Effect of environmental hydrogen pressure on the hydrogen yield from x-irradiated polyethylenes

An experimental assembly incorporating a capacitance-type, differential pressure transducer, which provides resolutions of 3 × 10^?4 torr at pressures extending to 30 torr, has been employed to monitor the effect of hydrogen environmental pressure on the hydrogen yield from x-irradiated polyethylenes. Contrary to the observations of previous investigators, the hydrogen yield is found to be independent of hydrogen environmental pressures extending over the critical range up to at least 30 torr. It is demonstrated that neglecting the temperature and density gradients inherent in closed-volume irradiation assemblies employing cryogenic traps to separate liberated gases into condensable and noncondensable fractions may lead to erroneous conclusions with respect to gas yields arising from the irradiation of materials. A homogeneous, variable-plate separation ion chamber consisting of a polyethylene body and utilizing flowing ethylene as the cavity gas was employed to obtain total volatile G values of 3.6 ± 0.4, 3.8 ± 0.4, and 4.0 ± 0.4 molecules/100 e.v., for Marlex 6002, Dow Ziegler (Q 917.5), and DuPont A-1410 polyethylenes, respectively. A hydrogen contribution of approximately 98 mole-% was obtained with this experimental method.     

A multi-criteria assessment tool for screening preliminary product platform concepts

Platform concept evaluation is a more challenging task than evaluating a single product concept since a platform must effectively support multiple product variants over a prolonged period of time. Existing platform methods develop specific criteria in depth, yet an evaluation of alternative platforms should be based on a broad set of criteria. Based on expert interviews, personal experience, and a literature search we propose a platform assessment tool consisting of 19 criteria for platform evaluation. The criteria are group into six categories: customer satisfaction, variety, after-sale, organization, flexibility, and complexity. The tool is focused on the early platform architecture phase, before proof-of-concept prototyping. However, it can also be used subsequently for platform refinement when more data becomes available. We demonstrate our platform assessment tool through an example with a cordless drill platform.     

Implementing packaged enterprise software in multi-site firms: intensification of organizing and learning

Packaged enterprise software, in contrast with custom-built software, is a ready-made mass product aimed at generic customer groups in a variety of industries and geographical areas. The implementation of packaged software usually leads to a phase of appropriation and customization. As the associated processes remain ill understood, particularly for multi-site implementations, the objective of this paper is to understand the impact of packaged software in a multi-site organization. Adopting a case study method, this paper reports on a multi-site project that was analyzed at the group, site, and corporate level. Our findings suggest that as organizational units face the unsettling experience of having to implement a single source code across globally distributed sites, packaged software intensifies organizing and learning processes across these levels. The paper identifies specific processes for these levels and concludes with implications for research and practice. Our research extends IS research on packaged software implementation with an emphasis on multi-site firms.     

Excessive cross-linking of caseins by microbial transglutaminase and its impact on physical properties of acidified milk gels

By varying cross-linking intensity, the effect of microbial transglutaminase on acid gels made from casein solution and raw milk was studied. To avoid any impact of heating, N-ethylmaleimide was used for enzyme inactivation after appropriately checking its efficiency. Up to a specific degree of oligomerisation gel stiffness and firmness increased and tan δ, time at gelation onset and syneresis decreased. Above approximately 70% and 25% of cross-linked protein in casein solution and raw milk, respectively, these parameters showed an opposite behaviour, and weak gels with high syneresis were obtained. Substrate differences, such as preferred cross-linking of adjoining κ-caseins on the surface of the micelle enhanced the effect of steric hindrance in raw milk and impaired proper rearrangements upon acidification at a much lower level of oligomerised protein. It is mainly dimeric and trimeric casein that successfully contributed to the enhanced properties of milk protein gels.     

Lagrangian Coherent Structures with Guaranteed Material Separation

Given an unsteady flow field, one common way to compute Lagrangian Coherent Structures (LCS) is to extract extremal structures of the Finite Time Lyapunov Exponent (FTLE). Experience has shown that the resulting structures are often close to material structures (i.e., material lines or material surfaces). Moreover, it has been proven that for an integration time converging to infinity, they converge to exact material structures. However, due to the finite integration time in FTLE, they are generally not exact material structures. In this paper we introduce a modification of the FTLE method which is guaranteed to produce separating material structures as features of a scalar field. We achieve this by incorporating the complete available integration time both in forward and backward direction, and by choosing an appropriate definition for separating structures. We apply our method to two test data sets and show the differences to classical FTLE.     

Zur Bestimmung der Nitrate im Wasser

Ohne ZusammenfassungIn den Mittelpunkt dieser Betrachtungen soll das Indigoverfahren gestellt werden.bedeutet mit Abbildungen.