Y2O2S∶Eu3+,Mg2+,Ti4+长余辉材料制备中烧结条件和助熔剂的影响

Y2O2S∶Eu3+;Mg2+;Ti4+长余辉材料制备中烧结条件和助熔剂的影响;Y2O2S∶Eu3+;Mg2+;Ti4+; 烧结条件; 助熔剂; 发光性质     

阿特拉津分子印迹固相萃取柱的制备及应用

以阿特拉津为模板分子,α-甲基丙烯酸为功能单体,乙二醇二甲基丙烯酸酯为交联剂,偶氮二异丁腈为引发剂,65 ℃聚合17 h,制备了对阿特拉津具有特异性识别的分子印迹聚合物.将聚合物研磨、过筛、洗涤并装柱,制备分子印迹固相萃取柱,其最大结合量比游离态的聚合物微球高600倍,结合时间为游离态的1/60,采用液相色谱法检测其回收率达90%;用于富集水样中含量低于2×10-8 mol/L的待测物,其回收率也可达到89.3%.与市售C18柱相比,分子印迹固相萃取柱回收时间仅为C18柱的1/3,试剂用量为其1/4,但回收率更好,净化更彻底,减少了杂质峰对分析的影响,提高了灵敏度,利于仪器的保护和保养.应用此方法对实际农业水样进行了检测,结果满意.     

Spectroscopic characterization of mechanisms of oxidation of Phe by SO_4~- radical: A pulse radiolysis study

By using time-resolved kinetic spectrophotometry and pulse radiolysis technique, the oxidation of Phe by SO4- radical has been investigated both in aqueous and water/acetonitrilemixed solutions. The results reveal that attack of the oxidizing SO4- radical on Phe leads directlyto the formation of Phe cation radical 3 with a strong absorption peak at 310 nm, then it proceeds in three competitive reactions via either hydroxylation, deprotonation or decarboxylation, which were found to be strongly dependent upon the ionization state of the substitutes -COOH and -NH2 and the nature of the solvents. Decarboxylation takes place only when the carboxyl group is deprotonated. At high pH deprotonation of Phe cation radical 3 is much easier to occur than that in neutral or acid solutions. Moreover, with addition of acetonitrile, deprotonation is more predominant than hydroxylation, whereas in aqueous solutions hydroxylation is much easier to occur.     

EPR study on the photosensitized generation of reactive oxygen species by actinomycin D

Actinomycin D (AMD) is an anticancer antibiotic that can bind selectively to both double-stranded and single-stranded DNA, and this binding greatly enhances DNA photosensitization. Using electron paramagnetic resonance (EPR) in combination with spin trapping techniques, a systematic study was carried out on the reactive oxygen species generated in the photosensitization process of AMD. It was found that 1O2 and O2- are important reactive intermediates either insolution or in DNA complexes, and the generation of these species is in competition. This finding suggests that the photodynamic action of AMD proceeds via two pathways: energy transfer (type Ⅰ mechanism) and electron transfer (type Ⅱ mechanism). 1O2 is the main product formed via energy transfer reaction in solution while electron transfer between the excited states of AMD and DNA becomes the predominant pathway in DNA complexes.     

Fe3+存在下磺胺甲恶唑与牛血清白蛋白相互作用的光谱学研究

在模拟生理条件下,应用荧光光谱、紫外吸收光谱以及傅立叶变换红外光谱研究Fe3+存在下磺胺甲恶唑(Sulfamethoxazole,SMZ)与牛血清白蛋(Bovine Serum Albumin,BSA)的相互作用.结果表明,Fe3+存在时SMZ与BSA结合常数增大,作用力类型由疏水作用力转变为氢键和范德华力.无论Fe3...     

两个三角不等式

定理１在任意△ＡＢＣ中,Ａ、Ｂ、Ｃ表示其三内角,则ｃｏｓ３Ａ＋ｃｏｓ３Ｂ＋ｃｏｓ３Ｃ≥３８．（等号当且仅当△ＡＢＣ为正三角形时成立）证明由三角恒等式ｃｏｓ３Ａ＋ｃｏｓ３Ｂ＋ｃｏｓ３Ｃ＝（２Ｒ＋ｒ）３－３ｓ２ｒ４Ｒ３－１（Ｒ、ｒ、ｓ为△ＡＢＣ的外接圆半...     

一个经典不等式的再探究

文[1]得到以下结论:命题A 若a1,a2,…,an∈R+,且a1+a2+…+an=s,P∈R,且|p|≥2,则∑ni=11/api(s-ai)≥np+2/sp+1(n-1).其实,关于上述不等式的研究很多文献早有出现.如:徐丹,杨露老师在2001年就已证明了p≤-2的情形[2],2003年,裘敬华老师将结果推广到p≤-1的情形[3].2010年,翁利帅老师[4]将p的范围推广到p∈(-∞,-1]U[0,+∞),但对于p∈(-1,0)的情形,翁老师自称还“留下一点遗憾”.笔者经一番探究,得到如下结论:     

难题难在何处?

难题之所以难,难在三方面:①看不懂题意;②算不出结果;③处理不了综合问题.下面以我们平时考试中几道选择或填空题为例来分析难题的难点所在,并试图找到破解难题的一些有效方法.1.情景不熟悉导致看不懂题意