微观相场法模拟Ni75Al5.3V19.7 中L12和D022结构反位缺陷的演化

运用微观相场法研究Ni₇₅Al_5.3V_19.7合金沉淀过程中L1₂结构和D0₂₂结构反位缺陷发现：在沉淀初期,L1₂结构反位缺陷Al_Ni,V_Ni,Ni_Al,D0₂₂结构反位缺陷V_Ni,Al_Ni关键词： 微观相场 反位缺陷 L1₂结构')" href="#">L1₂结构 D0₂₂结构')" href="#">D0₂₂结构     

酶催化光度法测定卡托普利

基于卡托普利对牛血红蛋白模拟酶催化体系的抑制作用,建立了酶催化光度法测定卡托普利的新方法.研究了该抑制反应的最佳实验条件及动力学行为,测定的线性范围为6.23×10-8～1.25×10-5 mol/L,检出限为3.88×10 -9mol/L.对浓度为6.23×10 -6mol/L的卡托普利进行11次平行测定,其相对标准...     

Microscopic Phase-Field Simulation of Atom Substitution Behaviour in Ni-Cr-Al Alloy

Simulations are performed on atom substitution behaviour in Ni75Al25-xCrx alloys based on a microscopic phasefield model at 873K. The ordering of both the Al and Cr atoms takes place simultaneously, Cr occupies both the Al and Ni sites with a preference for the Al sites, and Cr and A1 atoms together occupy the β-sites, and the complex γ‘ Ni3 (Al1-x Crx) (L12 structure) phases are formed during the precipitation. At the ordering boundary of L12 phases, Cr atoms occupy the Al sites, then Ni3Cr phases are formed.     

整个生育期玉米叶片SPAD高光谱预测模型研究

以两年完整生育期玉米田间试验为基础,利用便携式地物光谱仪和叶绿素仪(SPAD-502)分别测定了叶片高光谱数据和叶绿素含量(SPAD),在两者相关分析的基础上,选取多种光谱参数分别构建了每年的叶片SPAD预测模型,并对模型进行了详细的验证和评价。结果表明：两年间叶片光谱反射率及其一阶导数的平均值曲线差别很小;两年间叶片SPAD与光谱反射率及其一阶导数的相关系数曲线的敏感区域基本相同;以一阶导数为光谱参数构建的预测模型效果不稳定;以LCI和DSI(R_550附近,R_680附近)和DSI(R_680附近,R_710附近)构建的预测模型效果良好,能有效预测玉米叶片SPAD。     

Ni75Cr25-xAlx合金中L12相和D022相形核孕育期的微观相场模拟

基于微观相场动力学模型,运用原子图像、平均长程序参数和平均成分偏离序参数,研究了Al浓度对Ni₇₅Cr_25-xAl_x合金中L1₂相和D0₂₂相形核孕育期的影响以及孕育期与沉淀相析出顺序之间的关系.结果表明,L1₂相和D0₂₂相的形核孕育期不仅与Al浓度有关,而且与两相析出的先后顺序密切相关.当Al浓度小于7.5%时,先析出相为D0₂₂相,随着Al浓度的增大,D0₂₂相形核孕育期延长,后析出的L1₂相的形核孕育期也延长,L1₂相的原子簇?聚?速度加快;当Al浓度大于7.5%时,先析出相为L1₂相,随着Al浓度的增大,L1₂相的形核孕育期缩短,后析出的D0₂₂相形核孕育期也缩短.当Al浓度为7.5%时,L1₂相和D0₂₂相几乎同时析出,两者的孕育期没有明显的差别. 关键词： 形核孕育期 序参数 沉淀 微观相场模拟     

Dynamic scaling behaviour of late-stage phase separation in Ni75AlxV25-x alloys

The dynamic scaling behaviour of late-stage phase separation and coarsening mechanisms of L12 and D022 in Ni75AlxV25-x （3 ≤ x ≤ 10, at.%） alloys are studied using the microscopic phase-field dynamic model. The microelaso ticity field is incorporated into the diffusion dynamic model. The results show the morphology and coarsening dynamics being greatly changed by the elastic interactions among different precipitates, the particles aligning along the dominant directions, the average domain size （ADS） of L12 and D022 deviating from the exponent of temporal power-law, and the growth slowing down due to the increasing of elastic interactions. The dynamic scaling regime of late-stage coarsening of the precipitates is attained. Thus the scaling behaviour of structure function is also applicable for elastic interaction systems. It is also found that the variations of ADS and scaling function depend on the volume fraction of precipitates.