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31.
Technical Physics Letters - A new method for epitaxial growth of cadmium sulfide (CdS) films in the metastable cubic phase by atomic-layer deposition on silicon substrates with a buffer layer of...  相似文献   
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Nanostructured Cu(x)Zn(1-x)Al(2)O(4) with a Cu:Zn ratio of ?:? has been prepared by a microwave-assisted hydrothermal synthesis at 150 °C and used as a precursor for Cu/ZnO/Al(2)O(3)-based catalysts. The spinel nanoparticles exhibit an average size of approximately 5 nm and a high specific surface area (above 250 m(2) g(-1)). Cu nanoparticles of an average size of 3.3 nm can be formed by reduction of the spinel precursor in hydrogen and the accessible metallic Cu(0) surface area of the reduced catalyst was 8 m(2) g(-1). The catalytic performance of the material in CO(2) hydrogenation and methanol steam reforming was compared with conventionally prepared Cu/ZnO/Al(2)O(3) reference catalysts. The observed lower performance of the spinel-based samples is attributed to a lack of synergetic interaction of the Cu nanoparticles with ZnO due to the incorporation of Zn(2+) in the stable spinel lattice. Despite its lower performance, however, the nanostructured nature of the spinel catalyst was stable after thermal treatment up to 500 °C in contrast to other Cu-based catalysts. Furthermore, a large fraction of the re-oxidized copper migrates back into the spinel upon calcination of the reduced catalyst, thereby enabling a regeneration of sintered catalysts after prolonged usage at high temperatures. Similarly prepared samples with Ga instead of Al exhibit a more crystalline catalyst with a spinel particle size around 20 nm. The slightly decreased Cu(0) surface area of 3.2 m(2) g(-1) due to less copper incorporation is not a significant drawback for the methanol steam reforming.  相似文献   
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It was found that the room-temperature photoluminescence (PL) spectra of Cr4+:Ca2GeO4 single crystal films grown by magnetron sputtering on Ca2GeO4 bulk single crystal substrates exhibit a sharp emission band in the region of ~1.17 μm with satellites at ~1.21 and 1.27 μm. Particularities of the PL spectra are interpreted within the framework of a model based on the interaction between electrons of the Cr4+ center and the oscillations excited in the film.  相似文献   
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New types of prospective magnetic random access memory devices are reviewed. Operation principles, design, characteristics, and the state-of-the-art of magnetoresistive, microelectronic electrical, and quantum-optical devices are described.  相似文献   
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Translated from Atomnaya Énergiya, Vol. 66, No. 1, pp. 42–44, January, 1989.  相似文献   
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Investigations were carried out into the failure resistance in the temperature range +20 to –60°C in static bending of 13KhGMRB, 14KhG2SAFD, and 14KhGN2MDAFB steels with 0.2=600–700 MPa and also the weld metal and the heat affected zone (HAZ) of their welded joints. Evaluation of the cracking resistance of these steels and welded joints was carried out using fracture mechanics criteria: critical crack opening displacement c and stress intensity factor Kc. The values of the effective factor of stress concentration, generated by the crack {ie746-01}, and critical stress cr are also determined. The results show that of the three steels tested, the lowest failure resistance was exhibited by 14KhGN2MDAFB steel. The heat affected zones of the welded joints in the 13KhGMRB and 14KhGM2MDAFB steels have higher cracking resistance than the HAZ of the welded joints in 14KhG2SADF steel. The weld metal of welded joints produced in CO2 with PP-AN54 wire and in a Ar+CO2 mixture with Sv-08KhN2GNYu wire is characterized by higher failure resistance than the weld metal of welded joints produced in CO2 with Sv-10KhG2SMA wire. The welded joints in 13KhGMRB steel produced in CO2 with PP-AN54 wire, and in 14KhGN2MDAFB steel produced in the Ar+CO2 mixture, have high failure resistance at temperatures to –60 and –50°C, respectively. The welded joints in 14KhG2SAFD steel, produced in CO2 with Sv-10KhGSMA wire, can be used in service at temperatures not lower than –40°C.Translated from Problemy Prochnosti, No. 7, pp. 30–34, July, 1991.  相似文献   
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Russian Microelectronics - The influence of a magnetic field directed orthogonal to the easy magnetization axis (EMA) of an elliptical spin-tunnel junction based on the...  相似文献   
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