电化学分析法在铬形态分析中应用进展

对近年来电化学分析法应用于铬的形态分析的现状和发展趋势进行了概述。     

Suzuki Reaction of Aryl Bromides Using a Phosphine-Free Magnetic Nanoparticle-Supported Palladium Catalyst

A palladium catalyst immobilized on superparaganetic nanoparticles was prepared with a palladium loading of 0.30 mmol/g. The catalyst was characterized using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, vibrating sample magnetometry, thermogravimetric analysis, Fourier transform infrared, atomic absorption spectrophotometry, and nitrogen adsorption. The immobilized palladium catalyst was an efficient catalyst without added phosphine ligands for the Suzuki cross-coupling reaction of several aryl bromides with phenylboronic acid. The recovery of catalyst was simply by magnetic decantation in the presence of a magnet. The immobilized palladium catalyst can be reused many times without significant degradation in catalytic activity. No leaching of active palladium species into the reaction solution was detected.     

Butylene copolyesters based on aldaric and terephthalic acids. Synthesis and characterization

The synthesis, characterization, and some properties of new copolyesters analogous to poly(butylene terephthalate) (PBT), based on L ‐arabinaric and galactaric acids, are described. These copolyesters were obtained by polycondensation reaction in the melt of mixtures of methyl 2,3,4‐tri‐O‐methyl‐L ‐arabinarate or methyl 2,3,4,5‐tetra‐O‐methyl‐galactarate and dimethyl terephthalate with 1,4‐butanediol. Their weight‐average molecular weights ranged between 10,000 and 34,000, with polydispersities ranging from 1.4 to 2.2. The composition of all the copolymers was analyzed by NMR, and was found to have a statistical microstructure. All these copolyesters were thermally stable, with degradation temperatures well above 300 °C. The melting temperature and crystallinity decreased in both series, and the glass transition temperature increased and decreased respectively, for the PBTGa and PBTAr series with increasing amounts of aldaric units in the copolyester chain. Only PBT‐derived copolyesters containing a maximum of 30% aldaric units showed discrete scattering characteristic of crystalline material. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1168–1177, 2009     

1,10-邻菲咯啉-铜(Ⅱ)-L-丝氨酸/L-酪氨酸配合物的合成、SOD活性及电化学性质

合成了两个新的配合物:[Cu(Phen)(L-Ser)(H2O)]Cl(1)和[Cu(Phen)(L-Tyr)(H2O)]Cl.2H2O(2)(Phen=1,10-邻菲咯啉、L-Ser=L-丝氨酸、-LTyr=L-酪氨酸).用元素分析、摩尔电导率、红外光谱、紫外-可见光谱对配合物进行了表征.分别采用NBT光还原法和循环伏安法测定了配合物的SOD活性及电化学性质.结果表明,这些配合物具有较高的SOD活性,配合物1、2催化O2-.歧化分解速率常数KQ值分别为3.16×107和1.54×107mol-1.L.s-1.     

水基切伦科夫μ子探测器的研究

利用高速带电粒子在透明介质中产生切伦科夫辐射的特性,以蒸馏水作为辐射介质,搭建了一个小尺寸(π×22.52cm2×45 cm)的切伦科夫探测器,对能量在GeV量级的μ子进行了相应的测量,考虑其他能量损耗、光传输和收集效率、阴极量子效率后,实验结果与理论估计值有比较高的相符度,可以初步断定仪器具备探测GeV量级μ子的能力.     

A NOTE ON SINGULAR INTEGRALS WITH DOMINATING MIXED SMOOTHNESS IN TRIEBEL-LIZORKIN SPACES

Let h be a measurable function defined on R+×R+. LetΩ∈ L(log L+)νq(Sn1-1×Sn2-1)(1 ≤νq≤ 2) be homogeneous of degree zero and satisfy certain cancellation conditions. We show that the singular integral T f(x1, x2) = p. v.∫ Rn1+n2Ω(y′1, y′2)h(|y1|, |y2|)|y1|n1|y2|n2f(x1- y1, x2- y2)dy1dy2maps from Sα1, α2p, q˙F(Rn1× Rn2) boundedly to itself for 1 p, q ∞, α1, α2 ∈ R.     

[Bmim]Br3对酮的选择性单溴化反应

在无溶剂和室温条件下, 三溴化1-丁基-3-甲基咪唑([Bmim]Br₃)选择性地与酮反应, 以90%～96%的产率生成相应的α-溴代酮. 该方法反应条件温和、产率高、选择性好、环境友好.     

Optical Abelian lattice gauge theories

We discuss a general framework for the realization of a family of Abelian lattice gauge theories, i.e., link models or gauge magnets, in optical lattices. We analyze the properties of these models that make them suitable for quantum simulations. Within this class, we study in detail the phases of a U(1)$U\left(1\right)$-invariant lattice gauge theory in 2+1$2+1$ dimensions, originally proposed by P. Orland. By using exact diagonalization, we extract the low-energy states for small lattices, up to 4×4$4\times 4$. We confirm that the model has two phases, with the confined entangled one characterized by strings wrapping around the whole lattice. We explain how to study larger lattices by using either tensor network techniques or digital quantum simulations with Rydberg atoms loaded in optical lattices, where we discuss in detail a protocol for the preparation of the ground-state. We propose two key experimental tests that can be used as smoking gun of the proper implementation of a gauge theory in optical lattices. These tests consist in verifying the absence of spontaneous (gauge) symmetry breaking of the ground-state and the presence of charge confinement. We also comment on the relation between standard compact U(1)$U\left(1\right)$ lattice gauge theory and the model considered in this paper.