饰面型防火涂料阻燃防火机理及研究进展

探讨了饰面型防火涂料的阻燃及防火机理,阐述了我国饰面型防火涂料的研究进展。结合饰面型防火涂料在实际使用过程中烟气毒性、挥发性有机化合物的安全环保问题,对我国饰面型防火涂料的发展趋势进行了展望。     

椭圆对称奇异空心光束通过硬边光阑的传输特性

通过将圆孔光阑函数展开为有限复高斯函数和的方法,利用惠更斯-菲涅耳衍射积分推导出了椭圆对称奇异空心光束通过具有圆孔光阑的近轴ABCD光学系统的传输近似解析公式,并对椭圆对称奇异空心光束在自由空间中通过不同孔径下的硬边光阑的传输特性进行了数值模拟研究。结果表明:自由空间中的近轴光学系统无论在近场还是远场,椭圆对称奇异空心光束的衍射光强分布都与光阑大小有很大的关系。该研究方法对椭圆对称奇异空心光束通过具有圆孔光阑的传输和变换的研究非常有益。     

Growth of Pb((Zn1/3Nb2/3)0.91Ti0.09)O3 Single Crystals Using an Allomeric Seed Crystal and Their Electrical Properties

Single crystals of Pb((Zn_1/3Nb_2/3)_0.91Ti_0.09)O₃ (PZNT 91/9), 28 mm in diameter and 30 mm in length, have been successfully grown using a modified Bridgman technique with an allomeric seed crystal. X-ray fluorescence analysis (XRFA) measurement confirms that the effect of segregation is not serious. The segregation coefficient k for PbTiO₃ content during crystal growth is 0.99, which causes some fluctuation in the composition along the growth direction. The fluctuation of composition and the complicated domain structure cause a variation of electric properties. Dielectric measurement indicates that PZNT 91/9 crystals exhibit an almost normal ferroelectric phase transition at ∼183°C from the tetragonal phase to the cubic phase. In addition, a weak frequency-dependent ferroelectric-ferroelectric phase transition is observed at ∼85°C, which is attributed to partial conversion of the rhombohedral phase to a tetragonal phase. The dielectric thermal hysteresis behavior and the existence of polarization above the Curie temperature verify that the phase transitions at ∼85° and 183°C are first order with a slight diffuse character and first order, respectively. It is demonstrated that the effects of segregation can be decreased and the homogeneity of the obtained PZNT 91/9 single crystals can be improved by optimizing growth parameters.     

CDMA蜂窝网中功率控制对系统容量的影响

ＣＤＭＡ蜂窝网中存在远近效应，必须引入功率控制。功率控制对系统容量有极大的关系。本针着重功率控制精度以系统容量的影响，提出功率控制的高斯误差颁假设，并得到系统容量随功率控制变化的规律及可参考的计算方法。     

汽车油箱翻边机设计

介绍全自动液压式油箱翻边机的设计。实践证明,此专机保证了产品质量,满足了现代化生产的需要。     

富硒大蒜中不同含硒蛋白抗氧化活性的研究

以恩施高硒地区产富硒大蒜为研究对象,采用连续提取法依次提取不同种类的蛋白质;采用D-脱氧核糖法、改进邻苯三酚自氧化法及TBA比色法分析4种含硒粗蛋白清除自由基及抗脂质过氧化的效果。结果表明:4种含硒粗蛋白对清除羟基自由基.OH、O2-.具有较好的量效关系,其活性由弱到强次序为醇溶性蛋白盐溶性蛋白碱溶性蛋白水溶性蛋白。在体外反应体系中,水溶性、碱溶性和盐溶性蛋白能显著降低MDA生成量和肝中过氧化物的含量,说明富硒大蒜含硒粗蛋白对肝组织损伤具有良好的保护作用。通过抗氧化活性与硒含量之间的相关性分析,两者之间存在显著或极显著的正相关性。     

高效煤粉锅炉粉煤灰在熟料生产中的应用

山东东华水泥有限公司目前有两条5 000 t/d熟料生产线, 处理我市高效环保煤粉锅炉的产生的粉煤灰。通过增加高效煤粉锅炉粉煤灰的储存、计量和输送设备,实现了高效煤粉锅炉粉煤灰计量可控的掺加到生料中,并随生料一起进入回转窑煅烧的工艺途径,成功地解决了高效煤粉锅炉粉煤灰因成分波动大、烧失量高导致的水泥磨消耗量有限的处置瓶颈。     

我公司四代篦冷机换热效率提升改造

山东东华水泥有限公司目前有两条5 000 t/d熟料生产线,二线采用FL-Smith推动棒式篦冷机,为了降低熟料成本,熟料产量提高到6 300 t/d以上,原有篦冷机不能满足生产要求,出现篦床料层偏厚、篦床推动棒磨损大、熟料热交换率低、出篦冷机熟料温度过高等问题,既影响了篦冷机的使用寿命,又增加了煤耗。因此,我公司对二线篦冷机部分高压风机、流量调节阀等进行了改造,效果明显。     

Phase‐Controlled Synthesis of Monolayer Ternary Telluride with a Random Local Displacement of Tellurium Atoms

Alloying 2D transition metal dichalcogenides has opened up new opportunities for bandgap engineering and phase control. Developing a simple and scalable synthetic route is therefore essential to explore the full potential of these alloys with tunable optical and electrical properties. Here, the direct synthesis of monolayer WTe_2xS_2(1?x) alloys via one‐step chemical vapor deposition (CVD) is demonstrated. The WTe_2xS_2(1?x) alloys exhibit two distinct phases (1H semiconducting and 1T ′ metallic) under different chemical compositions, which can be controlled by the ratio of chalcogen precursors as well as the H₂ flow rate. Atomic‐resolution scanning transmission electron microscopy–annular dark field (STEM‐ADF) imaging reveals the atomic structure of as‐formed 1H and 1T ′ alloys. Unlike the commonly observed displacement of metal atoms in the 1T ′ phase, local displacement of Te atoms from original 1H lattice sites is discovered by combined STEM‐ADF imaging and ab initio molecular dynamics calculations. The structure distortion provides new insights into the structure formation of alloys. This generic synthetic approach is also demonstrated for other telluride‐based ternary monolayers such as WTe_2xSe_2(1?x) single crystals.     

基于能量变化的暂态频率安全紧急控制决策方法研究

从能量变化的视角,研究频率安全紧急控制决策问题。基于系统整体频率特性与系统等值同步发电机转子动能的关系,将频率安全约束转化为对系统等值同步发电机转子动能的约束。基于系统等值同步发电机转子动能变化与不平衡功率累积能量的关联,分析频率安全控制机理。研究通过控制不平衡功率累积能量实现频率安全控制目标的控制决策方法,将以往通过控制不平衡功率,转化为暂态过程的能量控制,从而使控制决策更为灵活。通过实际电网数据仿真验证方法的正确性。