首页 | 官方网站   微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4723篇
  免费   604篇
  国内免费   480篇
数理化   5807篇
  2024年   17篇
  2023年   74篇
  2022年   126篇
  2021年   169篇
  2020年   152篇
  2019年   171篇
  2018年   152篇
  2017年   132篇
  2016年   217篇
  2015年   190篇
  2014年   237篇
  2013年   337篇
  2012年   340篇
  2011年   366篇
  2010年   256篇
  2009年   252篇
  2008年   284篇
  2007年   260篇
  2006年   262篇
  2005年   187篇
  2004年   175篇
  2003年   155篇
  2002年   177篇
  2001年   133篇
  2000年   109篇
  1999年   113篇
  1998年   101篇
  1997年   86篇
  1996年   57篇
  1995年   75篇
  1994年   62篇
  1993年   51篇
  1992年   51篇
  1991年   31篇
  1990年   36篇
  1989年   15篇
  1988年   19篇
  1987年   13篇
  1986年   26篇
  1985年   24篇
  1984年   17篇
  1983年   15篇
  1982年   12篇
  1981年   12篇
  1980年   6篇
  1979年   10篇
  1977年   4篇
  1974年   7篇
  1973年   7篇
  1969年   4篇
排序方式: 共有5807条查询结果,搜索用时 15 毫秒
11.
In this article a new technique was developed to fabricate scaffolds with a unique microstructure by solid–liquid separation in combination with particulate-leaching. Firstly, the effects of polymer concentration, quenching temperature on the porous morphology and the mechanical property of obtained scaffolds during solid–liquid separation have been investigated. Then, salt granules as porogen were introduced into the solid–liquid phase separation to produce the unique pore structure of the scaffold. The pore diameter of the scaffold could be controlled with the particulate size and the wall of pores possessed special microstructure, which enhanced the pore interconnectivity. The cell culture results confirmed that a good interconnectivity of the scaffold prepared by the improved solid–liquid separation was useful for nutrition transportation and cell proliferation. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
12.
A high average power, high-repetition-rate TEA CO2 laser employing printed-circuit-board preionizer is described. The power scaling of this preionization configuration has been demonstrated. The average output power reaches 3.6 kW at pulse repetition rate of 180 pps. Furthermore, the scaling-up ability of the rotating spark gap as high-voltage switch for high-average-power gas laser has been validated.  相似文献   
13.
Apparatus integrating a Fourier transform-infrared (FT-IR) spectrometer and a mid-infrared difference frequency generation (DFG) laser spectrometer was built for the study of the matrix isolation spectrum in solid molecular hydrogen. A 3-cm-long molecular hydrogen crystal was grown in a liquid-helium Dewar, and its infrared absorption spectrum in the 1-5 μm region was recorded to test the system. The W0(0) (ν=0←0, J=6←0) line around 2410 cm−1 of solid hydrogen was investigated with the DFG laser spectroscopy. High-resolution matrix isolation spectrum of CO2 co-deposited with hydrogen on a BaF2 cold plate at liquid-helium temperature was studied.  相似文献   
14.
本文简要介绍线性代数学习网站的系统研究与开发设计.涉及到网络数据库、ASP、界面设计等多种技术.该线性代数网上学习系统为老师和学生提供了交流平台,其界面美观、操作简便.具有良好的应用前景.  相似文献   
15.
Traditionally spatial transformations such as translations and rotations are formulated in terms of transformations of the entire spatial space. In other words, transformations are taken automatically to be of a global nature. This paper investigates a local approach to spatial transformations; local transformations lead naturally to local observables in quantum mechanics.  相似文献   
16.
本文考虑积分方程的ε复杂性问题.问题的ε复杂性是在误差不超过ε的前提下解决问题所需的最小成本.对某些具各向异性核与自由项的第二类Fredholm方程,求得了ε复杂性的精确阶.同时,找到了解决该问题具最小成本的算法.  相似文献   
17.
Structure of thiocyanate adlayers on Rh(111): an in situ STM study   总被引:1,自引:0,他引:1  
In situ scanning tunneling microscopy (STM) was used to examine the structure of thiocyanate adlayers specifically adsorbed on Rh(111) in solutions of potassium hydroxide and perchloric acid, both containing potassium thiocyanate (KSCN). An atomically flat terrace-step structure was consistently observed on Rh(111) surfaces prepared by the flame-annealing-quenching method. The Rh(111)-(1 × 1) atomic structure was discerned on the atomically flat terrace even in the alkaline solution. High-resolution STM images disclosed two different structures of the SCN adlayers, () and (2 × 2), in the alkaline and the acidic media, respectively. In each structure, an individual adsorbed SCN ion appeared as a single spot with a constant corrugation height in STM images, suggesting that SCN ions adsorbed predominantly with their S-ends at particular bonding sites on Rh(111). The difference in the adlayer structure in the two solutions can be attributed to the interaction between adsorbed SCN and coadsorbed K+ in the alkaline solution, and is different from that between adsorbed SCN and H+ in the acidic solution. Received: 26 February 1997 / Accepted: 3 March 1997  相似文献   
18.
A method is proposed to calculate molar conductivity based on mode coupling theory in which the ion transference number is introduced into the theory. The molar conductivities of LiPF6, LiClO4, LiBF4, LiAsF6 in PC (propylene carbonate) are calculated based on this method. The results fit well to the literature data. This presents a potential way to calculate the conductivities of Li-ion battery electrolytes.  相似文献   
19.
20.
The assembly of small water clusters (H2O)n, n = 1-6, on a graphite surface is studied using a density functional tight-binding method complemented with an empirical van der Waals force correction, with confirmation using second-order M?ller-Plesset perturbation theory. It is shown that the optimized geometry of the water hexamer may change its original structure to an isoenergy one when interacting with a graphite surface in some specific orientation, while the smaller water cluster will maintain its cyclic or linear configurations (for the water dimer). The binding energy of water clusters interacting with graphite is dependent on the number of water molecules that form hydrogen bonds, but is independent of the water cluster size. These physically adsorbed water clusters show little change in their IR peak position and leave an almost perfect graphite surface.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司    京ICP备09084417号-23

京公网安备 11010802026262号