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21.
The effects of functionalized multi‐walled carbon nanotubes (MWCNTs) on thermal and chemorheological behaviors of an epoxy‐based nanocomposite system were investigated. Chemical functionalization of MWCNTs by acid modification (A‐MWCNTs) and chemical amidation (D‐MWCNTs) was confirmed using Fourier transform infrared spectroscopy and thermogravimetric analysis. It was found that the D‐MWCNTs had a significant effect on the chemorheological behaviors of the epoxy‐based nanocomposite. Compared to the epoxy/A‐MWCNT nanocomposite, the epoxy/D‐MWCNTs nanocomposite showed a significant increase in gel time, as obtained from isothermal rheology measurements. Also, the storage modulus of the diglycidylether of bisphenol F (DGEBF)/D‐MWCNTs nanocomposite was higher than that of the DGEBF/D‐MWCNTs nanocomposite and gradually increased with an increase of frequency. This could be interpreted by the relatively strongly interconnected structure of the D‐MWCNTs in the DGEBF epoxy resin, which arises from the functionalized alkyl groups of the D‐MWCNTs in dispersion phases with the DGEBF epoxy resin. Copyright © 2012 Society of Chemical Industry 相似文献
22.
ABSTRACT: A vacuum-sealed miniature X-ray tube based on a carbon nanotube field-emission electron source has been demonstrated. The diameter of the X-ray tube is 10 mm; the total length of the tube is 50 mm, and no external vacuum pump is required for the operation. The maximum tube voltage reaches up to 70 kV, and the X-ray tube generates intense X-rays with the air kerma strength of 108 Gy * cm2 min1. In addition, X-rays produced from the miniature X-ray tube have a comparatively uniform spatial dose distribution. 相似文献
23.
This paper investigates the spalling properties of high-strength concrete in order to improve the residual compressive strength and spalling resistance in specimens subjected to 3 h of unloading fire conditions. This study consists of three series of experiments with eighteen different specimens varying in fiber type and content, finishing material and simultaneous fiber content and lateral confinement. They were fabricated to a 300 × 300 × 600 mm mock-up size. Results of the fire test showed that the control concrete was explosive, while the specimens that contained more than 0.1 vol% of polypropylene (PP) and polyvinylalcohol (PVA) fibers were prevented from spalling. One specimen, finished by a fire endurance spray, exhibited even more severe spalling than the control concrete. The specimen containing 0.1 vol% of PP fiber and using a confining metal fabric at the same time, showed the most effective spalling resistance; in particular, the residual compressive strength ratio was even higher than that of the control concrete before the fire test. It was demonstrated that adding fibers in concrete prevented the spalling occurrence and confining metal fabric around the main bars of concrete specimens can secure the strength of structures during the conditions of elevated temperature. 相似文献
24.
Kyeong‐Yong Park Jinyong Lee Seong Jun Park Jung‐Nyoung Heo Hwan Jung Lim 《Advanced Synthesis \u0026amp; Catalysis》2015,357(18):3917-3926
A series of 1,2‐ and 1,4‐dihydroquinolines has been successfully prepared. The Pd‐catalyzed intramolecular N‐arylation of Z‐enamines, formally prepared by the Horner–Wadsworth–Emmons olefination, proceeded efficiently to furnish the cyclized products. Depending on the cyclization conditions, substituted 1,4‐dihydroquinolines and further isomerized 1,2‐dihydroquinolines were independently obtained in high yields with an excellent control of isomerization of the double bond.
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26.
2D Materials: Rotation‐Misfit‐Free Heteroepitaxial Stacking and Stitching Growth of Hexagonal Transition‐Metal Dichalcogenide Monolayers by Nucleation Kinetics Controls (Adv. Mater. 25/2015) 下载免费PDF全文
27.
Modulation of the band gap energy and diameter of quantum dots (QDs) formed in glasses is important to achieve the optimized performance for applications as infrared light sources, lasers, saturable absorbers, etc. Absorption and photoluminescence of PbS QDs were extended into mid-infrared wavelength range in glasses containing small amount of lead but oversaturated with sulfur. Dual-band photoluminescence of PbSe QDs was prepared in oxyfluoride glass-ceramics containing BaF2 nanocrystals. By introducing SnO in the glasses, alloyed Pb1-xSnxSe QDs with smaller band gap energies were formed in glasses, and mid-infrared photoluminescence of Pb1-xSnxSe QDs at ~2570 nm in wavelength was achieved. 相似文献
28.
Sung Jae Won Rendi Kurniawan Dae Kyung Kang Joong Sik Heo 《Journal of Mechanical Science and Technology》2018,32(9):4173-4181
The surge in demand for natural resources has shifted the focus of the international community toward the development of oil sands, shale oil, shale gas and other non-traditional energy sources. In extreme environments, materials used in petroleum gas plant modules are accompanied by various problems caused by low-temperature brittleness such as damage, corrosion and wear. Many researchers have been conducting studies to discover a suitable material whose lifespan could be improved by performing characteristics analyses and performance assessments. In this study, a material characteristics assessment was conducted based on a wear resistance test on materials that are commonly used at oil sands plants. Prior to a wear resistance test, a chemical composition analysis was performed on each of the specimens, and tensile, impact, hardness and corrosion tests were carried out to examine the correlation between their results with the results of the wear resistance test. Each test was performed according to ASTM G 105 standards, and the change in weight according to wear length was analysed for each material to determine the related tendencies. In addition, the results of the wear test were derived by analysing the change in the mass of the specimen before and after the test, and the surface roughness was assessed to analyse the performance related to wear and define the service life. The aim was to use these results to select a material that would be suitable for the abrasive environment of the key equipment and materials of plants. 相似文献
29.
Quantitative analysis of microbial community structure in two-phase anaerobic digesters treating food wastewater 总被引:1,自引:0,他引:1
Woong Kim Byung-Gon Ryu Sungwhan Kim Sung-Woon Heo Donghyun Kim Jungmin Kim Haechan Jo Jong-Hee Kwon Ji-Won Yang 《Korean Journal of Chemical Engineering》2014,31(3):381-385
An acidogenic reactor with a 0.5-L working volume and a methanogenic digester with a 5-L of working volume were operated for 150 days on a continuous mode to investigate the structure of a microbial community during food wastewater treatment. During the steady state of anaerobic digestion, volatile solids (VS) removal efficiency in the pilot plant was approximately 65%. The bacterial population was higher than any other methanogens detected during the entire anaerobic process and treatment of raw food wastewater. Methanomicrobiales (MMB), Methanosarcinales (MSL), and Methanobacteriales (MBT) were detected during digestion. The methanogenic population present in the acidogenic reactor was directly affected by the archaeal community in raw food wastewater. However, the shift of microbial community in the methanogenic digester was relatively gradual. The performance of methanogenic digester might be more related to the change of microbial metabolism affected by the physicochemical properties of the input substrate. 相似文献
30.