Clinical experiences of play therapists: Does race/ethnicity matter?

The authors describe racial/ethnic similarities and differences of a sample of 891 members of the Association for Play Therapy with regard to workplace variables, professional interests and activities, and supervision variables. Results indicate few differences between Caucasian and racial/ethnic minorities and few differences between the racial/ethnic groups. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Application of the DEPT pulse sequence for the generation of 13CHn subspectra of coal-derived oils

The application of the recently developed DEPT pulse sequence for the generation of ¹³CH_n subspectra of coal-derived oils is determined. The technique is able to generate subspectra with accurate cancellation of signals of unwanted multiplicity for complex oil mixtures containing broad and overlapping resonances. However, the use of signal intensities in DEPT subspectra to determine quantitatively the amounts of CH_n groups present in oil mixtures suffers in accuracy due to variable polarization transfer and relaxation rates.     

The effects of lithium hydroxide solution on alkali silica reaction gels created with opal

The reaction of Nevada opal with calcium hydroxide, potassium hydroxide and lithium hydroxide solutions was investigated. In addition, opal was exposed to a combined solution of these three hydroxides. The progress of the three reactions was followed using X-ray diffraction (XRD), ²⁹Si nuclear magnetic resonance (NMR) and scanning electron microscopy (SEM). The XRD results indicated the presence of a low-angle peak exclusive to the lithium-based reactions. The NMR results suggested a change in the silicate structure in the presence of lithium. These techniques indicated that the reaction of the alkali with the opal starting material is inhibited and perhaps stopped in the presence of lithium hydroxide. SEM revealed that the morphology of the reaction products on the surface of the reacted opal grains is markedly different invariably. It was concluded that evidence to support the theory of a protective layer exists and that the nature of the layer varies with ion type.     

Segmental mobility in poly(isoprene) rubber studied by deuterium-carbon NMR correlation spectroscopy

Summary A HMQC based deuterium-carbon correlation method is used for the first time to study the segmental mobility in a fully deuterated poly(isoprene) (PI) rubber network. The isotropic J _CD couplings can be utilized for polarization transfer between ²H and ¹³C spins in a mobile solid polymer. This makes it possible to correlate the ²H resonances with the ¹³C chemical shifts of the attached carbon in a two-dimensional (2D) experiment, and thus allow the extraction of the individual ²H signals. The experimental data obtained from the 2D correlation spectrum indicates differences in the segmental mobility of the C-D vectors in perdeuterated PI. The conclusions are fully consistent with ²H and ¹³C T ₁ relaxation data. The results shown in this paper demonstrate the potential of ²H-¹³C NMR correlation spectroscopy in solid systems which produce overlapped 1D ²H spectra. Received: 11 December 2000/Revised version: 1 March 2001/Accepted: 1 March 2001     

Utilisation of time-variant influence functions in the computer controlled polishing

In the computer controlled polishing, a polishing tool moves in a well-defined manner across the workpiece surface in order to individually remove the surface error-profile. The commonly used technique to calculate the moving of the polishing tool is the dwell time method. Based on a constant (time-invariant) removal characteristic of the polishing tool (influence function) the amount of material to be removed is controlled via the dwell time. The longer the polishing tool is in contact with a particular area of the workpiece, the more material is removed at this position.Mathematical basics to calculate dwell time-profiles are shown, and a new approach considering time-variant influence functions for the computer controlled polishing is introduced. The results point out that time-variant influence functions may contribute to further decrease the process time, and thus to make a computer controlled polishing process more efficient. The reduction of the process time was observed to approximately 35% using a combination of the dwell time method with time-variant influence functions.     

Simulation of a complex optical polishing process using a neural network

 Most modern manufacturing processes change their set of parameters during machining in order to work at the optimum state. But in some cases, like computer-controlled polishing, it is not possible to change these parameters during the machining. Then usually a standard set of parameters is chosen which is not adjusted to the specific conditions. To gather the optimum set of parameters anyway simulation of the process prior to manufacturing is a possibility. This research illustrates the successful implementation of a neural network to accomplish such a simulation. The characteristic of this neural network is described along with the decision of the used inputs and outputs. Results are shown and the further usage of the neural network within an automation framework is discussed. The ability to simulate these advanced manufacturing processes is an important contribution to extend automation further and thus increase cost effectiveness.     

Images and the Growth of Understanding of Mathematics-for-Working

Abstract

Some of mathematics teaching is routine, like an exercise from a textbook for which you have received instruction and already know what to do. On other occasions, however, teaching mathematics is challenging, involving problems of teaching for which the solutions may not be readily apparent. These situations require the application of mathematical knowledge in concert with other types of knowledge for teaching. In this article, we explore the idea that teachers of mathematics act as applied mathematicians in applying mathematical knowledge to the resolution of teaching problems. This task involves the complex interplay of mathematical and teaching knowledge and processes of problem solving with success judged according to how well students learn. The article discusses these ideas through an examination of seven scenarios.