全文获取类型
收费全文 | 1229篇 |
免费 | 57篇 |
国内免费 | 15篇 |
学科分类
数理化 | 1301篇 |
出版年
2023年 | 8篇 |
2022年 | 20篇 |
2021年 | 67篇 |
2020年 | 43篇 |
2019年 | 60篇 |
2018年 | 62篇 |
2017年 | 39篇 |
2016年 | 58篇 |
2015年 | 51篇 |
2014年 | 78篇 |
2013年 | 132篇 |
2012年 | 95篇 |
2011年 | 89篇 |
2010年 | 65篇 |
2009年 | 51篇 |
2008年 | 52篇 |
2007年 | 56篇 |
2006年 | 48篇 |
2005年 | 45篇 |
2004年 | 21篇 |
2003年 | 20篇 |
2002年 | 13篇 |
2001年 | 8篇 |
2000年 | 15篇 |
1999年 | 7篇 |
1998年 | 3篇 |
1997年 | 6篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 6篇 |
1986年 | 2篇 |
1985年 | 7篇 |
1984年 | 6篇 |
1983年 | 9篇 |
1982年 | 3篇 |
1981年 | 6篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1968年 | 2篇 |
1965年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有1301条查询结果,搜索用时 31 毫秒
81.
Lakovaara Matias Sirviö Juho Antti Ismail Mostafa Y. Liimatainen Henrikki Sliz Rafal 《Cellulose (London, England)》2021,28(9):5433-5447
Cellulose - In this work, deep eutectic solvent (DES) based on imidazole and triethylmethylammonium chloride was used as a reaction medium for the esterification of cellulose nanofiber (CNF) and... 相似文献
82.
Taguchi method was applied to optimize cloud point extraction (CPE) conditions for preconcentration and determination of trace amounts of copper by UV-Vis spectrophotometry. Briefly, the copper ions formed complexes with neocuproine in aqueous solution; then, Triton X-114 (0.15%, w/v) was added and phase separation occurred upon heating to 60°C. The copper complexes were preconcentrated into the small volume of the surfactant-rich phase; after centrifugation, the surfactant-rich phase was diluted with methanol and absorbance was measured at 455 nm. The main factors affecting the CPE were evaluated and optimized with Taguchi orthogonal array design (OA 25). Under the optimum conditions, the calibration curve was linear in the range 2–500 μg/L (r 2 > 0.997). The limit of detection and preconcentration factor were 1.8 μg/L and 37.2, respectively. The applicability of the proposed method was successfully confirmed by preconcentration and determination of trace amounts of copper in water samples and satisfactory results were obtained. 相似文献
83.
Mohammad Taghi Taghizadeh Nazanin Yeganeh Mostafa Rezaei 《Journal of Thermal Analysis and Calorimetry》2014,118(3):1733-1746
A peak deconvolution procedure used for the analysis of data corresponding to simultaneous overlapping processes begins with separation of individual processes using functions such as Gaussian, Lorentzian, Weibull, and Fraser–Suzuki (FS) followed by application of kinetic analysis methods to the separated peaks. We propose a coupled peak deconvolution procedure to link the parameters of the FS functions of similar peaks in two DTG curves obtained at different linear heating rates, so that the coordinates of each peak can be obtained in a constrained manner. The proposed technique is a kinetic deconvolution method rather than a pure mathematical deconvolution technique. To analyze individual peaks in our study, the non-parametric kinetic and Freidman’s isoconversional methods have been applied to determine kinetic triplet of each process. This technique has been tested with both simulated and experimental data. Using this technique, the effects of molecular weight and degree of hydrolysis of polyvinyl alcohol (PVA) samples on reaction mechanism and activation energy of thermal degradation were studied. The presence of acetate group in the PVA samples causes thermal stability, decreases the rate of main reactions, and increases the activation energy. The results of this study may help tailor heat-resistant materials with proper choice of polymer characteristics. 相似文献
84.
Ali Akbarzadeh Seyed Omid Ranaei Siadat Mostafa Motallebi Mohammad Reza Zamani Mohammad Barshan Tashnizi Sakineh Moshtaghi 《Applied biochemistry and biotechnology》2014,172(4):2253-2265
Bioconversion of cellulosic material into glucose needs cellulase enzymes. One of the most important organisms that produces cellulases is Trichoderma reesei, whose cellulose enzymes are probably the most widely used in the industry. However, these enzymes are not stable enough at high pH and temperatures. The optimized synthetic endoglucanase II gene with Pichia pastoris codon preferences was secretary expressed in P. pastoris. Recombinant enzyme characterization showed maximum activity at pH 4.8 and temperature 75 °C, and it demonstrated increasing thermal stability in high temperature. The enzyme maintained its activity in a wide pH range from 3.5 to 6.5. The optimization of fermentation medium was carried out in shaking flasks. Recombinant protein expression at optimum conditions (pH 7, temperature 25 °C, and 1 % methanol induction) for 72 h demonstrated 2,358.8 U/ml endoglucanase activity units. To our knowledge, this is the highest acidic thermophilic endoglucanase activity that is reported in crude intracellular medium in P. pastoris. We conclude that P. pastoris is an appropriate host for high-level expression of optimized endoglucanase gene with improved thermal stability. 相似文献
85.
86.
87.
88.
The spiro-compound 3′H-spiro[indole-3,2′-[1,3]benzothiazole-2(1H)-one (IBTH2) was synthesized and its structure was determined using spectroscopic techniques (FTIR, 1H NMR and mass) and X-ray crystallography. This ligand possesses different centers for coordination. Reactions of [M(CO)6], M = Cr, Mo or W with IBTH2 in THF under reduced pressure were studied. For chromium a complex with molecular formula [Cr(ITP)2] was isolated; where ITP is the opened form of the ligand which occurred through Cspiro–S bond, while [Mo(CO)5(IBTH2)] and [W(CO)5(IBTH2)] were isolated from the reaction of IBTH2 with molybdenum and tungsten carbonyls, respectively. All complexes were characterized by elemental analysis, IR, mass and 1H NMR spectroscopy. The biological activity of the ligand and its complexes were studied and compared with the parent compound isatin. 相似文献
89.
Mohsen M. Mostafa Rafaat M. El-Shazly Tawfik H. Rakha Mohamed H. Abdel-Rahman 《Transition Metal Chemistry》2002,27(2):237-237
Other Index
Forthcoming articles 相似文献90.