镍超细微颗粒的磁性

本文报道了镍超细微颗粒的磁性,比饱和磁化强度随颗粒尺寸减小而降低,当颗粒尺寸小于15nm时将会呈现剧烈地下降,此时矫顽力H_c亦将趋近于零,有效磁各向异性常数估算为K=-5.8×10⁵erg/cm³,远大于块状镍的数值,反磁化机制可用球键模型描述,对平均直径为9nm的样品,居里温度T_c值明显地低于块状镍的数值,这可能与点阵收缩有关。     

磁制冷工质材料的研究进展

本文简要叙述了磁制冷的基本原理和历史发展,详细地总结了国内外不同温区的磁制冷工质材料的研究成果,并展望了磁制冷工质材料的研究前景。     

全碳分子及其衍生物的结构与制备

本文介绍了全碳分子Ｃ＿（６０）,Ｃ＿（７０）以及管状全碳分子的构型、制备;全碳分子几种衍生物的类型。     

Effects of the Mn/Co ratio on the magnetic transition and magnetocaloric properties of Mn1+xCo1-xGe alloys

We have investigated the magnetic transition and magnetocaloric effects of Mn 1+x Co 1 x Ge alloys by tuning the ratio of Mn/Co.With increasing Mn content,a series of first-order magnetostructural transitions from ferromagnetic to paramagnetic states with large changes of magnetization are observed at room temperature.Further increasing the content of Mn (x=0.11) gives rise to a single second-order magnetic transition.Interestingly,large low-field magnetic entropy changes with almost zero magnetic hysteresis are observed in these alloys.The effects of Mn/Co ratio on magnetic transition and magnetocaloric effects are discussed in this paper.     

Martensitic transformation and related magnetic effects in Ni-Mn-based ferromagnetic shape memory alloys

Ferromagnetic shape memory alloys, which undergo the martensitic transformation, are famous multifunctional materials. They exhibit many interesting magnetic properties around the martensitic transformation temperature due to the strong coupling between magnetism and structure. Tuning magnetic phase transition and optimizing the magnetic effects in these alloys are of great importance. In this paper, the regulation of martensitic transformation and the investigation of some related magnetic effects in Ni-Mn-based alloys are reviewed based on our recent research results.     

Nonvolatile control of transport and magnetic properties in magnetoelectric heterostructures by electric field

Nonvolatile manipulation of transport and magnetic properties by external electric field is significant for information storage. In this study, we investigate the electric field control of resistance and magnetization in a magnetoelectric heterostructure comprising an electronic phase-separated La_(0.325)Pr_(0.3)Ca_(0.375)MnO_3(LPCMO) thin film and a ferroelectric(011)-oriented 0.7Pb(Mg_(1/3)Nb_(2/3))O_3-0.3PbTiO_3(PMN-PT) substrate. In a room-temperature poled sample, the metal-toinsulator transition temperature of an LPCMO film increases and the resistance decreases with variation in the effect of the remnant strain. Meanwhile, the increase in the magnetization of the sample is observed as well. This effect would be beneficial for the development of novel storage devices with low power consumption.     

共沉淀法制备Co掺杂ZnO的室温铁磁性的研究

利用共沉淀法并在5vol.%H₂/Ar气流中于300 ℃退火3 h,制备了Zn_1-xCo_xO稀磁半导体. 扫描电子微探针分析表明,对Co的名义组分分别为0.05,0.10,0.15的样品,其实际组分分别为x＝0.054, 0.100和0.159. X射线衍射表明, 主相为纤锌矿结构, x=0.100和 0.159的样品中含有CoO杂相. X射线光电子谱显示出Co有３种状态: 替代进入Z 关键词： 稀磁半导体 ZnO 共沉淀法 磁性来源     

Fe48Co52 Alloy Nanowire Arrays: Effects of Magnetic Field Annealing

详细研究了磁场退火对于具有不同线间距(30～60 nm)和不同线直径(22～46 nm)的Fe48Co52合金纳米线阵列性能的影响．研究表明,退火过程中沿纳米线方向施加3kOe的磁场对于阵列的最佳退火温度和晶体结构以及线直径较小或线间距较大阵列的磁性能均无明显影响．但是对于具有较大线直径或较小线间距的阵列,这种磁场退火处理限制了其易磁化方向的转动并明显提高了其矫顽力与矩形度．认为不同阵列内部有效各向异性场强度之间所存在的差异是导致磁场退火后阵列磁性能出现不同变化的主要原因．     

多晶Si0.9654Mn0.0346:B薄膜的磁性研究

利用磁控溅射和快速热处理的方法制备了Mn,B共掺的多晶硅薄膜(Si_0.9654Mn_0.0346:B).磁性和结构研究发现薄膜有两个铁磁相.低温铁磁相来源于杂相Mn₄Si₇,高温铁磁相(居里温度T_C～250K)是由Mn原子掺杂进入Si晶格导致.晶化后的薄膜利用射频等离子体增强化学气相沉积系统(PECVD)进行短暂(4min)的氢化处理后发现,薄膜的微结构没有发生变化而饱和磁化强度却随着 关键词： 磁性半导体 硅 氢化     

有机物包裹的Fe_3O_4颗粒表面自旋钉扎效应研究

测量了80A的Fe_3O_4颗粒和三种不同有机物包裹后的Mossbauer谱;不同有机物包裹后Mossbauer谱表现出不同程度的弥散,施加8kOe外磁场以后,所有样品的超顺磁谱均消失,并呈现六线谱。可以用有机物对Fe_3O_4表面Fe离子自旋产生钉扎作用来解释这些实验事实;从施加磁场前后Mossbauer谱的变化对钉扎作用的深度进行了估算。