全文获取类型
收费全文 | 14599篇 |
免费 | 1107篇 |
国内免费 | 398篇 |
学科分类
工业技术 | 16104篇 |
出版年
2024年 | 66篇 |
2023年 | 233篇 |
2022年 | 460篇 |
2021年 | 690篇 |
2020年 | 485篇 |
2019年 | 441篇 |
2018年 | 494篇 |
2017年 | 469篇 |
2016年 | 490篇 |
2015年 | 549篇 |
2014年 | 694篇 |
2013年 | 849篇 |
2012年 | 897篇 |
2011年 | 1041篇 |
2010年 | 756篇 |
2009年 | 705篇 |
2008年 | 716篇 |
2007年 | 617篇 |
2006年 | 538篇 |
2005年 | 425篇 |
2004年 | 380篇 |
2003年 | 305篇 |
2002年 | 347篇 |
2001年 | 273篇 |
2000年 | 215篇 |
1999年 | 241篇 |
1998年 | 577篇 |
1997年 | 371篇 |
1996年 | 290篇 |
1995年 | 170篇 |
1994年 | 167篇 |
1993年 | 147篇 |
1992年 | 90篇 |
1991年 | 92篇 |
1990年 | 76篇 |
1989年 | 86篇 |
1988年 | 49篇 |
1987年 | 45篇 |
1986年 | 45篇 |
1985年 | 50篇 |
1984年 | 41篇 |
1983年 | 39篇 |
1982年 | 43篇 |
1981年 | 32篇 |
1980年 | 33篇 |
1979年 | 25篇 |
1977年 | 46篇 |
1976年 | 69篇 |
1975年 | 18篇 |
1973年 | 18篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
Molecular dynamics (MD) simulations of-Al2O3, using a pairwise additive interaction potential of Pauling's type with four different radii for aluminum atoms, were analysed in order to determine the influence of the radius on the modification of coordination numbers of A1 relative to the ideal structure, at two different temperatures of 300 and 1500 K. It is found that the best choice is the radius of penta-coordinated aluminum, reproducing structural and vibrational properties of the compound in excellent agreement with experimentally observed properties. 相似文献
92.
Random Forests receive much attention from researchers because of their excellent performance. As Breiman suggested, the performance of Random Forests depends on the strength of the weak learners in the forests and the diversity among them. However, in the literature, many researchers only considered pre-processing of the data or post-processing of the Random Forests models. In this paper, we propose a new method to increase the diversity of each tree in the forests and thereby improve the overall accuracy. During the training process of each individual tree in the forest, different rotation spaces are concatenated into a higher space at the root node. Then the best split is exhaustively searched within this higher space. The location where the best split lies decides which rotation method to be used for all subsequent nodes. The performance of the proposed method here is evaluated on 42 benchmark data sets from various research fields and compared with the standard Random Forests. The results show that the proposed method improves the performance of the Random Forests in most cases. 相似文献
93.
SRAM-based pipelined architectures for high-speed IP lookup using Field Programmable Gate Arrays (FPGAs) has recently attracted a great deal of attention from researchers. Due to the limited amount of on-chip memory and the number of I/O pins of FPGAs, compact data structures providing high memory efficiency are in great demand. 相似文献
94.
Pornchai Rachtanapun Susan E. M. Selke Laurent M. Matuana 《Polymer Engineering and Science》2004,44(8):1551-1560
Polymer blends, such as those resulting from recycling postconsumer plastics, often have poor mechanical properties. Microcellular foams have been shown to have the potential to improve properties, and permit higher‐value uses of mixed polymer streams. In this study, the effects of microcellular batch processing conditions (foaming time and temperature) and HDPE/PP blend compositions on the cell morphology (the average cell size and cell‐population density) and impact strength were studied. Optical microscopy was used to investigate the miscibility and crystalline morphology of the HDPE/PP blends. Pure HDPE and PP did not foam well at any processing conditions. Blending facilitated the formation of microcellular structures in polyolefins because of the poorly bonded interfaces of immiscible HDPE/PP blends, which favored cell nucleation. The experimental results indicated that well‐developed microcellular structures are produced in HDPE/PP blends at ratios of 50:50 and 30:70. The cell morphology had a strong relationship with the impact strength of foamed samples. Improvement in impact strength was associated with well‐developed microcellular morphology. Polym. Eng. Sci. 44:1551–1560, 2004. © 2004 Society of Plastics Engineers. 相似文献
95.
96.
A. Storck M. A. Latifi G. Barthole A. Laurent J. C. Charpentier 《Journal of Applied Electrochemistry》1986,16(6):947-963
Hydrodynamic and mass transfer parameters (pressure drop, gas and liquid hold-up, liquid-solid mass transfer coefficients) have been measured for porous electrodes with upward or downward co-current gas-liquid flow by means of several electrochemical techniques. The influence of the most important parameters (packing diameter, gas and liquid flow rates) and of the hydrodynamic flow regimes, has been studied. It is found that in the trickle flow regime the limiting current densities depend only on the liquid flow rates (with no measurable influence of the gas). In the upward flow configuration, the strong turbulence generated by the ascending gas bubbles leads to a sharp increase of current densities with the gas flow rate. A comparison between both configurations is presented. 相似文献
97.
Novel silica nanoboxes were prepared by controlled dealumination of Na-X and Ca-A type zeolites using ammonium hexafluorosilicate (AHFS). The silica-richer
the parent zeolite, the smaller the average pore size produced and the narrower the pore size distribution obtained. This
was due to the specific reactivity of the extracting agent with the zeolite framework aluminum atoms. High temperature calcination
of the dealuminated X-zeolite (ammonium form) resulted in mesoporous materials exhibiting an ink-bottle shape, a quite high
surface area (330 m2/g, no micropores), an average pore diameter of 4.5 nm with a quite narrow pore size distribution (± 1.0 nm) and finally,
a pore opening diameter of 3.9 nm. The latter was determined by using the nitrogen sorption isotherms (BET technique) and
related pore volume data. The sorption behavior also suggested the interconnecting character of the newly created nanoboxes. The periodicity of these nanoboxes throughout the mesoporous material was clearly shown by X-ray powder diffraction at very small angles.
These materials, herein called monomodal nanoboxes because of the absence of micropores in the structure, were also thermally stable. Incorporation of orthosilicate into the obtained silica nanoboxes, in accordance with the recently developed technique for
pore size engineering in zeolites, led to materials with smaller pore openings but having almost the same textural properties. Solid superacidic materials were prepared by incorporating a liquid superacid
(triflic acid or trifluoromethanesulfonic acid) into the silica nanoboxes using the wet impregnation technique. The maximum
triflic acid loading which did not significantly affect the mesoporous framework of the materials was 24 wt%. As a reference,
the maximum loading of less acidic sulfuric acid was slightly lower. All this showed the high chemical stability of the silica nanoboxes for supporting very acidic species. Temperature-programmed desorption using a combined DTA/TGA system
allowed the identification of the bound phases and some liquid phase of the loaded triflic acid. 相似文献
98.
Richard V. Flor Le Tiet Hecking Brian David Martin 《Journal of the American Oil Chemists' Society》1993,70(2):199-203
Criteria for authentic olive oils were developed from isocratic high-performance liquid chromatography analyses of 99 olive
oils from the major Mediterranean producers in the 1983–1986 crop years. Authentic olive oils include extra virgin, virgin
and pure or refined oils, but exclude all reesterified and adulterated oils. The extra virgin through pure grades will have
a combined area for the LOO (C18:2C18:1C18:1), LOP (C18:2C18:1C16:0), OOO (C18:1C18:1C18:1), POO (C16:0C18:1C18:1), POP (C16:0C18:1C18:1), and SOO (C18:0C18:1C18:1) peaks between 82.0 and 92.6% of the total area (L, linoleic; O, oleic; P, palmitic; S, stearic). Authentic oils will have
ratios of LOO/LOP and OOO/POO that coincide with a line defined by OOO/POO=0.7844(LOO/LOP)+0.0968; correlation coefficient
is 0.885. Authentic oils will not have a trilinolein (LLL) peak over 0.5% in area. Neither triolein (OOO) nor any other single
peak suffices to characterize an olive oil sample as one of the authentic grades. 相似文献
99.
100.
It is shown that even pure quartz, other silicas or aluminas can enhance the aromatization activity of a ZSM-5 zeolite. Incorporation of gallium oxide onto these supports increases further the production of aromatics. The use of supported gallium oxide co-catalyst obtained by co-evaporation of a colloidal silica and a Ga salt has led to extremely high aromatization performance for the hybrid catalyst. 相似文献