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31.
32.
The adsorption of TiO nanoclusters onto a TiS2 single layer surface is investigated via the density functional theory in combination with random structure searching algorithms. The nanoclusters are Ti—O dipoles and their orientation in the electrostatic field is induced by S atoms near the TiS2 single layer surface. The binding energy of nanoclusters with a TiS2 single layer surface is found to be 4.713 eV. Another curious observation is the creation of a nanocluster with an S–S–S–O anionic tetrahedron by Ti atoms, where the O anion is located at the maximum distance from the surface. 相似文献
33.
Morozova L. V. Kovalko N. Yu. Kalinina M.V. Shilova O. A. 《Theoretical Foundations of Chemical Engineering》2019,53(5):848-854
Theoretical Foundations of Chemical Engineering - The synthesis technology of a chemically pure nanodisperse precursor powder (10–12 nm) based on a tetragonal solid zirconia (t-ZrO2) solution... 相似文献
34.
A. I. Aleksandrov V. G. Shevchenko I. A. Aleksandrov N. A. Tebeneva I. B. Meshkov A. A. Kalinina E. N. Degtyarev A. A. Dubinskii A. L. Kovarsky S. B. Zezin V. G. Krasovskii S. S. Abramchuk M. I. Buzin A. M. Muzafarov 《应用聚合物科学杂志》2019,136(26):47681
Multiferroic (MF) composites based on nanoparticles consisting of a silica core and a shell of spin-variable Fe(III) complexes in a polymer matrix (polystyrene) were synthesized and characterized by different methods. The nanoparticles had the formula 80SiO2·20{Fe[OSi(Me)(OEt)2]3}, and their particle size was on the order of 5–7 nm. Dielectric and electron spin resonance studies showed the presence of two types of Fe ions in the nanocomposite. Iron ions in the low-spin state [Fe(III)-LS] and iron ions in the high-spin state [Fe(III)-HS], which were bound by indirect exchange interactions through oxygen and silicon atoms {[Fe(III)-LS]─O─Si─O─[Fe(III)-HS]} were responsible for the MF properties of the composites with core–shell nanoparticles. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47681. 相似文献
35.
T. O. Shekunova A. E. Baranchikov A. D. Yapryntsev P. G. Rudakovskaya O. S. Ivanova Yu. A. Karavanova M. A. Kalinina M. N. Rumyantseva S. G. Dorofeev V. K. Ivanov 《Journal of Materials Science》2018,53(3):1758-1768
A new facile method is proposed for the preparation of aqueous sols of highly crystalline tungsten trioxide with a particle size of 60–150 nm, containing no organic stabilizers/surfactants. These sols possess high sedimentation stability, which is quite unusual for inorganic colloidal systems containing relatively large particles, with a rather high density (ρ c(WO3) = 7.3 g/cm3). The method is based on the thermal decomposition of ammonium paratungstate, followed by dispersing the resulting powders in water under ultrasonic treatment. Thermal decomposition of ammonium paratungstate, and the composition and structure of the resulting tungsten trioxide and its aqueous dispersions, were investigated with thermal analysis combined with the mass spectrometry of gaseous thermolysis products, powder X-ray diffraction, scanning electron microscopy, low-temperature nitrogen adsorption, IR spectroscopy and dynamic light scattering. It has been demonstrated that the high sedimentation stability of WO3 results from electrostatic stabilization, which might be caused by the formation of tungstic acid on the surface of WO3 particles when they come into contact with water. The nanocrystalline WO3 obtained can be used to produce gas sensors for ammonia. 相似文献
36.
L. V. Morozova M. V. Kalinina M. Yu. Arsent’ev O. A. Shilova 《Inorganic Materials》2017,53(6):640-647
We have studied the influence of cryochemical and ultrasonic processing on the formation, structure, particle size, and thermal decomposition of xerogels in the ZrO2〈Y2O3〉–Al2O3 (20 wt %) system. Nanopowders of tetragonal-zirconia-based solid solutions with a high degree of tetragonality (c/a = 1.4366) have been synthesized. Al2O3 has been shown to slow down t-ZrO2 crystallite growth in the temperature range 600–1400°C. We have optimized nanopowder consolidation conditions, obtained nanoceramics stable to low-temperature “aging” in a humid medium, and investigated their physicochemical and mechanical properties. 相似文献
37.
T.?L.?Simonenko M.?V.?Kalinina N.?P.?Simonenko E.?P.?Simonenko T.?V.?Khamova O.?A.?ShilovaEmail author 《Glass Physics and Chemistry》2018,44(4):314-321
Nanopowders with a composition of (СeO2)1–x(Gd2O3)x (x = 0.03, 0.05, 0.07, and 0.10) are synthesized by the coprecipitation method using cryotechnologies. The coherent scattering region (CSR) of the powders is 10–14 nm and the specific surface area is 70–81 m2/g. Based on the powders, ceramic nanosized materials with CRS of 64–71 nm are obtained. The dependence of the phase composition, microstructure, and electrical transport properties of the obtained samples on the Gd2O3 content is established. In a CeO2–Gd2O3 system, a solid solution with the composition of (CeO2)0.90(Gd2O3)0.10 has the highest ionic conductivity with the transfer number of ions of ti = 0.74 at a temperature of 700°C. It is shown that ceramics of this composition can be used as a solid electrolyte of intermediate-temperature fuel cells due to their physicochemical characteristics. 相似文献
38.
L. V. Morozova M. V. Kalinina P. A. Tikhonov I. A. Drozdova O. A. Shilova 《Glass Physics and Chemistry》2017,43(3):276-281
The possibility of fabricating electroconducting (101–104 S cm–1) ceramics based on In2O3, CdO, and LaCrO3 by liquid-phase synthesis methods has been demonstrated. The results of studies of the effect of temperature, dopants, and partial oxygen pressure on the specific electroconductivity of ceramic composites are presented. 相似文献
39.
Powder precursors have been prepared by means of the sol-gel technique and codeposition, and nanoceramics in the ZrO2-Al2O3-rare-earth (RE) oxide system (RE = Ce, Sc, or Y) based on them have been obtained. Physicochemical properties of the resulting ceramic composites have been investigated. The energy model for oxygen-ionic transport processes in a solid solution based on ZrO2, which relies on computer simulation procedure, has been proposed, and the structural, strength, and electrophysical characteristics of the solid solution have been calculated. The obtained materials are promising as high-melting electrochemical sensors in molten oxides. 相似文献
40.
Kalinina E. V. Kudoyarov M. F. Nikitina I. P. Dementyeva E. V. Zabrodskii V. V. 《Semiconductors》2022,56(3):184-188
Semiconductors - The results of the effect of irradiation with Ar ions on the structural, electrophysical, and optical characteristics of ultraviolet Cr/4H-SiC photodetectors in the spectral range... 相似文献