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11.
Masao Tamada Masaharu Asano Reimar Spohr Johann Vetter Christine Trautmann Masaru Yoshida Ryouichi Katakai Hideki Omichi 《Macromolecular rapid communications》1995,16(1):47-51
The porous copolymer films of N-methacryloyl-L -alanine methyl ester and diethyleneglycol-bis-allylcarbonate (diallyl oxydiethylene dicarbonate) were hydrolyzed with 1 M NaOH solution for 40 min at 25°C. The pores of the films showed pH response in diameter. The pore diameter of 3,7 μm in the buffer solution of pH 3 was closed completely at pH 5. 相似文献
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Reimar Leschber und Hilde Schlichting 《Fresenius' Journal of Analytical Chemistry》1969,245(5):300-303
Zusammenfassung In Reihenuntersuchungen über das Verhalten einfach und komplex gebundenen Cyanids gegenüber dem Angriff von verdünnter Schwefelsäure im Rahmen einer sog. Gesamtcyanidbestimmung in Abwässern wurde festgestellt, daß im Konzentrationsbereich 100 mg CN-/l die Cyanid-Komplexverbindungen des Zinks, Cadmiums, Kupfers, Nickels sowie des zwei- und dreiwertigen Eisens relativ schnell durch die verdünnte Schwefelsäure aufgespalten werden, so daß man die Gesamtmenge des vorhandenen Cyanids in den ersten 25 ml Destillat analytisch bestimmen kann.
Herrn Prof. Dr. Fritz Meinck, dem ehemaligen Abteilungsleiter, zu seinem 70 jährigen Geburtstag gewidmet. 相似文献
On the decomposability of complex metal cyanides in the determination of cyanide in waste water
Serial studies on the behaviour of simple and complex cyanides against the attack of dilute sulphuric acid within the determination of total cyanide in waste water resulted in the cyanide complexes of zinc, cadmium, copper, nickel, iron(II) and iron(III) being decomposed quite rapidly by dilute sulphuric acid in the concentration range of 100 mg CN-/l. Consequently, in such cases the total amount of cyanide can be determined in the first 25 ml of the distillate.
Herrn Prof. Dr. Fritz Meinck, dem ehemaligen Abteilungsleiter, zu seinem 70 jährigen Geburtstag gewidmet. 相似文献
13.
Frank Marlow Freddy Kleitz Ursula Wilczok Wolfgang Schmidt Ines Leike 《Chemphyschem》2005,6(7):1269-1275
Powder samples can show pronounced texture effects in X-ray scattering. Here, texture effects are described theoretically for circularly ordered fibers and shown experimentally for a special type of these fibers based on nanostructured silica. The systematic diffraction peak intensity dependences, observed with the tilting of the samples, fit well with the theoretical model proposed and can be used as an efficient detection method for circulite-type mesopore organization. Our investigations clearly emphasize the difficulties encountered in the interpretation of peak intensities in the X-ray scattering analyses because of pronounced texture effects. 相似文献
14.
Expectations for constraints on extra Z bosons are derived for LEP2 and future linear e+e? colliders. For typical GUTs, a Z′ with MZ′ ≤ 3 to $6sqrt {s}$ may cause observable effects. The Z′ discovery limits are dominated by statistical errors. However, if a Z′ signal is observed, the discrimination between different models becomes much worse if systematic errors are taken into account. Discrimination between models is possible for $M_{Z^{?ime}} < 3sqrt {s}$. A determination of Z′ff couplings independently of models becomes attractive with future colliders. Anticipated bounds are determined. 相似文献
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The complete standard model corrections together with the QED contributions from an additionalZ boson to the forward backward asymmetry of the reactione + e ?→(ψ,Z, Z′, ...)→f + f + are calculated. They include soft photon exponentiation and a cut on the photon energy. Some numerical applications are considered forE 6 generated extraZ bosons. Though being small at TRISTAN and LEP1 energies, the QED corrections due toZ′ exchange are very important near and above theZ′ peak. 相似文献
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A series of benzo[b]furan‐2(3H)‐ones (coumaran‐2‐ones) bearing a urea substructure, namely derivatives of 3‐(aminocarbonylamino)benzo[b]furan‐2(3H)‐one, was prepared for the first time. The accessibility of these compounds through an electrophilic α‐amidoalkylation approach of phenols (Tscherniac–Einhorn reaction) in the key step as well as the chemiluminescence (CL) properties of the desired compounds are strongly dependent on the substitution patterns at the urea moiety. Competing reaction pathways are discussed and an improved one pot synthetical approach of also general interest is presented. In conclusion, especially N,N‐dialkylaminocarbonylamino‐derivatives of benzo[b]furan‐2(3H)‐ones exhibit a strong flash like blue CL upon treatment with bases such as 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) in the presence of oxygen or hydrogen peroxide. Comparative physico‐chemical investigations revealed that novel compounds outperform their urethane‐analogues in terms of CL‐intensity and the speed of the decay making them potentially useful as new tools for CL‐based applications on the short time scale. 相似文献
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J.?FleischerEmail author A.?Leike T.?Riemann A.?Werthenbach 《The European Physical Journal C - Particles and Fields》2003,31(1):37-56
We present the complete electroweak one-loop corrections to top-pair production at a linear e
+
e
- collider in the continuum region. Besides weak and photonic virtual corrections, real hard bremsstrahlung with simple realistic kinematical cuts is included. For the bremsstrahlung we advocate a semi-analytical approach with a high numerical accuracy. The virtual corrections are parameterized through six independent form factors, suitable for Monte Carlo implementation. Alternatively, our numerical package Topfit, a stand-alone code, can be utilized for the calculation of both differential and integrated cross sections as well as forward-backward asymmetries.Received: 3 March 2003, Published online: 26 September 2003Work supported in part by the European Communitys Human Potential Programme under contract HPRN-CT-2000-00149 Physics at Colliders and by Sonderforschungsbereich/Transregio 9 of DFG Computergestützte Theoretische Teilchenphysik. This research has also been supported by a Marie Curie Fellowship of the European Community Programme Improving Human Research Potential and the Socio-economic Knowledge Base under the contract number HPMF-CT-2002-01694 相似文献
20.
We establish a rigorous time-dependent density functional theory of classical fluids for a wide class of microscopic dynamics. We obtain a stationary action principle for the density. We further introduce an exact practical scheme, to obtain hydrodynamical effects in density evolution, that is analogous to the Kohn-Sham theory of quantum systems. Finally, we show how the current theory recovers existing phenomenological theories in an adiabatic limit. 相似文献