High Capacity,Dendrite‐Free Growth,and Minimum Volume Change Na Metal Anode

Na metal anode attracts increasing attention as a promising candidate for Na metal batteries (NMBs) due to the high specific capacity and low potential. However, similar to issues faced with the use of Li metal anode, crucial problems for metallic Na anode remain, including serious moss‐like and dendritic Na growth, unstable solid electrolyte interphase formation, and large infinite volume changes. Here, the rational design of carbon paper (CP) with N‐doped carbon nanotubes (NCNTs) as a 3D host to obtain Na@CP‐NCNTs composites electrodes for NMBs is demonstrated. In this design, 3D carbon paper plays a role as a skeleton for Na metal anode while vertical N‐doped carbon nanotubes can effectively decrease the contact angle between CP and liquid metal Na, which is termed as being “Na‐philic.” In addition, the cross‐conductive network characteristic of CP and NCNTs can decrease the effective local current density, resulting in uniform Na nucleation. Therefore, the as‐prepared Na@CP‐NCNT exhibits stable electrochemical plating/stripping performance in symmetrical cells even when using a high capacity of 3 mAh cm^?2 at high current density. Furthermore, the 3D skeleton structure is observed to be intact following electrochemical cycling with minimum volume change and is dendrite‐free in nature.     

BearCam: automated wildlife monitoring at the arctic circle

In this paper we describe the development of the BearCam, a camera system which was deployed in Fall 2005 to monitor the behaviour of grizzly bears at a remote location near the arctic circle. The system aided biologists in collecting the data for their study on bears’ behavioural responses to ecotourists. We developed a camera system for operating in the challenging arctic conditions. We describe a novel “motion shapelet” algorithm for automatically detecting bears in the video captured by this camera system. This algorithm is an extension of the shapelet features (Sabzmeydani and Mori in CVPR 2007), which are mid-level features capturing pieces of shape. Our extension of this technique incorporates motion information and proves effective at automatically detecting the occurrence of bears. We present quantitative results demonstrating that our algorithm can reliably detect bears in the vast amounts of video footage collected by our system.

Position,Jacobian and workspace analysis of a 3-PSP spatial parallel manipulator

This paper investigates the problems of kinematics, Jacobian, singularity and workspace analysis of a spatial type of 3-PSP parallel manipulator. First, structure and motion variables of the robot are addressed. Two operational modes, non-pure translational and coupled mixed-type are considered. Two inverse kinematics solutions, an analytical and a numerical, for the two operational modes are presented. The direct kinematics of the robot is also solved utilizing a new geometrical approach. It is shown, unlike most parallel robots, the direct kinematics problem of this robot has a unique solution. Next, analytical expressions for the velocity and acceleration relations are derived in invariant form. Auxiliary vectors are introduced to eliminate passive velocity and acceleration vectors. The three types of conventional singularities are analyzed. The notion of non-pure rotational and non-pure translational Jacobian matrices is introduced. The non-pure rotational and non-pure translational Jacobian matrices are combined to form the Jacobian of constraint matrix which is then used to obtain the constraint singularity. Finally, two methods, a discretization method and one based on direct kinematics are presented and robot non-pure translation and coupled mixed-type reachable workspaces are obtained. The influence of tool length on workspace is also studied.     

5-Fluorouracil-loaded poly(vinyl alcohol)/chitosan blend nanofibers: morphology,drug release and cell culture studies

Electrospun polymeric nanofibers as carriers for anticancer drugs have received a great deal of attention to treat tumor cells. This work was aimed to prepare an optimized nanofibrous sample based on poly(vinyl alcohol) (PVA)/chitosan (CS) blend, and then evaluate it containing 5-fluorouracil (5-FU) in terms of morphology, drug release, and cell culture. The electrospinning conditions to produce PVA/CS (50/50) blend nanofibers with an average diameter of approximately 150.8 nm were adjusted as follows: applied voltage 17 kV, needle tip to collector distance 60 cm, and flow rate 0.1 mL/h. The obtained results from Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) showed that there were no chemical interactions between the polymers and drug during the electrospinning process and the uniform morphology without beads. Moreover, to prolong 5-FU release from the blend nanofibers, three layered samples consisting of PVA/CS blend and poly (ε-caprolactone) (PCL) [PVA/CS-PCL 3-layers] were electrospun. On the other hand, by adding PCL in the PVA/CS blend nanofibers, the samples showed more hydrophobic property. Eventually, thiazolyl blue (MTT) assay along with NIH 3T3 cells culture proved that the sample could kill more than 80% of the cells. This formulation could be a promising candidate for cancer therapy potentially.

     

A tiny EBG‐based structure multiband MIMO antenna with high isolation for LTE/WLAN and C/X bands applications

This article proposes a compact multiple‐input multiple‐output (MIMO) antenna with the electromagnetic band gap (EBG) structures for mobile terminals. The proposed MIMO antenna is composed of two radiation patches in which diagonal and folded microstrip lines are utilized to control the frequency bands. The radiation patch, one EBG structure and a rectangular‐shaped ground plane are etched on both sides of the antenna. The EBG structures have been employed for reducing the mutual coupling between the antenna elements. As a result of the effect of these structures, the mutual coupling between the two elements is reduced by less than ?30 dB. The proposed antenna is implemented on an FR4 substrate with dimensions 20 × 10 × 1 mm³. According to measured results, frequency ranges of 2.2 to 3.6 GHz and 5.1 to 5.9 GHz with S₁₁ < ?10 dB and also 3.7 to 5 GHz and 8 to 12 GHz with S₂₂ < ?10 dB have been obtained. Moreover, measured S₁₂ and S₂₁ with values of less than ?30 dB for both Ports have been realized. Additionally, the envelope correlation and radiation efficiency of the purposed antenna are less than 0.09 and more than 82%, respectively.     

Effect of trapezoidal collars as a scour countermeasure around wing-wall abutments

Local scour around bridge abutments is a widespread problem that can result in structural failure. Collars can be used as a countermeasure to reduce the scour depth. In this study, the temporal scour development around a wing-wall abutment was investigated with and without collars. The tests were carried out under clear-water conditions for different abutment lengths, with collars of different sizes placed at the bed level. When no collar was used in the experiments, 70% of the maximum scour depth occurred in less than 2 h. However, when a collar with a width greater than the length of the abutment was used, no scour was observed for up to 200 min from the beginning of the experiments. The results show that an increase in the collar width not only led to a lag time for the onset of scouring but also reduced the maximum scour depth. Moreover, an increased collar width led to a better performance in mitigating scouring around smaller abutments. Generally, the scour depth decreased by 9%–37% with different collar widths.     

Optimized formulation of an oxidative curing system for liquid polysulfide sealants used in fuel tanks by D‐optimal design method

In this work, the effective parameters in liquid polysulfide curing system were optimized by D ‐optimal design method. Five main components in the formulation, carbon black, vulcanizing agents (MnO₂, Na₂Cr₂O₇, and PbO₂), CaCO₃, fumed silica, and chlorinated paraffin, were selected. Mechanical and chemical properties of the samples were investigated. The results showed that tensile strength, hardness, viscosity, and optimum cure time (t₉₀) presented a suitable coordination with reduced quadratic model. For elongation at break and swelling tests, reduced two‐factor interaction (2FI), and for peel strength, a linear model showed the best correlation. To achieve the desirable properties for liquid polysulfide sealants used in fuel tanks, an optimized amount of the above components in the formulation were used. Finally, MnO₂ curing system, compared with Na₂Cr₂O₇ and PbO₂, was selected as the best choice. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Crosstalk of Diabetic Conditions with Static Versus Dynamic Flow Environment—Impact on Aortic Valve Remodeling

Type 2 diabetes mellitus (T2D) is one of the prominent risk factors for the development and progression of calcific aortic valve disease. Nevertheless, little is known about molecular mechanisms of how T2D affects aortic valve (AV) remodeling. In this study, the influence of hyperinsulinemia and hyperglycemia on degenerative processes in valvular tissue is analyzed in intact AV exposed to an either static or dynamic 3D environment, respectively. The complex native dynamic environment of AV is simulated using a software-governed bioreactor system with controlled pulsatile flow. Dynamic cultivation resulted in significantly stronger fibrosis in AV tissue compared to static cultivation, while hyperinsulinemia and hyperglycemia had no impact on fibrosis. The expression of key differentiation markers and proteoglycans were altered by diabetic conditions in an environment-dependent manner. Furthermore, hyperinsulinemia and hyperglycemia affect insulin-signaling pathways. Western blot analysis showed increased phosphorylation level of protein kinase B (AKT) after acute insulin stimulation, which was lost in AV under hyperinsulinemia, indicating acquired insulin resistance of the AV tissue in response to elevated insulin levels. These data underline a complex interplay of diabetic conditions on one hand and biomechanical 3D environment on the other hand that possesses an impact on AV tissue remodeling.     

Exploring the link between early constructor involvement in project decision-making and the efficacy of health and safety risk control

The position of the constructor in communication networks, including those before the commencement of construction, is likely related to the quality of work health and safety (WHS) outcomes realized. In order to examine the extent of this relationship, 23 cases were drawn from 10 participating construction projects in Australia and New Zealand. Social network analysis was used to mathematically and graphically model information exchanges in 13 of these cases. For each case, the quality of WHS risk control outcomes was measured. This measurement was based on an established ‘hierarchy of control’ in which risk controls are classified in descending order of effectiveness from the elimination of a hazard (the most effective) to the reliance on personal protective equipment (the least effective). Social network metrics were calculated reflecting: (1) the ratio of actual links among parties in the project network relative to the maximum number of links possible (network density); and (2) the extent to which the constructor communicated with other parties in pre-project planning and design stages (the constructors’ degree centrality). Network metrics were compared for cases in which the risk control scores were higher and lower than average. The results showed a significant difference in constructors’ pre-construction degree centrality for cases with high and low risk control scores. The results provide preliminary evidence as to the potential WHS benefits of ensuring that constructors’ knowledge about construction methods, materials, WHS risks and means of risk control, are integrated into pre-construction decision-making.