基于单面金属结构的二维宽带左手材料

利用将磁谐振器与共面短金属导线相结合的思想,设计了一种基于单面金属结构的二维左手材料. 理论分析与仿真结果均表明该结构在某一频段同时具有负等效磁导率和负等效介电常数,并且相对左手带宽达到36%. 此外,该结构具有良好的容错能力,短金属导线宽度的变化对整体结构的谐振频率及通带宽度影响很小,这不仅有利于实际加工而且对于设计红外及太赫兹频率范围下的左手材料具有参考价值. 关键词： 左手材料 磁谐振器 宽频带 容错性     

基于多阶等离激元谐振的超薄多频带超材料吸波体

本文设计了一种超薄螺旋结构超材料吸波体,其厚度(1.034 mm)约为其工作波长(4.81 GHz,6.59 GHz,9.16 GHz,12.69 GHz和13.71 GHz)的(1/60,1/44,1/32,1/23,1/21).仿真和实验结果表明,该吸波体在4.81 GHz,6.59 GHz,9.16 GHz,12.69 GHz和13.71 GHz处吸收率分别达到94.55%、99.89%、99.73%、99.26%和99.41%,实现了多频带强吸收.从表面电流和功率损耗密度两个方面分析了产生强吸收的原因,理论分析表明,多频带强吸收能在五个相邻频率处产生多阶局域表面等离激元谐振,螺旋结构之间强烈的电谐振使超材料结构单元产生强烈的吸收.该超材料吸波体设计简单、易于制作和应用,在电磁波吸收中具有应用价值.     

Effects of A-site non-stoichiometry on the structural and electrical properties of 0.96K0.5Na0.5NbO3- 0.04LiSbO3 lead-free piezoelectric ceramics

Effects of A-site non-stoichiometry on the structural and electrical properties of 0.96K0.5+xNa0.5+xNbO3- 0.04LiSbO3 lead-free piezoelectric ceramics were examined for 0 ≤ x ≤ 0.02. The piezoelectric coefficients exhibited a maximum, d33 = 187 pC/N at x = 0.0075, coinciding with the maximum of the grain size and the apparent density at x = 0.0075. The apparent density and the piezoelectric coefficients decreased with increasing x at higher x which was likely due to the crystal geometrical distortion of 0.96K0.5+xNa0.5+xNbO3-0.04LiSbO3. In addition, super-large grains were found and this may be due to liquid phase sintering. Excess (K++Na+) attracted a sum of space charges to keep the charge neutral, resulting in charge leakage during the course of ceramic polarization, influencing the piezoelectric and ferroelectric properties. These findings are of importance for guiding the design of K0.5Na0.5NbO3-based lead-free ceramics with enhanced electrical properties.     

Decoupling technique of patch antenna arrays with shared substrate by suppressing near-field magnetic coupling using magnetic metamaterials

In this paper,we propose the decoupling technique of patch antenna array by suppressing near-field magnetic coupling(NFMC) using magnetic metamaterials.To this end,a highly-integrated magnetic metamaterials,the substrate-integrated split-ring resonator(SI-SRR),is firstly proposed to achieve negative permeability at the antenna operating frequency.By integrating SI-SRR in between two closely spaced antennas,magnetic fields are blocked in the shared substrate due to negative permeability of SI-SRR,reducing NFMC between the two antennas.To verify the technique,a prototype was fabricated and measured.The measured results demonstrated that the isolation can be enhanced by more than 17 dB even when the gap between the two patch antennas is only about 0.067 A.Due to high integration,this technique provides an effective alternative to high-isolation antenna array.     

施主掺杂对BaTiO3钙钛矿半导体纳米晶光催化性能的影响

以沉淀法制备的Cu_2O为牺牲模板剂,采用水热法制备La施主掺杂的BaTiO_3钙钛矿半导体纳米晶,借助X射线衍射(XRD)、透射电子显微镜(TEM)、高分辨透射电镜(HRTEM)、X射线光电子能谱((XPS)、扫描电子显微镜(SEM)、紫外-可见漫反射光谱(UV-Vis DRS)表征La掺杂的BaTiO_3晶的物相、微观形貌及光催化性能。结果表明,La掺杂BaTiO_3构建了晶体缺陷,有效提高了BaTiO_3的光催化性能。当掺杂量为4%(w/w)时,样品的光催化性能最好,在可见光照射360 min后,对4-硝基苯酚溶液的降解率可达到93.2%。该催化剂5次循环后的活性仍然大于86.7%,表明La施主掺杂的BaTiO_3是一种有效的可见光催化剂。     

基于人工表面等离激元的双通带频率选择结构设计

本文提出了一种基于人工表面等离激元的频率选择结构的设计方法：将设计的频率选择表面和金属鱼骨结构阵列相结合得到一种新的频率选择结构.文中采用这种方法设计了一种具有陡截止和高透、高抑制性能的双通带频率选择结构.该结构由金属鱼骨结构阵列和上下两层相同的频率选择表面复合而成.通过仿真可得,该结构的两个通带频率范围分别是3.0–4.1和10.5–10.9 GHz,透射率均在-0.5 dB以上.透射率低于-10 dB的频率范围是4.7–9.2和12.1–18 GHz.在12.4–15.5 GHz频率范围内,该结构的透射率甚至低于-20 dB.在通带内,电磁波可以高效地透过该结构;在阻带内,该结构对电磁波的透射具有较好的抑制作用.测试结果表明用这种方法设计出的频率选择结构的实际性能和仿真基本一致.在金属鱼骨结构空隙中填入轻质泡沫后该结构具有一定的力学承载性能,可以实现结构功能一体化的设计.     

Shared aperture metasurface antenna for electromagnetic vortices generation with different topological charges

Vortex beams carrying orbital angular momentum (OAM) have aroused great interest of both scientific and engineering communities. Encouragingly, generating OAM with different topological charges in a shared aperture is regarded as a potential route to expanding the communication capacity, which yet is an academic challenging task. In this work, a paradigm of designing metasurface-based shared aperture antenna for generating polarization-dependent vortex beams with distinct topological charges is proposed. Anisotropic unit cells that can tailor different resonance phase profiles in two orthogonal orientations are used to assemble a metasurface reflector. As a proof-of-concept, a planar reflector antenna is designed with two Vivaldi sources, which can generate x- and y-polarized vortex beams with topological charges of l=-1 and l=-2, respectively. Both the simulation results and the measurement results are in good agreement, which demonstrates the feasibility of our design. Significantly, this work provides a new route to achieving vortex beams carrying different topological charges in the same frequency band, which may have potential applications in communication systems.     

多孔羰基铁/SiO2/聚吡咯核壳结构复合材料的制备及电磁特性

首先对羰基铁进行点腐蚀得到多孔羰基铁,然后采用St?ber法和原位聚合法将SiO_2和导电高分子聚吡咯包覆在多孔羰基铁表面,制备多孔羰基铁/SiO_2/聚吡咯电磁复合吸波材料。采用XRD、SEM、TEM、FT-IR对样品结构、微观形貌进行了表征,在网络分析仪中采用同轴法测试样品电磁参数,并根据传输线理论研究了2~18 GHz微波频段内吡咯含量及涂层厚度对样品吸波性能的影响。实验结果表明:制备的多孔羰基铁/SiO_2/聚吡咯复合电磁吸波材料具有核壳结构;随着吡咯加入量的增加,吸波材料吸收峰逐渐向低频方向移动;当涂层厚度为3.5 mm、吡咯加入量为6%(w/w)时,在9.44~17.56 GHz范围内反射率均低于-10 d B,频带宽度为8.12 GHz,损耗反射率达到-23 d B。良好的吸波性能归因于复合物有效的阻抗匹配特性及多重界面极化效应,多孔羰基铁/SiO_2/聚吡咯是一种轻质、宽频、强吸收的吸波材料。     

KCdF3晶体中Cr3+-Li+中心局域结构研究

利用零场分裂参量与晶体结构之间的定量关系,研究了双掺杂晶体KCdF3∶Cr3+,Li+的局域结构.指出,对于 KCdF3∶Cr3+,Li+晶体,四角晶场的形成包含两个方面:(1)由于电荷补偿而产生的等效电荷形成的四角对称晶场;(2)Cr3+的局域结构发生晶格畸变而产生的四角对称晶场.事实上,当Cr3+和Li+掺入KCdF3晶体时,Cr3+代替了Cd2+离子;由于Cr3+离子与Cd2+离子的半径不同、电荷不同、质量不同,导致Cr3O+的局域结构发生晶格畸变,由此而产生四角对称晶场;由于电荷补偿,Li+ 离子取代了[001]方向与Cr3+离子邻近的Cd2+离子,由此产生的等效电荷而形成的四角晶场.这样,Cr3+的局域结构由Oh对称变为C4v点对称 .文中建立了ZFS参量和晶体结构之间的定量关系.在考虑晶格畸变和等效电荷的基础上,研究了KCd F 3∶Cr3+,Li+晶体的ZFS参量,理论结果和实验符合很好.得到了F-离子向中心离子分别移动为ΔR1=0.00268nm,ΔR2=0.001nm,ΔR3=0.00165nm .     

基于群表示论的微波等离激元谐振器模式响应研究

作为光频段局域表面等离激元的低频对应物,人工局域表面等离激元因其深亚波长局域场增强和高Q值谐振的特点而受到广泛关注。微波等离激元谐振器是产生人工局域表面等离激元的典型器件,其特点是具有多重离散旋转对称性和镜面反射对称性。以往的研究提出了等效媒质法和等效色散法分析微波等离激元谐振器的模式响应,但这两种方法都未能充分考虑谐振器的几何对称性从而未能全面揭示其模式特性。本文针对谐振器的几何对称性提出了群表示论方法分析其模式响应。通过对称性分析,发现谐振器的几何对称性所构成的群的不可约表示数等于谐振器所能支持的人工局域表面等离激元模式的数目。以对称性构成C_7v群的谐振器为例,C_7v群的5个不可约表示数对应了5种人工局域表面等离激元模式,分别为零阶模式(也即磁偶极子)、偶极子、四极子、六极子和十四极子。受限于几何对称性,谐振器将不能支持更多阶的模式。为验证群表示论方法,设计了对称性构成C_7v群的微波等离激元谐振器,全波仿真结果很好地证明了上述理论。本文提出的群表示论方法也可推广到其他频段如光频,因而具有广泛的适用性。