基于预处理HLLEW格式的全速域数值算法

基于HLLEW(Harten-Lax-Van Leer-Einfeldt-Wada)格式引入预处理技术发展适合求解全速域流场的三维Navier-Stokes求解器.引入低速预处理技术,重新构造HLLEW格式的耗散项,给出预处理后的HLLEW格式,并根据预处理后的雅克比矩阵构造相应的隐式时间推进方程.利用预处理方法求解NACA 4412低速不可压流动与RAE 2822跨声速可压缩流动,并与实验结果及原有方法的计算结果对比.结果表明:预处理HLLEW格式不仅提高低速不可压缩流动的计算效率和精度,也保持了对可压缩流动的处理能力,是一种适用于全速域流场数值模拟的有效方法.     

凹腔非定常特性的数值模拟

采用基于Menter SST两方程湍流模型的DES方法,数值模拟开式凹腔在跨声速条件下的非定常流动特性.计算凹腔底部和后壁面上的点的声压级频谱以及总声压级,证明在第二噪声模态上的声压级最大.     

静气动弹性计算方法研究

对基于结构网格的Euler方程及N-S方程求解器和基于非结构网格的Euler方程求解器,采用结构模态分析方法和柔度矩阵方法,对无人机大展弦比机翼在Ma=0.6,α=2?, 飞行高度20km的巡航状态下的静气动弹性特性进行了数值模拟. 验证了两种求解器对静气动弹性模拟的准确性. 同时,对模态分析方法和柔度矩阵方法进行了对比研究,发现柔度矩阵方法更适用于静气动弹性数值模拟. 另外,对应用物面法向偏转方法替代网格变形技术模拟静气动弹性进行了研究,计算表明物面法向偏转方法可以大大提高静气动弹性计算效率和克服机翼结构变形过大时动网格技术无法处理的不足.      

高速列车气动外形优化研究进展

随着运行速度的提升,高速列车对气动外形的要求也越来越高,追求性能优异、美观大方的气动外形是新型高速列车研发的一个重要方向.基于当前高速列车外形研发的思路,可以将气动外形优化概括为基于流场机理的改型优化和基于优化算法的外形优化两类.本文简要回顾了当前国内外在这两类优化途径上的系列工作,着重介绍了作者所在团队近年来做过的一...     

可压缩涡中的激光传播

采用一种二维弱可压缩性的轴对称的涡模型,研究单个涡和光波阵面的相互干扰.对于低能量激光,在近场采用几何光学的分析方法.计算受干扰波阵面的光程差以及抖动角,确定通过涡的低密度区后会加速波阵面的变形,单体涡对光束有散焦作用.计算化学氧碘激光(COIL)通过涡之后的斯特列尔比,证明涡强对斯特列尔比有重要的影响.     

金刚石在C60薄膜表面的成核研究

用扫描电子显微术(SEM)研究了微波等离子体CVD生长金刚石系统,金刚石在以C₆₀蒸发膜为抛光Si衬底中间层上的成核行为,实验证实金刚石成核于C₆₀蒸发膜表面,同时观察到成核分布的不均匀性即成核聚集现象,并对此进行了初步分析。金刚石在C₆₀薄膜表面的成核表现出取向生长的特征。     

Laser fragmentation in liquid synthesis of novel palladium-sulfur compound nanoparticles as efficient electrocatalysts for hydrogen evolution reaction

One promising way to tune the physicochemical properties of materials and optimize their performance in various potential applications is to engineer material structures at the atomic level. As is well known, the performance of Pd-based catalysts has long been constrained by surface contamination and their single structure. Here, we employed an unadulterated top-down synthesis method, known as laser fragmentation in liquid (LFL), to modify pristine PdPS crystals and obtained a kind of metastable palladium-sulfur compound nanoparticles (LFL-PdS NPs) as a highly efficient electrocatalyst for hydrogen evolution reaction (HER). Laser fragmentation of the layered PdPS crystal led to a structural reorganization at the atomic level and resulted in the formation of uniform metastable LFL-PdS NPs. Noteworthy, the LFL-PdS NPs show excellent electrocatalytic HER performance and stability in acidic media, with an overpotential of -66 mV at 10 mA· cm^-2, the Tafel slope of 42 mV· dec^-1. The combined catalytic performances of our LFL-PdS NPs are comparable to the Pt/C catalyst for HER. This work provides a top-down synthesis strategy as a promising approach to design highly active metastable metal composite electrocatalysts for sustainable energy applications.     

Tuning Bandgap of Si-C Heterofullerene-Based Aanotubes by H Adsorption

We theoretically show that H atoms can be chemically adsorbed onto the surface of the Si-C heterofullerene- based nanotubes. The adsorbing energy of the H atom on Si-C heterofullerene-based nanotubes is in the range of 4.28-5.66 eV without any barrier for the H atom to approach to the Si-C heterofullerene-based nanotubes. The band-gap of Si-C heterofullerene-based nanotubes can be dramatically modified by introducing dopant states, i.e., there is a transition from semiconductor to conductor of the Si-C heterofullerene-based nanotubes induced by the adsorption of the H atom. These results actually open a way to tune electronic properties of heterofullerene-based nanotubes and thus may propose an efficient pathway for band structure engineering.