Surface Oxidation as a Cause of High Open‐Circuit Voltage in CdSe ETA Solar Cells

TiO₂/CdSe/CuSCN extremely thin absorber (ETA) solar cells are found to give relatively high values of open‐circuit voltage (>0.8 V) but low currents upon annealing the cadmium selenide (CdSe) in air (500 ºC). Annealing in N₂ produces much lower photovoltages and slightly lower photocurrents. Band structure measurements show differences between the two annealing regimes that, however, appear to favor the N₂‐annealed CdSe. On the other hand, chemically resolved electrical measurements (CREM) of the cells reveal marked differences in photo‐induced charge trapping, in particular at absorber grain boundaries of the air versus N₂‐annealed systems, correlated with the formation of Cd–O species at the CdSe surface. Using transient absorption and photovoltage decay, pronounced lifetime differences are also observed, in agreement with the strong suppression of charge recombination. The results point to a multiple role of grain surface‐oxidation, which both impedes electron injection from the CdSe to the TiO_2, but, much more significantly, enhances hole injection to the CuSCN via passivation of hole traps that act as efficient recombination centers.     

Prospects for application of post-consumer used plastics in food packaging

The two most widely used polymers in packaging in recent years are polyethylene terephthalate (PET) and polyethylene (PE). The biggest fractions of these polymers are not re-utilized, in spite of the fact that they possess excellent properties even after their first application. The ban on using recycled polymers in food packaging applications and the lack of good value outlets for these materials causes them to end up in landfills. The high cost nylon, used in packaging primarily as high gas barrier laminates with PE, also finds its way to landfills. In this case, the reason is the difficulty of recycling different polymers that are incompatible. Thus, the Municipal Solid Waste (MSW) stream transferred to landfills contains many plastic packages. These packages are being blamed as a major pollutant of the environment in spite of the fact that all plastics contribute only a small percentage to the weight of the garbage in landfills. If proper and cost effective applications for the recycled polymers could be developed, the waste related to their disposal could be limited. In addition, the contribution of plastic packages to the environmental problem could be diminished. In the present paper, the possibility of sandwiching a contaminated PET layer between two layers of the virgin material was studied. The aim of the study was to determine whether such an operation could lower the migration level of contaminants from a multilayer structure (containing a recycled layer of PET) to values below the limits required by regulatory agencies. The diffusion coefficients (required to determine migration) of four organic liquids in PET were determined. As a result of the sandwiching operation, the amount of pollutant (toluene) migrating into the food simulant was reduced by two orders of magnitude. The properties of PE/nylon blends were also studied. It was found that the high gas barrier properties of nylon are preserved in the blend when proper processing conditions are used. Therefore, the recycled material could be used as a centre layer in a multilayer structure providing good gas barrier properties to this structure.     

Neuropilin-1 is a placenta growth factor-2 receptor

Placenta growth factor (PlGF) belongs to the family of vascular endothelial growth factors (VEGFs). It binds to the flt-1 VEGF receptor but not to the KDR/flk-1 receptor which is thought to mediate most of the angiogenic and proliferative effects of VEGF. Three PlGF isoforms are produced by alternative splicing. PlGF-1 and PlGF-3 differ from PlGF-2 since they lack the exon 6 encoded peptide which bestows upon PlGF-2 its heparin binding properties. Cross-linking experiments revealed that 125I-PlGF-2 binds to two endothelial cell surface receptors in a heparin dependent fashion. The binding of 125I-PlGF-2 to these receptors was inhibited by an excess of PlGF-2 and by the 165-amino acid form of VEGF (VEGF165), but not at all by VEGF121 and very marginally if at all by PlGF-1. The apparent molecular weight and the binding characteristics of these receptors correspond to those of the recently identified VEGF165 specific receptor neuropilin-1, and we therefore conclude that neuropilin-1 is a receptor for PlGF-2. The binding of 125I-PlGF-2 as well as the binding of 125I-VEGF165 to these receptors was inhibited by a synthetic peptide derived from exon 6 of PlGF. Furthermore, the binding of 125I-PlGF-2, but not that of 125I-VEGF165, was also inhibited by a synthetic peptide derived from exon 7 of PlGF. These observations indicate that the peptides encoded by these exons probably participate in the formation of the domain which mediates the binding of PlGF-2 to these receptors. We have also determined, using chemically modified heparin species, that the presence of sulfate moieties on the glucosamine-O-6 and on the iduronic acid-O-2 groups of heparin was required for the potentiation of 125I-PlGF-2 binding to these receptors. To determine if PlGF-2 is able to induce biological responses that are not induced by PlGF-1, we compared the effects of PlGF-1 and PlGF-2 on the migration and proliferation of endothelial cells. Both PlGF forms induced migration of endothelial cells. However, there was no quantitative difference between the response to PlGF-2 and the response to PlGF-1. Furthermore, neither PlGF-1 nor PlGF-2 had any effect upon the proliferation of the endothelial cells.     

人性化的用户界面

在过去，移动电话只是带内置地址簿的固定电话的无线替代品。向拥有更多连接性、更多数据和更多性能、更精巧设备的加速推进，使广大用户产生了更多、更强烈的市场需求。移动电话的生态系统正努力寻求适当的途径实现数据和服务，并充分友好地为用户所使用。只有语音功能的移动电话市场将会越来越小。     

Effects of computerized mediation of analogical thinking in kindergartens

Abstract  The current study describes an attempt to improve children's analogical thinking through the use of a 'humanized' computer program. This program was experimentally designed to incorporate several basic features of what has been defined theoretically and empirically as basic criteria of human mediation to children. The objective of the study was to examine the possibility of improving the educational benefits of using computers in early childhood education. More specifically, it was hypothesized that by introducing into a computer program basic features of human mediation, it would be possible to raise children's educational gains to the level of the gain achieved when they work with an adult mediator. Subjects were 120 Israeli-born kindergarten children between 4.5 and 6 years old. Despite no differences in test scores between the two experimental groups a higher frequency of 'stopping to think' (in contrast to trial and error responses) was found in the experimental group working with an adult as compared to the experimental group working independently.     

Structure-property relationships in blends of linear low- and conventional low-density polyethylene as blown films

Three-layer coextruded blown (either blend or composite) films, made of low-density polyethylene and linear lowdensity polyethylene (1:1 ratio) of identical density, were compared. The tensile properties of both systems are nearly as high as those of the linear polyethylene while high strain rate properties including impact strength and tear resistance of the composite film are superior. Some structural insight was obtained by thermal analysis and thermoelastic measurements. Structure property relationships are discussed in light of the unique behavior, structure, and morphology of linear low-density polyethylene. The two polyethylenes are only compatible to a rather limited extent mainly affecting their blend behavior. However, a strong mutual reinforcement effect was observed.     

Simultaneous intraparticle forced convection,diffusion and reaction in a porous catalyst—II: Selectivity of sequential reactions

The selectivity of a sequence of isothermal irreversible heterogeneous reactions

within a catalytic pellet is investigated under conditions where intraparticle forced convection is a non-negligible transport mechanism. The nature of the effect of the internal filter flow depends mostly on the value of the Thiele modulus, φ₂, of the desired (middle) species. The asymptotic values of the selectivity, as φ₂ → 0 and φ₂ → ∞, are unaltered, independent of the strength of the internal flow. The intermediate region is divided into two parts. In the subregion with lower values of φ₂ the selectivity is enhanced. In the other subregion, with higher values of φ₂, the selectivity is significantly retarded to values which can be markedly below the lower asymptote. These trends are common to both poor and good selective catalysts.     

Annular flow of two immiscible liquids I. Mechanisms

A study was made of the flow mechanisms of two immiscible liquids with a small density difference introduced at a horizontal-pipe inlet in initial concentric flow. Extent of the annular flow, its break-up mechanisms and the subsequent flow patterns encountered were investigated with the aid of high-speed photography. Annular-flow break-up was found to occur by one of two mechanisms: collapse of the core-liquid by varicose Rayleigh-type waves or rupture of the top-wall liquid-film, attenuated by the ascent of the lighter core-liquid. Flow patterns observed after break-up involve fine dispersions, slugs or stratified layers. Charts mapping flow-pattern zones show conditions under which annular-flow holds over a considerable extent.     

On Interpretation of ESCA Spectra with Application to Thymine and Other Molecules

1s binding energies are calculated for nitrogen atoms in thymine, pyrrole, adenine, and pyridine and for carbon atoms in thymine, adenine, pyrrole, and furan, and compared with experimental values. Calculations are performed in the framework of a perturbational model using CNDO molecular wave functions. Interactions of the 1s electron with its own atom are calculated exactly whereas interactions with neighbor atoms are calculated according to two levels of approximation: (1) Point charge approximation. (2) Rigorous calculations of integrals. Magnitudes of the different interactions and integrals are analysed. The questions of assignments of ESCA shifts and the errors inherent in the calculations are discussed.