High pressure synthesis and characterization of the pyrochlore Dy2Pt2O7:A new spin ice material

The cubic pyrochlore Dy2Pt2O7 was synthesized under 4 GPa and 1000℃ and its magnetic and thermodynamic properties were characterized by DC and AC magnetic susceptibility and specific heat down to 0.1 K.We found that Dy2Pt2O7 does not form long-range magnetic order,but displays characteristics of canonical spin ice such as Dy2Pt2O7,including(1)a large effective moment 9.64μB close to the theoretical value and a small positive Curie-Weiss temperatureθCW=+0.77 K signaling a dominant ferromagnetic interaction among the Ising spins;(2)a saturation moment ~4.5μB being half of the total moment due to the local<111>Ising anisotropy;(3)thermally activated spin relaxation behaviors in the low(~1 K)and high(~20 K)temperature regions with different energy barriers and characteristic relaxation time;and most importantly,(4)the presence of a residual entropy close to Pauling’s estimation for water ice.     

超音速气流中受热曲壁板的非线性颤振特性

基于von Karman 大变形理论及带有曲率修正的一阶活塞理论, 用Galerkin方法建立了超音速气流中受热二维曲壁板的非线性气动弹性运动方程; 采用牛顿迭代法计算得到由静气动载荷和热载荷引起的静气动弹性变形; 根据李雅谱诺夫间接法分析了壁板初始曲率与温升对颤振边界的影响; 对二维曲壁板的非线性气动弹性方程组进行数值积分求解,分析了动压参数对受热二维曲壁板分岔特性的影响, 给出了典型状态下曲壁板非线性颤振响应的时程图与相图. 分析结果表明对小初始曲率的曲壁板, 温升对其静气动弹性变形影响较大, 且随着温升的增加其颤振临界动压急剧减小; 对具有较大初始曲率的曲壁板, 温升对其静气动弹性变形的影响较弱, 且随着温升的增加颤振临界动压基本保持不变. 初始几何曲率与气动热效应使得曲壁板具有复杂的动力学特性, 不再像平壁板一样, 经过倍周期分岔进入混沌, 而会出现由静变形状态直接进入混沌运动的现象, 且在混沌运动区域中还会出现静态稳定点或谐波运动, 在大曲率情况下, 曲壁板不会产生混沌运动, 而是幅值在一定范围内的极限带振荡.      

资金约束下三层供应链的融资和定价决策研究

实际生活中,供应链的资金管理是极其复杂多变的,现有学者关于供应链定价问题研究多以简单的二层供应链为基础,脱离了实际可用性。本文将二层供应链拓展成三层供应链,以单一供应商、单一生产商和单一零售商组成的三层供应链为研究对象,在市场风险中性的假设条件下,探究在供应商拥有不同初始资金约束情形下的供应链融资与最优定价决策,弥补了原先模型使用范围的狭隘性。通过模型的建立与数值分析显示,当供应商存在资金约束时,供应链融资能够使整条供应链上参与者的最优利润增加,从而创造价值。     

新型带宽调制型Mott化合物的高压合成及其金属化相变

利用高温高压条件，制备了（SrCa）CrO3系列带宽可调型的钙钛矿Mort化合物。在10 GPa的外加压力下，观察到SrCrO3的绝缘体-金属化相变。原位高压x射线衍射实验表明，Sr／CaCrO3晶体结构在0-9 GPa压力范围内保持稳定。但SrCrO3在4 GPa时存在着电子结构变化所引起的等结构相变，表现为体弹性模量的反常软化。此外，由于电子关联效应，磁性和热输运性质的测试结果表明了材料的奇异电子态特征。     

Light scattering effect of submicro-textured Ag/Al composite films prepared at lower substrate temperatures

We present a new and practical approach for preparing submicro-textured silver and aluminum (Ag/Al) double-structured layers at low substrate temperatures. The surface texturing of silver and aluminum double-structured layers was performed by increasing the deposition temperature of the Al layers to 270℃. The highly submicro-textured silver and aluminum double-structured layers were prepared by thermal evaporation on quartz glasses and their surface microstructure, light scattering properties, and thermal stability were investigated. Results showed that the highly submicro-textured Ag/Al composite films prepared at low substrate temperatures used as back reflectors not only can enhance the light scattering and have good thermal stability, but also have good adhesion properties. In addition, their fabrication is low cost and readily carried out.     

英国化学思想史家大卫·奈特

随着化学史的逐步成熟,相应地,其研究内容日益丰富。其中,关于化学思想史的研究近年来在我国化学史界方兴未艾。在西方,由于化学史的成熟和化学史与社会学相联系的研究趋势,化学思想史已经成为化学史研究的一门重要分     

基于在险价值的物流网络规划模糊两阶段模型与精确求解方法

针对物流网络规划问题中顾客需求和运输成本的不确定性,使用在险价值量化投资风险,建立了以投资损失的在险价值最小化为目标的模糊两阶段物流网络规划模型。对于模型中不确定参数均为规则模糊数的这一类模糊两阶段规划模型,本文通过理论分析和证明将其转化为等价的确定一阶段规划模型进行求解,从而将无穷维的优化问题转化为有限维的经典优化问题,降低了计算难度且得到了模型的精确解。不同规模的数值实验证实了所提出模型及其求解方法的有效性。     

Synthesis, Crystal Structures and Characterization of Ba5LiTiNb9O30

A new niobate compound with the chemical composition of Ba5LiTiNb9O30 was synthesized by doping Li^ into the system BaO-TiO2-Nb2O5 in conventional solid state reaction method. The crystalline structure was determined by X-ray diffraction analysis (XRD). The results showed that crystal structure of Ba5LiTiNb9O30 belongs to tetragonal tungsten bronze structure with space group P4bm and its unit cell parameters: a=b=1.2512(2) nm, c=0.4008(5)nm. The microstructure of reaction products was observed by scanning electron microscopy (SEM).     

Highly sensitive torsion sensor based on Mach–Zehnder interference in helical seven-core fiber taper

We propose a high-sensitivity bidirectional torsion sensor using a helical seven-core fiber taper embedded in multimode fiber(MHSTM).Sensors with different taper waists and helical pitches are fabricated,and their transmission spectra are obtained and analyzed.The waist and length of the sandwiched seven-core fiber are finally determined to be 68 μm and3 mm,respectively.The experimental results show that the clockwise and counterclockwise torsion sensitivities of the proposed sensor are 2.253 nm...     

高氧压合成产物La2CuO4+δ的相变研究

 本文采用超高氧压2.3 GPa合成方法，得到超导相含量大于30%的超导化合物La₂CuO_4+δ所采用的压力是目前所见报导中对La₂CuO₄化合物施加的最高氧压。湿化学方法测量给出过量氧含量δ=0.05±0.01，而TGA（氮气中）给出δ=0.143。高氧压合成产物经在空气中、不同温度下加热，然后淬火到室温，结果发现超导体在200~300 ℃的加热处理中存在着一个一级相变。经此相变后，超导体转变成反铁磁半导体。TGA及DSC证实了此相变的存在。该相变前后所联系的氧含量变化恰好为湿化学方法给出的结果，这部分与超导电性存在联系的过量氧，实际上引起了Cu²⁺向Cu^(2+2δ)+的转变。该结果强有力地排除了所谓“超氧化物”引起超导电性的可能性。