原油破乳脱钙复合剂的研制

介绍了原油破乳脱钙复合剂的筛选方法。所用的破乳剂有PY、UD 10、2 0 40、SDX、SL、硬脂酸 三乙醇胺 ,所用的脱钙剂有KL 1、KL 2、KL 3、KL 4、YH、EA、SJ、LP。首先将一定量的破乳剂与原油混合 ,振荡、静置 ,按油水分层情况及脱水率 ,筛选出较优的破乳剂。然后 ,在已加入破乳剂的原油中加入一定量的脱钙剂水溶液 ,振荡、静置 ,用燃烧瓶法处理油样 ,用原子吸收分光光度计测其钙含量 ,并与未经处理的原油对比。根据脱钙率 ,筛选出较优的脱钙剂。经过对破乳剂和脱钙剂的种类、用量、pH值等条件的选择 ,配出了针对俄罗斯原油、布伦特原油、扎非罗原油破乳、脱钙效果最好的复合剂PY YH、PY EA ,其脱钙率大于 80 %,脱水率大于98%,可直接用于炼厂的原油破乳脱钙工艺中。     

Preparation of the TiB2 coatings by electroplating in molten salts

The improvement of titanium diboride (TiB₂) coatings over the molybdenum substrate was investigated by comparing the electrochemical techniques of continuous current plating (CCP) and periodically interrupted current (PIC). The solvent used was a eutectic Flinak mixture (LiF-NaF-KF, 46.5:11.5:42 molar ratio) with solutes K₂TiF₆ and KBF₄ with the electrochemically-active components in the molar ratio of one to five. The coatings produced by PIC show improvements in morphology and microstructure for the suitable conditions: i = 0.5 A/cm², frequency = 100 Hz, the time ratio t_c/t_off (current on/current off) = 4/1. X-ray diffraction (XRD) analyses indicated that the coatings are composed of the relatively pure TiB₂ and the preferred orientation is [001] + [110], which is in accordance with the prediction of the two-dimensional crystal nuclei theory.     

Effects of alloying elements on fracture toughness in the transition temperature region of base metals and simulated heat-affected zones of Mn-Mo-Ni low-alloy steels

This study is concerned with the effects of alloying elements on fracture toughness in the transition temperature region of base metals and heat-affected zones (HAZs) of Mn-Mo-Ni low-alloy steels. Three kinds of steels whose compositions were varied from the composition specification of SA 508 steel (grade 3) were fabricated by vacuum-induction melting and heat treatment, and their fracture toughness was examined using an ASTM E1921 standard test method. In the steels that have decreased C and increased Mo and Ni content, the number of fine M₂C carbides was greatly increased and the number of coarse M₃C carbides was decreased, thereby leading to the simultaneous improvement of tensile properties and fracture toughness. Brittle martensite-austenite (M-A) constituents were also formed in these steels during cooling, but did not deteriorate fracture toughness because they were decomposed to ferrite and fine carbides after tempering. Their simulated HAZs also had sufficient impact toughness after postweld heat treatment. These findings indicated that the reduction in C content to inhibit the formation of coarse cementite and to improve toughness and the increase in Mo and Ni to prevent the reduction in hardenability and to precipitate fine M₂C carbides were useful ways to improve simultaneously the tensile and fracture properties of the HAZs as well as the base metals.     

大水矿床残矿开采技术研究

莱芜铁矿业庄矿区为一大水矿床，曾采用预留护顶矿层隔水进路采矿法开采，—25m中段以上矿体已呈蜂窝状。为回收该部份残矿体，针对该矿体的具体特征，采用有限元法模拟采矿开挖步骤，并对采场结构参数进行优化；改进凿岩爆破工艺，改善了爆破效果，达到了安全、经济回采的目的。可为类似矿床开采提供借鉴。     

多功能复合化学剂在蒸汽吞吐中的应用

辽河油田稠油热采以蒸汽吞吐开采为主,随着注汽轮次的不断增加、生产过程中各种工艺措施的不断介入,油藏受热水及其它侵入介质的影响,综合含水逐步上升,油层近井地带污染日益严重,直接影响了采收率,限制了稠油的高效开发.从油藏地质条件变化和伤害机理入手,开发研制出注蒸汽化学辅助技术--多功能复合化学剂.室内试验和现场应用表明,该技术能有效降低原油粘度、疏通油层、降低油水界面张力、改善稠油流动性、增加油层能量、提高采收率,从根本上改善稠油热采效果.     

组建实时可靠安全的工业以太网

工业以太网在企业的信息层、控制层和设备层网络中得到了越来越多的应用。本文从实时性、网络弹性、可靠性和安全性的角度对工业应用的具体要求进行了分析，提出了在组建工业以太网时需要注意的若干主要问题。     

企业信息化中的网络存储整合应用

首先介绍了网络存储技术中NAS技术和SAN技术的基本原理,并对两者的特性进行了比较;然后详细介绍了企业信息化过程中网络存储整合的一个典型案例,分析了其整合前存在的不足,制定有效的整合实施方案,并对实施过程中许多关键技术部分进行了阐述,最终很好的达到了预定目标;最后总结了网络存储整合需要规划多种技术相融合的必要性.     

桥梁检测综合作业车工作装置控制策略研究

以桥梁检测综合作业车工作装置液压缸为研究对象，在建立液压缸位置控制系统模型基础上，采用Matlab7．1进行了仿真和动态分析，研究了电液位置控制比例系统的动态特性。在分析传统PID及模糊控制器优缺点的基础上提出了PI＋模糊规则自校正的控制策略，仿真结果表明采用这种控制方法，电液位置控制比例系统的动态特性能满足性能要求。     

分形理论在固体吸附式制冷系统中的应用研究

固体吸附式制冷系统中吸附剂一般是多孔介质结构，吸附剂的内部结构特征对传热特性和吸附质的传质特性有直接影响，进而影响吸附解吸时间。本文探讨利用分形理论来分析固体吸附剂的结构特点，为目前通过对吸附剂的固化处理来提高吸附剂的传热速率的处理方法提供理论上的分析，并指出最佳分形维数的分形结构。     

双功能加氢精制催化剂在焦化富气制氢中的应用

介绍了JT-1G／JT-4加氢精制催化剂的烯烃饱和功能和有机硫转化功能；阐述了该催化剂在中石油辽河石化分公司、浙江工程设计院共同开发的用于焦化富气制氢原料的烯烃饱和及有机硫转化的新加氢工艺——逆流-等温-绝热加氢精制工艺中的使用情况。原料中体积分数13％～16％的烯烃经过加氢精制后降至0；原料中有机硫得到充分转化；焦化富气经过加氢精制后，满足了作为制氢原料的要求，降低了制氢成本。