Downhole Upgrading of Extra-heavy Crude Oil Using Hydrogen Donors and Methane Under Steam Injection Conditions

An extra-heavy crude oil underground upgrading process is described which involves the downhole addition of a hydrogen donor additive under steam injection conditions (280-315°C and residence times of at least 24-h). Laboratory experiments showed a 4° increase in the API gravity (from 9 to 12°) of the upgraded product, a two-fold reduction in the viscosity and, an approximately 8% decrease in the asphaltene content with respect to the original crude. Further increases on the temperature led to products with improved properties reaching 15°API at 315°C. It was found that the presence of the natural formation (catalysts) and methane (natural gas) is necessary to enhance the properties of the upgraded crude oil. From GC and GC-MS results a reaction pathway is proposed that involves hydrogen transfers from tetralin to the extra-heavy crude oil resulting in the formation of 1,2-dihydronaphthalene. This compound is then transformed into naphthalene, further upgrading of crude oil through hydrogen donation. The results of the experiments carried out in the presence and absence of the mineral formation and with an inert solid (SiC) strongly indicate that the former acts as a catalyst and not as a heat transfer matrix. Isotopic labeling studies (CD₄ and ¹³CH₄) give evidences that, most probably, methane is involved in the upgrading reactions.     

Computer simulation of the effective double layer occurring on a catalyst surface under electro-chemical promotion conditions

In this work, the structural and energetic properties of two typical catalytic surfaces, Na/Pt(111) and O/Pt(111), are studied by means of quantum mechanical calculations and Monte Carlo Grand Canonical simulations. The simulations were performed with electrostatic potentials at different truncation schemes. In order to elucidate the modification of catalyst surfaces produced by the backspillover of ionic species onto Pt(111), the electrostatic field at the interface due to the electric double layer was also analyzed.     

Virtual Teams: Guide to Successful Implementation

The successful initiation and execution of a virtual team is gaining increasing attention in the design and construction community. From opportunities to integrate international and multidisciplinary teams to the opportunity to leverage the best resources in an organization on a given project, virtual teams can transform the concept of project planning and execution. However, potential barriers exist in several areas to the successful implementation of virtual teams. The needs of increased management emphasis, social and cultural understanding, and emphasis on common goals are only a few of the nontechnical factors that can turn successful virtual teaming into virtual frustration. When combined with traditional technical challenges including compatibility of systems, security, and the selection of appropriate technologies, the line between leveraging virtual technologies for enhanced solutions and introducing additional complications into the project process is one that can be easily crossed. This paper presents the findings of research that addresses the opportunities and potential barriers to successful virtual teams in the engineering, procurement, and construction industry. Combining results from current research, industry practices, and early results from nonconstruction industries, the research findings provide an initial path to successful virtual team implementation.     

Two-dimensional Green's function for a wedge with impedance faces

The solution for the two-dimensional (2-D) Green's function for a wedge with impedance faces is presented. The important feature of this Green's function is that there are no restrictions on the locations for the source and observation points-they can be anywhere. Its development proceeds along two separate lines: one for when the source or observation point is far from the wedge vertex and another one for when it is close. Much of the effort that has been expended in these formulations has been in obtaining forms for the Green's function which are efficient to evaluate numerically. This involved deforming the various contours of integration so that they are rapidly convergent and separating the contributions from the numerous singularities that occur in the integrands and evaluating them in closed form. The formulations that are employed here allow for the individual field components such as the diffracted, geometrical optics, and surface wave components to be identified and studied individually so that a physical understanding for the various scattering mechanisms for the impedance wedge can be appreciated     

Current-mode analogue defuzzifier

A CMOS current-mode approach for implementing the defuzzification function in analogue fuzzy controllers is proposed. The circuit computes the centre of area of the output fuzzy conclusion using switched current adders and a current divider. Simulation results of the defuzzifier show how the circuit can produce a good approximation of the centre of area even if a small number of levels are used to quantise the output variable.<>     

Rigid polyurethane foams: A model of the foaming process

A model of the manufacture of rigid polyurethane foams by free rising is presented. The extent of cream and rise periods as well as the amount of blowing agent necessary to give the desired foam density are theoretically predicted. The rate of blowing agent evaporation is calculated from an experimental boiling temperature vs. composition curve. Experimental runs were carried out with a formulation consisting of a polymeric isocyanate, a polyether polyol based on sorbitol, a silicone-polyol block-copolymer as surfactant, dibutyltin dilaurate as catalyst, and trichlorofluoromethane as blowing agent. Mixing was performed in situ in the mold using a commercial foaming machine. Experimental results gave a satisfactory agreement with model predictions. A diagram containing all the relevant information may be theoretically built and used for the selection of adequate operating parameters for a given formulation.     

Explicit Solution for a Class of Discrete‐Time Algebraic Riccati Equations

In the present paper we obtain an explicit closed‐form solution for the discrete‐time algebraic Riccati equation (DTARE) with vanishing state weight, whenever the unstable eigenvalues are distinct. We discuss links to current algorithmic solutions and observe that the AREs in such a class solve on one hand the infimal signal‐to‐noise ratio (SNR) problem, whilst on the other hand, in their dual form they solve a Kalman filter problem. We then extend the main result to an example case of the optimal linear quadratic regulator gain. We relax some of the assumptions behind the main result and conclude with possible future directions for the present work.     

Linear quadratic gaussian optimization approach for signal-to-noise ratio constrained control over network

The research area of control over networks has attracted great interest in recent years. Inserted in this research area is the study of control feedback limitations imposed by the presence of a communication channel. In this paper we analyze the fundamental limitations in control feedback stabilizability imposed by a class of Signal-to-Noise Ratio (SNR) constrained communication channels. We solve the SNR constrained control over network problem as a linear quadratic Gaussian (LQG) optimization with loop transfer recovery (LTR). If the communication channel is located on the feedback path then the LTR is said to be performed at the output. Vice versa, if the communication channel is on the control path, then the recovery is said to be performed at the input. In the present paper we address both cases, namely the LQG optimization with LTR at the output and the LQG optimization with LTR at the input to solve an LTI SNR constrained problem. We then explore the link between these two solutions.     

Inductively coupled probe for the measurement of partial discharges

Partial discharges are a transient phenomena whose measurement is remarkably important for electrical equipment diagnosis and maintenance. These discharges appear in the measurement circuit as very narrow current pulses of some nanoseconds. Therefore, discharge pulse detection is a particularly difficult problem, especially because they are superposed on the high voltage waveforms that cause them. In this paper, we present an inductively coupled probe able to measure this physical phenomenon by means of a very simple and inexpensive device that can be installed in the equipment under test. After modeling the probe, its response will be compared to that of commercial devices using both calibrated discharges and partial discharges occurring at real power.     

Optical Properties of Self‐Assembled Cellulose Nanocrystals Films Suspended at Planar–Symmetrical Interfaces

Hierarchically structured materials comprising rod‐like, chiral, nanoparticles are commonly encountered in nature as they can form assemblies with exceptional optical and mechanical characteristics. These include cellulose nanocrystals (CNCs), which have a large potential for the fabrication of bioinspired materials mimicking those advanced properties. Fine‐tuning the optomechanical properties of assemblies obtained from CNCs hinges on the transformations from suspensions of liquid crystals to long‐range order in the dry state. So far, associated transitions have been studied using trivial interfaces such as planar substrates. Such transitions are explored as they evolve onto meshed supports. The meshed substrate offers a complex topology, as is encountered in nature, for the formation of CNCs films. The CNCs self‐assembly occurs under confinement and support of the framework bounding the mesh openings. This leads to coexisting suspended and supported nanoparticle layers exhibiting nematic and/or chiral nematic order. Optical microscopy combined with crossed polarizers indicate that the formation of the suspended films occurs via intermediate gelation or kinetic arrest of CNCs across the mesh's open areas. The formation of self‐standing, ultrathin films of CNCs with tunable optical properties, such as selective reflections in the visible range (structural color), is demonstrated by using the presented simple and scalable approach.