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981.
982.
The electrochemical behavior of the Fe(III)/Fe(II)-triethanolamine(TEA) complex redox couple in alkaline medium and influence of the concentration of TEA were investigated. A change of the concentration of TEA mainly produces the following two results. (1) With an increase of the concentration of TEA, the solubility of the Fe(III)-TEA can be increased to 0.6 M, and the solubility of the Fe(II)-TEA is up to 0.4 M. (2) In high concentration of TEA with the ratio of TEA to NaOH ranging from 1 to 6, side reaction peaks on the cathodic main reaction of the Fe(III)-TEA complex at low scan rate can be minimized. The electrode process of Fe(III)-TEA/Fe(II)-TEA is electrochemically reversible with higher reaction rate constant than the uncomplexed species. Constant current charge-discharge shows that applying anodic active materials of relatively high concentrations facilitates the improvement of cell performance. The open-circuit voltage of the Fe-TEA/Br2 cell with the Fe(III)-TEA of 0.4 M, after full charging, is nearly 2.0 V and is about 32% higher than that of the all-vanadium batteries, together with the energy efficiency of approximately 70%. The preliminary exploration shows that the Fe(III)-TEA/Fe(II)-TEA couple is electrochemically promising as negative redox couple for redox flow battery (RFB) application. 相似文献
983.
对冰箱用聚氨酯泡沫塑料的密度分布机理进行了探讨,为配方和工艺优化提供了有价值的参考,并通过对密度分布的研究来解决冰箱泡沫的其他性能缺陷。 相似文献
984.
厌氧发酵处理味精废水中氯离子的影响 总被引:6,自引:0,他引:6
在3L 的CSTR 型厌氧反应器中研究了味精废水厌氧处理中氯离子毒性的反应。试验证明,已中毒的厌氧过程只要Cl~-浓度降至抑制限以下,厌氧过程就可在15~20d 内恢复,在恢复期间加入新污泥有利于恢复过程。保持足够大的SRT 和污泥浓度对于处理含有毒物的废水很有效。对本研究,SRT 得大于20d,污泥浓度在15~24g/L 左右就可达到较好的处理效率。Cl~-的抑制浓度对污泥浓度分别为24.28g/L,15.18g/L 和6.07g/L 时,Cl~-的抑制浓度分别是7750mg/L,7250mg/L和6300mg/L。此外,本文提出以I=S_(Cl)/X_v~n作为判断Cl~-抑制的指标。当COD 去除率大于80%时,n=0.1519。因此,要使过程的COD 去除率分别大于80%,85%和90%时,I 就得分别小于4.7,4.1和3.6。并且污泥浓度必须大于6.07g/L。 相似文献
985.
抛秧田杂草不但种类多,危害重,而且化除难度大,技术要求高,据1993-1995年的试验、示范结果证明,一般草害田,掌握在抛栽后10-15天,每公顷用50%二氯喹啉酸375-450克加10%苄嘧黄隆150-225克,采用喷雾或毒土法防治一次,对稗草和多种阔叶草的防效一般可稳定在90-93%左右,并且可使亩产增加2成左右,但多草田和漏水田,则应通过二次用药或提高药剂用量的方法加以解决。 相似文献
986.
周祝林 《玻璃钢/复合材料》1995,(6):13-18
本文讨论产生复合材料产品固化变形的主要原因是树脂收缩引起的各方向上不同的线膨胀系数具体分析了复合材料夹层结构的的固化变形,经技术上的改进解决了固化变形,以满足产品的设计要求。 相似文献
987.
988.
Yong Peng Xinguo Sun Xiaoli Zhang Huicheng Zhou Zixin Zhang 《Water Resources Management》2017,31(3):1031-1045
The hydraulic projects, such as reservoirs, ponds, and paddy fields, have a marked influence on the generation of floods, causing a number of difficulties where hydrological forecasting is concerned. To consider the influence of the hydraulic projects in hydrological forecasting, a modified TOPMODEL is presented in the paper, based on the simulation rules of the aggregate reservoir’s retaining and discharging (ARRD). In the new purposed model, termed as ARRD-TOPMODEL, the hydraulic projects are first aggregated as an equivalent reservoir, then the simulation rules of the aggregate reservoir’s retaining and discharging are determined, finally, the simulation rules are combined with an original TOPMODEL model calibrated using the floods not influenced by the hydraulic projects for flood forecasting. The ARRD-TOPMODEL was tested on the upstream of Wudaogou station basin in Northeast China. The results show that compared to the original model, the qualified rate (i.e., the ratio of the number of floods that meet acceptable criteria and the total number of floods) of runoff forecasting was increased from 73% to 100%. The problems that the overestimation of the runoff at beginning of flood season and after a long drought, as well as that the underestimation of the large flood in middle flood season are both solved, and the flood processes predicted by the new model are more consistent with the observed ones. All of these demonstrate that the newly developed model is superior to the original one and the simulation rules of the aggregate reservoir’s retaining and discharging are capable of accurately accounting for the influence of the hydraulic projects on the floods. 相似文献
989.
Huyong Yan Guoyin Wang Di Wu Yu Huang Mingsheng Shang Jianjun Xu Kun Shan Xiaoyu Shi Jianhua Dong Lei Feng Botian Zhou Ye Yuan Yufei Zhao 《Water Resources Management》2017,31(5):1435-1456
In the field of water quality management, it is vital to determine the main precursory anomalies from the precursor of intricate water bloom in the context of a given area. In this paper, a water bloom precursor analysis method, based on two direction singular rough set, was proposed. This approach was produced on the basis of the different sections and pre-water bloom of water bloom precursor anomalies and characteristic of elements transferred in singular rough set. For testing the validity of two direction singular rough set application in water bloom precursor analysis, Xiangxi River, which is one of the typical tributaries of Three Gorges Reservoir in China, was selected as study area. The result showed that compared with other indexes, pH and dissolved oxygen (DO) are the most valuable indicators of water bloom in the precursory anomalies. Furthermore, regarding with water bloom precursory anomalies in Xiangxi River, most of the nutrient loading and biological community are the key indicators. Hence, this method can determine the main precursory anomaly for water bloom in the study area, which provides powerful knowledge support to water quality specialists for them to comprehensively analyze precursory anomaly so as to find out its relationship with occurrence law of water bloom. 相似文献
990.
Analysis of the Spatial Characteristics of the Water Usage Patterns Based on ESDA-GIS: An Example of Hubei Province,China 总被引:1,自引:0,他引:1
The spatial characteristics and the high-duty water regions of the Water Usage Patterns (WUP) are very important for the allocation and management of water resources. Taken Hubei province, China as an example, we adopted the exploratory spatial data analysis (ESDA) method to investigate the spatial dependence and local patterns of the WUP from 2003 to 2012. Subsequently, the spatial variation mechanisms were analyzed through the gravity center model. The results indicated that the overall spatial dependence of the agricultural WUP was detected (more significant after 2008). Moreover, the global spatial autocorrelation analysis results on the domestic WUP showed statistical significance (Moran’s I?>?0.1, P?<?0.05). These indicated that the local patterns were presented. The high values clustering areas of the agricultural and domestic WUP were mainly distributed in the central province and in the western province respectively. However, the approximate random distribution was identified for the industrial WUP because the industrial development had been conducted widely in the whole province during these years. Furthermore, the governmental policies and natural environment contributed to the spatial evolution tendency of the WUP. An increasing trend of the spatial association of the agricultural WUP and a significant decreasing trend of that of the domestic WUP, which suggested that the natural circumstance superiority and the industrial structure adjustment related to water utilization has been utilized and implemented effectively. This study can provide a useful reference and guidance for scientific planning of water resource systems. 相似文献