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Very large magnetic entropy change Δ SM, which originates from a fully reversible second-order transition at Curie temperature TC, has been discovered in compounds La(Fe, Si)13, La(Fe, Al)13 and those with Co doping. The maximum change ΔSM\approx19 J·kg-1·K-1, achieved in LaFe11.4Si1.6 at 209K upon a 5T magnetic field change, exceeds that of Gd by more than a factor of 2. The TC of the Co-doped compounds shifts to higher temperatures. ΔSM still has a considerable large magnitude near room temperature. The phenomena of very large ΔSM, convenience of adjustment of TC, and also thesuperiority of low cost, strongly suggest that the compounds La(Fe, M)13 (M=Si, Al) with Co doping are suitable candidates for magnetic refrigerants at high temperatures. 相似文献
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本报道了TIBACaCuO超导体(2212,2223单相,多晶及薄膜材料)中磁弛豫现象的实验结果,从实验上证实了能量运动由热激活到非热激活机制的转变,实验中得到与温度无关的磁弛豫速率与由通量运动量子隧道效应理论计算结果相一致,同时讨论了各向异性和磁场对磁通的量子漂移速率的影响。 相似文献
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The magnetic and transport properties of the Ga-doped charge-ordering state La0.5Ca0.5MnO3 have been studied. A current-dependent large positive magnetoresistance (1080%) at 5 K was observed. These observations are interpreted in terms of the spin-dependent tunnelling process between ferromagnetic clusters embedded in an antiferromagnetic matrix. 相似文献