monomers mixture‐grafted PET fibers. Pseudofirst order and pseudosecond order kinetic equations were used to examine the experimental data of different graft yield. It was found that the pseudosecond order kinetic equation described the data of dye adsorption on fibrous adsorbent very well. The experimental isotherms data were analyzed using Langmuir and Freundlich isotherm models. The data was that Freundlich isotherm model fits the data very well for the dyes on the fibers adsorbent. The dye adsorbed was easily desorbed by treating with acetic acid/methanol mixture (50% V/V) at room temperature. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010