钯在乙醇水溶液中与钌、银、铜和铅的析相绿色萃取分离

在硫酸铵存在下,乙醇水溶液能够分为醇/水两相,在分相过程中,Pd²⁺与KBr和C₂H₅OH₂⁺生成的[PdBr₄^2-][C2HsOH-2⁺]₂三元缔合物能被乙醇相萃取,使Pd²⁺与Ru²⁺、Ag⁺、Cu²⁺和Pb²⁺完全分离。该法在微量钯的分离和富集分析中有一定的实用价值。     

十六烷基氯化吡啶-水-KI体系浮选分离锑

研究了十六烷基氯化吡啶-水-KI体系分离Sb3+的行为及与一些金属离子分离的条件。结果表明,在一定条件下,Sb3+可与Co2+、Al3+、Zn2+、Ni2+、Fe2+和Mn2+定量分离。     

Sodium atom in strong magnetic fields：a pseudospectral approach

Energies and wavefunctions of low-lying states and Rydberg states for the sodium atom in uniform magnetic fields varying from 0 to 10^5T are calculated using a pseudospectral approach with a model potential in spherical coordinates. The energies are comparable with experimental results as well as those obtained by other calculations. The spectra of oscillator strength are worked out. The evolution of them with the magnetic field is shown.     

(S)-(+)-姜黄烯的立体选择性全合成

利用不对称双羟化反应和Raney镍的原位还原,高对映选择性和高产率地实现了(S)-(+)-α-姜黄烯(1)的立体选择性合成.用MsCl保护化合物7a和7b时,发现了有趣的消除和重排反应,得到对应的二烯化合物8.     

An alternating periodic－chaotic ISI sequence of HH neuron under external sinusoidal stimulus

A study of Hodgkin－Huxley (HH) neuron under external sinusoidal excited stimulus is presented in this paper. As is well known, the stimulus frequency is to be considered as a bifurcate parameter, and numerous phenomena, such as synchronization, period, and chaos appear alternatively with the changing of the stimulus frequency. For the stimulus frequency less than 2f_B (f_B being the base frequency in this paper), the simulation results demonstrate that the single HH neuron could completely convey the sinusoidal signal in anti-phase into interspike interval (ISI) sequences. We also report, perhaps for the first time, another kind of phenomenon, the beat phenomenon, which exists in the phase dynamics of the ISI sequences of the HH neuron stimulated by a sinusoidal current. It is shown furthermore that intermittent transition results in the general route to chaos.     

The isolated critical value phenomenon in local－global riddling bifurcation

A chaotic synchronized system of two coupled skew tent maps is discussed in this paper. The locally and globally riddled basins of the chaotic synchronized attractor are studied. It is found that there is a novel phenomenon in the local－global riddling bifurcation of the attractive basin of the chaotic synchronized attractor in some specific coupling intervals. The coupling parameter corresponding to the locally riddled basin has a single value which is embedded in the coupling parameter interval corresponding to the globally riddled basin, just like a breakpoint. Also, there is no relation between this phenomenon and the form of the chaotic synchronized attractor. This phenomenon is found analytically. We also try to explain it in a physical sense. It may be that the chaotic synchronized attractor is in the critical state, as it is infinitely close to the boundary of its attractive basin. We conjecture that this isolated critical value phenomenon will be common in a system with a chaotic attractor in the critical state, in spite of the system being discrete or differential.     

弱的参数周期扰动对一非线性系统安全域的影响与分形侵蚀安全域的控制

讨论了弱参数周期扰动对于非线性系统安全域的影响,在一定频率下的参数周期扰动将加速安全域的分形侵蚀,而在另一些频率的扰动下,将抑制安全域的分形侵蚀,并且存在着增进安全域的最优频率.提出了用弱参数周期扰动控制受到分形侵蚀的安全域的方法,并用Melnikov方法进行了分析.最后讨论了这种控制安全域的方法在实际环境中当具有外加噪声时的鲁棒性. 关键词： 分形吸引域边界 参数的周期扰动 控制     

A light scalar in the Minimal Dilaton Model in light of the LHC constraints

Whether an additional light scalar exists is an interesting topic in particle physics beyond the Standard Model(SM), as we do not know as yet the nature of physics beyond the SM in the low mass region in view of the inconsistent results of the ATLAS and CMS collaborations in their search for light resonances around 95 GeV in the diphoton channel. We study a light scalar in the Minimal Dilaton Model(MDM). Under the theoretical and the latest experimental constraints, we sort the selected data samples into two scenarios according to the diphoton rate of the light scalar: the large-diphoton scenario(with σ_(γγ)/SM■0.2) and the small-diphoton scenario(with σ_(γγ)/SM■0.2),which are favored by the CMS and ATLAS results, respectively. We compare the two scenarios, test the characteristics of the model parameters, the scalar couplings, production and decay, and consider how they could be further discerned at colliders. We draw the following conclusions for the two scenarios:(i) The large-diphoton scenario has in general a small Higgs-dilaton mixing angle(|sinθ_S|■0.2) and a small dilaton vacuum expectation value(VEV)f(0.5■η≡ v/f■1),and the small-diphoton scenario has large mixing(| sinθ_S|■0.4) or large VEV(η≡v/f ■0.3).(ii) The large-diphoton scenario in general predicts small syy coupling(|C_(sγγ)/SM|■ 0.3) and large sgg coupling(0.6■|C_(sgg)/SM|■1.2), while the small-diphoton scenario predicts small sgg coupling(|C_(sgg)/SM|■0.5).(iii) The large-diphoton scenario can interpret the small diphoton excess seen by CMS at its central value, when m_s■ 95 GeV,η■0.6 and | sinθ_S|■0.(iv) The large-diphoton scenario in general predicts a negative correlation between the Higgs couplings |C_(hγγ)/SMI and |C_(hgg)/SM|, while the small-diphoton scenario predicts that both couplings are smaller than 1,or |C_(hγγ)/SM|■0.9■|C_(hgg)/SM|.     

Analytical expressions of non-relativistic static multipole polarizabilities for hydrogen-like ions

Analytical formulas for the static multipole polarizabilities of hydrogen-like ions are derived by using the analytical wave functions and the reduced Green function and by applying a numerical fitting procedure.Our results are then applied to the studies of blackbody radiation shifts to atomic energy levels at different temperatures.Our analytical results can be served as a benchmark for other theoretical methods.