Effect of amphiphilic compatibilizers on the filler dispersion and properties of polyethylene—thermally reduced graphene nanocomposites

Compatibilizers of different chemical structures and specifications were used to enhance the filler exfoliation in nanocomposites of polyethylene and thermally reduced graphene prepared by melt mixing route. The mechanical performance of the compatibilized nanocomposites was observed to be better than PE/G nanocomposites due to enhanced extent of filler exfoliation and distribution. Highest increase of 45% in tensile modulus and 13% in peak stress was observed in the composites. Overall, from the mechanical, rheological, thermal, and calorimetric properties, the compatibilizers with best performance were ethylene acrylic acid (EAA) copolymer and chlorinated polyethylene (CPE25). Furthermore, the extent of filler exfoliation was observed to increase with increasing EAA content thus confirming positive interactions between EAA and thermally reduced graphene, though no specific chemical interactions could be detected. The composite properties were observed to reach maximum around 7.5 wt % EAA content, followed by reduced performance due to extensive matrix plasticization. The observed behaviors were a result of interplay of opposing factors like filler exfoliation due to compatibilizer addition and matrix plasticization due to its lower molecular weight, thus the observed optimum comaptibilizer amount was specific to the compatibilizer. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42484.     

Some Thermodynamic Aspects of the Oxides of Chromium

To understand Cr emissions from slag melts to a vapor phase, an assessment of the stabilities of the chromium oxides at high temperatures has been carried out. The objective of the present study is to present a set of consistent data corresponding to the thermodynamic properties of the oxides of chromium, with special reference to the emission of hexavalent chromium from slags. In the current work, critical analysis of the experimental data available and a third analysis in the case of Cr₂O₃ have been carried out. Commercial databases, Fact Sage and ThermoCalc along with NIST-JANAF Thermochemical Tables, have been used for the analysis and comparisons of the results that are presented. The significant discrepancies in the available data have been pointed out. The data from NIST-JANAF Thermochemical Tables have been found to provide a set of consistent data for the various chromium oxides. An Ellingham diagram and the equations for the ΔG° (standard Gibbs free energy change) of formation of CrO _x have been proposed. The present analysis shows that CrO₃(g) is likely to be emitted from slag melts at high oxygen partial pressures.     

Measurement of Bulk Mechanical Properties and Modeling the Load-Response of Rootzone Sands. Part 1: Round and Angular Monosize and Binary Mixtures

The bulk mechanical properties of two different types of rootzone sands (round and angular) were measured using a cubical triaxial tester. Two monosize sands (d 50 = 0.375 mm and 0.675 mm) and their 50:50 binary mixtures (d 50 = 0.500 mm) were studied. The compression, shear, and failure responses of the above-mentioned six compositions were analyzed, compared, and modeled. Two elastic parameters (bulk and shear moduli) and two elastoplastic parameters (swelling and consolidation indices) of the six sand compositions were also calculated and compared. The angular sand was more compressible than round sand during isotropic compression. In addition, the angular sands tended to have lower initial bulk density and high porosity values. Among the three different size fractions, the 0.375 mm mixture was least compressible for both sand shapes. The failure strength and shear modulus of the angular sand were higher than the round sands. In addition, due to their simplicity, phenomenological models were developed to predict the compression and shear behavior of the sands. The prediction models were validated using subangular and subround sands. Average relative difference values were calculated to determine the effectiveness of the prediction models. The mean average relative difference values for compression profiles, i.e., volumetric stress vs. volumetric strain, were from 16 % to 39 %, except for the initial load-response portion (< 1 % volumetric strain). The predictive models were effective in reproducing the failure responses: at 17.2 kPa confining pressure, the mean of average relative difference was 23 %; at 34.5 kPa , the mean difference was 24 %.     

Noncovalent assembly of carbon nanofiber–layered double hydroxide as a reinforcing hybrid filler in thermoplastic polyurethane–nitrile butadiene rubber blends

A new synthetic route was applied to develop carbon nanofiber (CNF)–layered double hydroxide (LDH) hybrid through a noncovalent assembly using sodium dodecyl sulfate as bridging linker between magnesium–aluminum LDH and CNF and then characterized. Furthermore, this hybrid was used as nanofiller in thermoplastic polyurethane–acrylonitrile butadiene rubber (TN; 1:1 w/w) blend. Mechanical measurements showed that the 0.50 wt % hybrid loaded TN blend exhibited the maximum improvements in the elongation at break, tensile strength, and storage modulus of 1.51 times and 167 and 261% (25 °C), respectively. Differential scanning calorimetric analysis and thermogravimetric analysis showed maximum improvements in the melting temperature (5 °C), crystallization temperature (17 °C), and thermal stability (14 °C) in the 0.50 wt % surfactant modified carbon nanofiber–LDH loaded blend compared to the neat blend. Such enhancement in the properties of the TN nanocomposites could be attributed to the homogeneous dispersion, strong filler–blend interfacial interaction, and synergistic effect. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43470.     

Stopping power of Mylar for heavy ions up to copper

The stopping powers of Mylar for several heavy ions covering Z=11 to 29 in the energy range 0.3 to 2.3 MeV/n have been measured using the elastic recoil detection technique and twin detector system. The technique provided a unique method to generate a variety of variable energy ion species utilizing a fixed energy 140 MeV Ag¹³⁺ primary beam from the Pelletron accelerator facility at Nuclear Science Center, New Delhi, India. Most of these measurements are new. The experimentally measured stopping power values have been compared with those calculated using LSS theory, Ziegler et al. formulation and Northcliffe and Schilling tabulations. Merits and demerits of these formulations are highlighted. Stopping power calculations using the Hubert et al. formulation have been extended successfully beyond its recommended range of validity, i.e. 2.5–500 MeV/n down to energies as low as 0.5 MeV/n.     

A Novel FrWT Based Arrhythmia Detection in ECG Signal Using YWARA and PCA

Wireless Personal Communications - In general, Electrocardiogram (ECG) signal gets corrupted by variety of noise at the time of its acquisition. Unfortunately, these noise tend to mask the crucial...     

Residual U-Network for Breast Tumor Segmentation from Magnetic Resonance Images

Breast cancer positions as the most well-known threat and the main source of malignant growth-related morbidity and mortality throughout the world. It is apical of all new cancer incidences analyzed among females. Two features substantially influence the classification accuracy of malignancy and benignity in automated cancer diagnostics. These are the precision of tumor segmentation and appropriateness of extracted attributes required for the diagnosis. In this research, the authors have proposed a ResU-Net (Residual U-Network) model for breast tumor segmentation. The proposed methodology renders augmented, and precise identification of tumor regions and produces accurate breast tumor segmentation in contrast-enhanced MR images. Furthermore, the proposed framework also encompasses the residual network technique, which subsequently enhances the performance and displays the improved training process. Over and above, the performance of ResU-Net has experimentally been analyzed with conventional U-Net, FCN8, FCN32. Algorithm performance is evaluated in the form of dice coefficient and MIoU (Mean Intersection of Union), accuracy, loss, sensitivity, specificity, F1score. Experimental results show that ResU-Net achieved validation accuracy & dice coefficient value of 73.22% & 85.32% respectively on the Rider Breast MRI dataset and outperformed as compared to the other algorithms used in experimentation.     

The strength of the fibre-polymer interface in short glass fibre-reinforced polypropylene

A method for the determination of the interfacial bond strength in well-aligned short glass fibre-reinforced polypropylene samples is discussed. The method takes into account the variation of the interfacial shear stress during the deformation process; consequently, it yields very consistent results at all values of the composite strain. The influence of the fibre orientation with respect to the load axis is appropriately considered using macro-mechanical analyses for stiffness and strength of the composite. The method is compared with two other methods reported in the literature.     

Effect of gamma irradiation on the optical properties of CR-39 polymer

The UV-Visible absorption spectra of virgin and gamma irradiated (20–800 kGy) CR-39 polymer have been deduced by using Shimadzu Double beam Double Monochromator UV-Visible Spectrophotometer (UV-2550). The existence of the peaks, their shifting and broadening as a result of gamma irradiation has been discussed. Finally the indirect and direct band gap in virgin and gamma irradiated CR-39 has been determined. The values of indirect band gap have been found to be lower than the corresponding values of direct band gap.